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JP2001069801A - Organic waste treatment method - Google Patents

Organic waste treatment method

Info

Publication number
JP2001069801A
JP2001069801A JP24726199A JP24726199A JP2001069801A JP 2001069801 A JP2001069801 A JP 2001069801A JP 24726199 A JP24726199 A JP 24726199A JP 24726199 A JP24726199 A JP 24726199A JP 2001069801 A JP2001069801 A JP 2001069801A
Authority
JP
Japan
Prior art keywords
organic waste
active carbon
activated carbon
biogas
treating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP24726199A
Other languages
Japanese (ja)
Inventor
Tsutomu Tsuruta
勉 鶴田
Tomohiro Sakakibara
知洋 榊原
Kiyoshi Yoshida
清 吉田
Tetsuo Shiotani
哲夫 塩谷
Shuhei Kanda
修平 神田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Exeo Group Inc
Original Assignee
Kyowa Exeo Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyowa Exeo Corp filed Critical Kyowa Exeo Corp
Priority to JP24726199A priority Critical patent/JP2001069801A/en
Publication of JP2001069801A publication Critical patent/JP2001069801A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

PROBLEM TO BE SOLVED: To treat organic waste without causing environmental disruption due to malodor by treating the organic waste together with active carbon under a specific condition. SOLUTION: Organic waste and active carbon are thrown into an anaerobic fermentation vessel and treated under an anaerobic condition. It is preferable to place an organic waste tank in a previous step to the anaerobic fermentation vessel and to premix the organic waste and the active carbon. An amount added of the active carbon is preferably >=2 vol.% and the active carbon may be leaf charcoal obtained from chaff. The organic waste mainly comprises garbage and excreta of animals or the like. This method is very useful because biogas having a decreased content of sulfur can be obtained even when a conventional facilities are used as they are and also a digested liquid can be converted into an organic fertilizer having soil improving effect. The method also has a great advantage that the biogas does not always need a desulfurizer when being utilized.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は嫌気性処理によって
有機性廃棄物を処理する方法に関し、特に、畜産の糞尿
や生ゴミ等から、硫黄分の少ないバイオガスを製造する
ことができると共に、消化液にも土壌改良作用を有する
有機肥料としての付加価値を付与することのできる、有
機性廃棄物の処理方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for treating organic wastes by anaerobic treatment, and more particularly to a method for producing biogas with low sulfur content from livestock manure and garbage and digestion. The present invention relates to a method for treating organic waste, which can provide a liquid with added value as an organic fertilizer having a soil improving effect.

【0002】[0002]

【従来技術】従来から、畜産の糞尿等を嫌気性条件下で
処理し、メタンガス等のバイオガスを発生させ、これを
燃料として使用することが行われている。この場合、一
般に酸発酵を経てメタン発酵が起るが、このようなバイ
オガス中には多量の硫化水素が含まれているのが普通で
あり、これがバイオガスの悪臭の原因となるばかりでな
く、該ガスを使用する施設を腐蝕するという欠点があっ
た。また、嫌気性処理以前における糞尿等の貯留時の悪
臭も環境を破壊するという欠点があった。
2. Description of the Related Art Conventionally, livestock manure and the like have been treated under anaerobic conditions to generate biogas such as methane gas, which is used as fuel. In this case, methane fermentation generally occurs via acid fermentation, but such a biogas usually contains a large amount of hydrogen sulfide, which not only causes a bad smell of the biogas but also However, there is a disadvantage that the facility using the gas is corroded. In addition, there is a drawback that an odor during storage of manure or the like before the anaerobic treatment also destroys the environment.

【0003】本発明者等は、上記の欠点を解決するため
に種々検討した結果、糞尿等の有機性廃棄物の発酵時に
活性炭を添加しておくことによりバイオガス中の硫化水
素含有量を著しく低減させることができ、これによって
上記悪臭の発生を防止することができると共に、消化液
中の活性炭は土壌改良材として機能するので土壌改良効
果を有する有機肥料を得ることもできるということを見
出し本発明に到達した。
[0003] The present inventors have conducted various studies to solve the above-mentioned drawbacks. As a result, by adding activated carbon during the fermentation of organic waste such as manure, the content of hydrogen sulfide in biogas is significantly reduced. It is possible to reduce the occurrence of the above-mentioned odor, and it is possible to obtain an organic fertilizer having a soil improvement effect because the activated carbon in the digestive juice functions as a soil improvement material. The invention has been reached.

【0004】[0004]

【発明が解決しようとする課題】従って本発明の第1の
目的は、悪臭による環境破壊を起こすことのない、有機
性廃棄物の処理方法を提供することにある。本発明の第
2の目的は、硫黄分の含有量が低減されたバイオガスを
生産することのできる、有機性廃棄物の処理方法を提供
することにある。更に、本発明の第3の目的は、有機性
廃棄物を、環境破壊を起こすことのないエネルギー源と
してのみならず、土壌改良効果を有する肥料源として再
活用することのできる処理方法を提供することにある。
SUMMARY OF THE INVENTION Accordingly, it is a first object of the present invention to provide a method for treating organic waste, which does not cause environmental destruction due to bad smell. A second object of the present invention is to provide a method for treating organic waste, which can produce biogas with a reduced sulfur content. Further, a third object of the present invention is to provide a method for treating organic waste which can be reused not only as an energy source that does not cause environmental destruction but also as a fertilizer source having a soil improvement effect. It is in.

【0005】[0005]

【課題を解決するための手段】本発明の上記の諸目的
は、有機性廃棄物と活性炭を嫌気性発酵槽に投入し、嫌
気性条件下で処理することを特徴とする、有機性廃棄物
の処理方法によって達成された。
SUMMARY OF THE INVENTION The above objects of the present invention are attained by charging organic waste and activated carbon into an anaerobic fermenter and treating it under anaerobic conditions. Was achieved by the following processing method.

【0006】[0006]

【発明の実施の形態】本発明における有機性廃棄物は、
嫌気性条件下で処理することのできるものであることが
必要であり、その代表的なものは、生ゴミ、及び、動物
の糞尿等である。本発明においては、特に、畜産によっ
て廃出されるこれらの有機性廃棄物が、大量であるだけ
でなく収集し易いので好適である。
DETAILED DESCRIPTION OF THE INVENTION The organic waste in the present invention is:
It must be one that can be treated under anaerobic conditions, and typical ones are garbage and animal manure. In the present invention, it is particularly preferable that these organic wastes discharged from livestock farming are easy to collect as well as in large quantities.

【0007】本発明で使用する活性炭は特に限定される
ものではないが、特に、安価であると共に取り扱い性が
良いという観点から、籾殻燻炭を使用することが好まし
い。この活性炭を有機性廃棄物と共に貯留槽に添加すれ
ば、従来有機性廃棄物貯留槽から発生していた悪臭の発
生を防止することができる。また、有機性廃棄物の嫌気
性発酵槽に混在させることにより、発生したバイオガス
中の硫黄分を著しく低減することができる。従って、本
発明においては、有機性廃棄物の貯留槽に活性炭を予め
添加し、この活性炭を含有する有機性廃棄物を定量的に
嫌気性発酵槽に移送して、嫌気性条件下で処理すること
が好ましい。このようにすることにより、硫黄分の含有
量の少ないバイオガスを定常的に発生させることができ
るので、これを回収してクリーンなエネルギー源として
利用することが容易となる。
[0007] The activated carbon used in the present invention is not particularly limited, but it is particularly preferable to use rice husk charcoal from the viewpoint of low cost and good handling. If this activated carbon is added to the storage tank together with the organic waste, it is possible to prevent the generation of offensive odor which has conventionally been generated from the organic waste storage tank. Also, by mixing organic waste in an anaerobic fermenter, the sulfur content in the generated biogas can be significantly reduced. Therefore, in the present invention, activated carbon is previously added to an organic waste storage tank, and the organic waste containing the activated carbon is quantitatively transferred to an anaerobic fermenter and treated under anaerobic conditions. Is preferred. By doing so, a biogas having a low sulfur content can be constantly generated, so that it is easy to recover the biogas and use it as a clean energy source.

【0008】本発明における活性炭の添加量は上記の如
き効果を生ずる量であれば良いが、必要以上に多くする
ことによる利点もないので、通常は、混合物中の体積%
で、2〜10%となる量を添加すれば足りる。活性炭添
加による上記の効果は、単純には、活性炭による硫黄分
の優先的吸着効果であると推定することができる。しか
しながら、活性炭の添加量を増加するにつれ、バイオガ
スの回収量も増加するように見えるので、活性炭が多孔
質構造を有するために、これが菌床として作用する可能
性や、発酵阻害物質の吸着等、更に別の作用の存在も考
えるべきとも思われる。また、本発明における発酵槽は
公知の方法によって適宜撹拌・混合すれば良い。
In the present invention, the amount of activated carbon added may be any amount that produces the above-mentioned effects. However, since there is no advantage by increasing the amount more than necessary, usually, the volume% in the mixture is
It is sufficient to add an amount of 2 to 10%. The above effect by adding activated carbon can be simply assumed to be a preferential adsorption effect of sulfur by activated carbon. However, as the amount of activated carbon added increases, the amount of biogas recovered also seems to increase, so the activated carbon has a porous structure, which may act as a bacterial bed, adsorb fermentation inhibitors, etc. It may be necessary to consider the existence of yet another effect. The fermenter in the present invention may be appropriately stirred and mixed by a known method.

【0009】本発明によって得られたバイオガス中の硫
黄分は極めて少ないので、該ガスを利用する施設を腐蝕
することがない。また、原料である有機性廃棄物中に含
有されていた硫黄分は消化液中の活性炭に吸着されてい
るので、その分消化液は硫黄分を多く含有することにな
る。消化液中の液分及び有機固形分は有機肥料となり、
活性炭部分は土壌改良材となるので、施肥の対象となる
植物に応じて、施肥量を調節したり有機性廃棄物の処理
時に添加する活性炭の量を調節して、施肥の最適化を図
ることもできる。
[0009] Since the sulfur content in the biogas obtained by the present invention is extremely low, the facility utilizing the gas does not corrode. Further, since the sulfur content contained in the organic waste as the raw material is adsorbed by the activated carbon in the digestive juice, the digestive juice contains a large amount of sulfur by that amount. The liquid and organic solids in the digestive juice become organic fertilizer,
Activated carbon is used as a soil amendment material, so it is necessary to adjust the amount of fertilizer or the amount of activated carbon added when processing organic waste according to the plant to be fertilized to optimize fertilization. Can also.

【0010】[0010]

【発明の効果】以上詳述した如く、本発明によれば、従
来の施設をそのまま使用しても、硫黄分の含有量が低減
されたバイオガスが得られる上、消化液の方は、土壌改
質効果を有する有機肥料に転換されるので極めて有意義
である。また、バイオガスを利用する場合に、脱硫装置
を必ずしも必要としないという大きな利点も生ずる。更
に、活性炭として籾殻燻炭を使用すれば、農業系廃棄物
である籾殻を有効利用することもできる。
As described above in detail, according to the present invention, even if the conventional facility is used as it is, a biogas with a reduced sulfur content can be obtained, and the digestive juice can be used in the soil. This is extremely significant because it is converted to an organic fertilizer having a modifying effect. Also, when using biogas, there is a great advantage that a desulfurization device is not necessarily required. Furthermore, if rice husk charcoal is used as activated carbon, rice husk, which is agricultural waste, can be effectively used.

【0011】[0011]

【実施例】以下、本発明を実施例によって更に詳述する
が、本発明はこれによって限定されるものではない。
尚、実験試料としては、東京農工大学付属農場で飼育さ
れている乳牛(成牛)より排泄された糞を採集し、この
糞1リットルに対して水道水2リットルの割合で希釈し
た。この希釈試料を磨砕機(増幸産業(株)製)にて磨
り潰し、粒状を均一化したものを実験試料とした。実験
試料の性状を表1に示す。
EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto.
As an experimental sample, feces excreted from dairy cows (adult cows) bred on a farm attached to Tokyo University of Agriculture and Technology were collected, and diluted at a ratio of 2 liters of tap water to 1 liter of the feces. The diluted sample was crushed with a grinding machine (manufactured by Masuko Sangyo Co., Ltd.) to obtain a uniform sample and used as an experimental sample. Table 1 shows the properties of the experimental samples.

【表1】 但し、表中の記号は下記の通りであり、また、pHを除
き単位はmg/リットルである。 TOC:全有機炭素 BOD:生物化学的酸素要求量 CODcr:化学的酸素要求量 T−N:全窒素 T−P:全リン K :カリウム
[Table 1] However, the symbols in the table are as follows, and the unit is mg / liter except for the pH. TOC: Total organic carbon BOD: Biochemical oxygen demand CODcr: Chemical oxygen demand TN: Total nitrogen TP: Total phosphorus K: Potassium

【0012】実施例1〜3.実験装置として、1m
メタン発酵槽を有する実験機を用いた(図2参照)。磨
砕機2に投入した実験試料1は、粉砕された後、原料貯
留槽3(有効容量500リットル)に一時貯留され、4
0℃に加温した発酵槽4(有効容量1,000リット
ル)に、1日1回、ポンプにて90リットルづつ投入さ
れた。
Embodiments 1-3. As an experimental apparatus, an experimental machine having a 1 m 3 methane fermentation tank was used (see FIG. 2). The experimental sample 1 put into the attritor 2 is pulverized and then temporarily stored in the raw material storage tank 3 (effective capacity 500 liters).
The fermenter 4 (effective capacity: 1,000 liters) heated to 0 ° C. was charged once a day by 90 liters with a pump.

【0013】発酵槽内液の撹拌は、ガスホルダー5
(1,000リットル)に貯留された発生ガスをルーツ
式ブロワ6(アンレット社製 BS40−gs)にて吸
引し、ガス貯留タンク7(有効容量200リットル)に
送気し、本タンクに圧縮貯留されたガスを発酵送下部よ
り流入させることにより行った。なお、撹拌ガス量はガ
ス貯留タンク内の水量を調整することによって行い、撹
拌回数は24時間タイマーを調整して行った。1回の撹
拌は、貯留タンクに0.5kgf/cmまで圧縮され
たバイオガスを0.3kgf/cmに低下するまで発
酵槽下部から注入するものとした。また、発生ガス量は
積算ガスメーター(金門製作所製N−2)にて測定し
た。
The liquid in the fermenter is stirred by a gas holder 5.
The generated gas stored in (1,000 liters) is sucked by a roots-type blower 6 (BS40-gs, manufactured by Anlet), sent to a gas storage tank 7 (effective capacity 200 liters), and compressed and stored in this tank. This was carried out by flowing the gas from the lower part of the fermentation feeder. The amount of stirring gas was adjusted by adjusting the amount of water in the gas storage tank, and the number of stirring was adjusted by adjusting a 24-hour timer. Stirring once were assumed for injecting biogas are compressed in the storage tank to 0.5 kgf / cm 2 from the fermentation tank bottom until reduced to 0.3 kgf / cm 2. The amount of generated gas was measured by an integrating gas meter (N-2 manufactured by Kinmon Seisakusho).

【0014】籾殻燻炭を実験試料に10%(実施例
1)、5%(実施例2)、2%(実施例3)の容積比で
添加した時の発生ガス収量は10%添加の場合が最も多
く、他の添加試料においても無添加の対照と比較して、
発生ガス収量の増加が確認された。この増加要因として
は、燻炭の構造が多孔質状であるため菌床として作用し
たこと、また、燻炭の物質吸着効果により発生阻害物質
が吸着されたこと、という2つが考えられる。また、発
生したバイオガス中の硫化水素濃度をガス検知管(ガス
テック(株)製のGV−100検知管)によって測定
したところ、下記表2の結果が得られた。
In the case where rice husk charcoal is added to the experimental sample at a volume ratio of 10% (Example 1), 5% (Example 2), and 2% (Example 3), the generated gas yield is 10%. Is the most, and also compared to the control without addition in other addition samples,
An increase in the generated gas yield was confirmed. There are two possible causes of this increase: the fact that the structure of the charcoal has a porous structure, thus acting as a bacterial bed, and the fact that the generation inhibiting substance is adsorbed by the substance adsorption effect of the charcoal. The concentration of hydrogen sulfide in the generated biogas was measured with a gas detector tube (GV-100 + detector tube manufactured by Gastech Co., Ltd.), and the results in Table 2 below were obtained.

【表2】 表2の結果から、本発明の方法によって得られたバイオ
ガス中の硫化水素濃度が、従来より著しく低減されたこ
とが実証された。
[Table 2] From the results in Table 2, it was demonstrated that the concentration of hydrogen sulfide in the biogas obtained by the method of the present invention was significantly reduced as compared with the conventional case.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の有機性廃棄物処理方法の工程概念図で
ある。
FIG. 1 is a process conceptual diagram of an organic waste treatment method of the present invention.

【図2】実施例で使用した、実験装置の概念図である。FIG. 2 is a conceptual diagram of an experimental device used in Examples.

【符号の説明】 1 有機性廃棄物 2 磨砕機 3 原料貯留槽 4 メタン発酵槽 5 ガスホルダー 6 撹拌ブロワ 7 ガス貯留タンク 8 液肥として散布[Description of Signs] 1 Organic waste 2 Grinding machine 3 Raw material storage tank 4 Methane fermentation tank 5 Gas holder 6 Stirring blower 7 Gas storage tank 8 Spray as liquid fertilizer

───────────────────────────────────────────────────── フロントページの続き (72)発明者 榊原 知洋 東京都渋谷区渋谷3丁目29番20号 株式会 社協和エクシオ内 (72)発明者 吉田 清 東京都渋谷区渋谷3丁目29番20号 株式会 社協和エクシオ内 (72)発明者 塩谷 哲夫 東京都中野区上高田4−8 高田第二住宅 (72)発明者 神田 修平 東京都府中市幸町2−40 C−505 Fターム(参考) 4D004 AA02 BA02 BA04 CA18 CB03 CB04 CC08 CC11 DA03 DA10 DA11 4H061 AA02 CC36 CC55 DD14 DD20 EE01 EE61 GG50 HH42 LL26 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Tomohiro Sakakibara 3-29-20, Shibuya, Shibuya-ku, Tokyo Inside Kyowa Exio Co., Ltd. (72) Inventor Kiyoshi Yoshida 3-29-20, Shibuya, Shibuya-ku, Tokyo Stock Company Kyowa Exio (72) Inventor Tetsuo Shioya 4-8 Kamitada, Nakano-ku, Tokyo 2nd Takada Second House (72) Inventor Shuhei Kanda 2-40 Sachimachi, Fuchu-shi, Tokyo C-505 F-term (reference) 4D004 AA02 BA02 BA04 CA18 CB03 CB04 CC08 CC11 DA03 DA10 DA11 4H061 AA02 CC36 CC55 DD14 DD20 EE01 EE61 GG50 HH42 LL26

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 有機性廃棄物と活性炭を嫌気性発酵槽に
投入し、嫌気性条件下で処理することを特徴とする、有
機性廃棄物の処理方法。
1. A method for treating organic waste, comprising charging an organic waste and activated carbon into an anaerobic fermenter and treating it under anaerobic conditions.
【請求項2】 前記嫌気性発酵槽の前段に有機性廃棄物
貯留槽を配し、該槽内において、有機性廃棄物と活性炭
を予め混合する、請求項1に記載された有機性廃棄物の
処理方法。
2. The organic waste according to claim 1, wherein an organic waste storage tank is disposed in front of the anaerobic fermenter, and the organic waste and activated carbon are mixed in the tank in advance. Processing method.
【請求項3】 前記活性炭の添加量が、容量比で2%以
上である、請求項1又は2に記載された有機性廃棄物の
処理方法。
3. The method for treating organic waste according to claim 1, wherein the amount of the activated carbon added is 2% or more by volume.
【請求項4】 前記活性炭が籾殻燻炭である、請求項1
〜3の何れかに記載された有機性廃棄物の処理方法。
4. The activated carbon is rice husk smoke.
4. The method for treating organic waste according to any one of claims 1 to 3.
【請求項5】 前記嫌気性発酵槽の後段に、嫌気性条件
下での処理によって発生したガスを回収する工程及び/
又は、消化液を貯留する工程を含む、請求項1〜4の何
れかに記載された有機性廃棄物の処理方法。
5. A step of recovering a gas generated by a process under anaerobic conditions in a stage subsequent to the anaerobic fermenter, and / or
Alternatively, the method for treating organic waste according to any one of claims 1 to 4, further comprising a step of storing digestive juice.
【請求項6】 前記貯留された消化液を有機肥料化する
工程を含む、請求項5に記載された有機性廃棄物の処理
方法。
6. The method for treating organic waste according to claim 5, comprising a step of converting the stored digestive juice into an organic fertilizer.
JP24726199A 1999-09-01 1999-09-01 Organic waste treatment method Withdrawn JP2001069801A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102167627A (en) * 2010-12-21 2011-08-31 上海博琛生物科技有限公司 Method for additionally applying carbon dioxide air fertilizer to warm-house booth through agricultural organic waste fermentation
CN102424611A (en) * 2011-09-13 2012-04-25 商丘三利新能源有限公司 Carbon-based biogas fertilizer and production method thereof
CN104245635A (en) * 2012-04-26 2014-12-24 宝洁公司 Articles for in-home composting and method of composting
JP2015519281A (en) * 2012-04-26 2015-07-09 ザ プロクター アンド ギャンブルカンパニー Articles for composting at home

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102167627A (en) * 2010-12-21 2011-08-31 上海博琛生物科技有限公司 Method for additionally applying carbon dioxide air fertilizer to warm-house booth through agricultural organic waste fermentation
CN102424611A (en) * 2011-09-13 2012-04-25 商丘三利新能源有限公司 Carbon-based biogas fertilizer and production method thereof
CN104245635A (en) * 2012-04-26 2014-12-24 宝洁公司 Articles for in-home composting and method of composting
JP2015519281A (en) * 2012-04-26 2015-07-09 ザ プロクター アンド ギャンブルカンパニー Articles for composting at home
JP2015520100A (en) * 2012-04-26 2015-07-16 ザ プロクター アンド ギャンブルカンパニー Domestic composting articles and composting method

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