JP2000513387A - Conditioning shampoo composition - Google Patents

Abstract

  (57) [Summary] (a) about 0.05 to about 50% by weight of a polyhydrophilic anionic surfactant; and (b) about 0.05 to about 50 to about 50% by weight selected from the group consisting of cationic surfactants, cationic polymers, and mixtures thereof. Disclosed is a conditioning shampoo composition comprising about 20% by weight of a cationic conditioning agent, (c) about 0.2 to about 10% by weight of a betaine conditioning agent, and (d) an aqueous carrier.

Description

DETAILED DESCRIPTION OF THE INVENTION                   Conditioning shampoo composition                               Technical field   The present invention relates to a conditioning shampoo for washing and conditioning hair. Composition.                               Background of the Invention   Human hair becomes soiled by contact with the surrounding environment and sebum secreted from the scalp. It is. If your hair gets dirty, you will feel messy and look ugly. Therefore, it is necessary to shampoo hair frequently and regularly.   Shampooing hair removes dirt and sebum and cleans the hair. But, When you shampoo, your hair gets wet and tangled, and in general it becomes unwieldy I have. Once dry, the hair's natural oils and other conditioning and moisturizing ingredients Hair is dry, shabby, dull, or curly because hair is removed It is in a state. In addition, drying increases the level of charge on the hair, which Or cause the hair to be in a condition commonly referred to as "fluttering hair". You.   Various methods have been proposed to solve such post-shampooing problems. Was. These methods can be used for “leave as-is” products or “rinse-off” after shampooing. Products that apply a hair conditioner, such as Hair conditioning shampoo that tries both cleansing and conditioning Up to.   To give hair conditioning effect in cleaning shampoo base In addition, a wide variety of conditioning active substances have been proposed. Cationic con The conditioning substance is used when the hair dries, the overall condition it has. Effective for conditioning and shampooing with anti-static properties and anti-static properties However, it is also known that there is difficulty in compatibility with a detergent having a detergency. In addition, the cationic conditioning agent alone is satisfactory while the hair is wet. The conditioning effect cannot be exhibited.   Based on the above, compatible with detersive surfactants, and A cationic core that provides improved conditioning while the hair is wet To provide a conditioning shampoo composition comprising a conditioning substance There is a need.   None of the existing technologies can provide all the advantages and effects of the present invention.                               Summary of the Invention   The present invention     (A) about 0.05 to about 50% by weight of polyhydrophilic anionic A surfactant;     (B) cationic surfactants, cationic polymers and mixtures thereof From about 0.05 to about 20% by weight of a cationic conditioner selected from the group consisting of: Agent     (C) about 0.2 to about 10% by weight of a betaine conditioning agent;     (D) an aqueous carrier, And a conditioning shampoo composition comprising:   All components, aspects and advantages of the present invention will become apparent to one of ordinary skill in the art upon reading this specification. Should be clear.                           Detailed description of the invention   This specification discloses clay which specifically points out and expressly claims the subject matter of this invention. But the content of the invention can be better understood by the following description. Seem.   All percentages are by weight of the total composition, unless otherwise specified. When All ratios are by weight unless otherwise indicated. Referred to in this specification All percentages, ratios and concentrations of the ingredients are based on the actual amount of the ingredient, and Unless otherwise specified, solvents, fillers, or ingredients may not be compatible with commercially available products. It does not contain other substances that are associated with it.   The term "comprising" as used in this specification may affect the end result. This means that other steps or components that do not need to be added can be added. This term includes The terms “consisting of” and “consisting essentially of” are included.   All cited references are part of the references in this specification. References in the application No judgment is made as to whether the document can be used as prior art of the invention. I do not admit.Polyhydrophilic anionic surfactant   The present invention relates to a composition comprising from about 0.05 to about 50% by weight, preferably from about 0.1 to about 30%, More preferably, about 0.5 to about 20% of a polyhydrophilic anionic surfactant is included. You. Polyhydrophilic anionic surfactants useful in this specification have at least one It has two anionic hydrophilic groups. Of polyhydrophilic anionic surfactant The hydrophilic groups contained in one molecule may be the same or different. The hydrophilic group is Preferably, the carboxy sulfate, sulfonate and phosphate groups And more preferably at least one carboxy group, even more preferably Suitably there are at least two carboxy groups.   Although there is no theoretical basis, the polyhydrophilic anionic surfactants in this specification are The presence of an on-conditioning agent increases the amount of conditioning on the hair surface. Considered to be able to provide large area droplets that can capture and deliver Has been obtained. Droplets made from the polyhydrophilic anionic surfactants of this specification Is a conditioning agent that can be easily separated from the aqueous phase and therefore sent to the hair surface It is also believed that the amount can be increased.   Numerous examples of polyhydrophilic anionic surfactants include N-cocoyl-L-gluta , N-acyl-L-glutamates such as N-lauroyl-L-glutamate, Sodium lauryl-aminodiacetate, laurymino-dipropionate, N-lau Lyl-β-imino-dipropionate, N-acyl-L-aspartate, polyoxy Ethylene-lauryl sulfosuccinate, N-octadecyl sulfosuccinate dinate Lium, lauryl-sulfosuccinate disodium, lauryl-sulfosuccinate dia Ammonium, N- (1,2-dicarboxyethyl) -N-octadecylsulfosuccinic acid Tetra sodium, diamyl ester of sodium sulfosuccinate, sulfo Dihexyl ester of sodium succinate, dioctyl sodium sulfosuccinate Esters and 2-cocoalkyl N-carboxyethyl N-carboxyethoxy There is ethyl-imidazolinium-betaine.   Suitable polyhydrophilic anionic surfactants include, among others, those of the formulas (I) and (II) There are surfactants: Wherein R is alkyl having 12 to 18 carbon atoms, and In the formula, R ′ is a linear or branched alkyl or alkyl having 5 to 21 carbon atoms. And M1 and M2 are independently hydrogen, an alkali metal, an alkaline earth metal, Monium, alkyl or alkenyl having 1 to 22 carbon atoms, 1 to carbon atoms 18 alkyl or alkenyl substituted pyridinium or basic amino acids You. Suitable examples of formula (I) include lauroyl-N, N'-ethylenediaminetrivine Acid, myristoyl-N, N'-ethylenediaminetriacetic acid, cocoyl-N, N'-ethyl Of diaminetriacetic acid and oleoyl-N, N'-ethylenediaminetriacetic acid N-acyl-N such as sodium, triethanolamine and ammonium salts , N'-ethylenediaminetriacetic acid. A suitable example of formula (II) is , N-hexanoyl-N-carboxyethyl-β-alanine, N-octanoyl-N-ca Ruboxyethyl-β-alanine, N-decanoyl-N-carboxyethyl-β-alanine , N-lauroyl-N-carboxyethyl-β-alanine, N-tetradecanoyl-N-hi Droxyethyl-β-alanine, N-hexadecanoyl-N-carboxyethyl-β- Alanine, N-isostearoyl-N-carboxyethyl-β-alanine and N-O Leoyl-N-carboxyethyl-β-alanine.   Commercially available polyhydrophilic anionic surfactants suitable for this invention are Witc N-acyl-L-glutamate with trade name AMISOFT CT-12S supplied by o N-Cocoil-L-Glutamate with the trade name EMCOL4 400-1, Mitsubishi Chemical Lauroyl-glutamate with the trade name AMISOFT LS-11 supplied by ASPA Acyl aspartate with trade names RACK and AAS, N supplied by Nippon Yushi Sodium lauryl-aminodiacetate with the trade name ISSAN ANON LA, and Ha mpshire Chemical Corp. N-Acyl-N with the trade name ED3A, supplied by It is an N-ethylenediaminetriacetic acid derivative.Cationic conditioning agent   The invention includes from about 0.05 to about 20% by weight of a cationic conditioning agent. It is included. The cationic conditioning agent is a cationic surfactant, It is selected from the group consisting of cationic polymers and mixtures thereof.Cationic surfactant   Cationic surfactants useful in this specification are those known to those skilled in the art. You.   Among the cationic surfactants useful in this specification, those corresponding to general formula (I) There is: Where R¹, R^Two, R^ThreeAnd R^FourAt least one of the fatty acids having 8 to 30 carbon atoms Aliphatic groups, or aromatic, alkoxy, polyoxy, up to about 22 carbon atoms Silalkylene, alkylamide, hydroxyalkyl, allyl or aryl Selected from each group of alkylaryl, and the remaining R¹, R^Two, R^ThreeAnd R^FourIs charcoal Aliphatic groups having 1 to 22 atoms or aromatics having up to about 22 carbon atoms , Alkoxy, polyoxyalkylene, alkylamide, hydroxyalkyl, Independently selected from allyl or aryl groups; and X represents a halogen (eg, chloride, bromide), acetate, cytole Sulfate, lactate, glycolate, phosphate, nitrate, sulfonate , Sulfates, alkyl sulfates and alkyl-sulfonates A salt-forming anion selected from the group Aliphatic groups include carbon atoms, hydrogen atoms, In addition to tell bonds and other groups, other groups such as amino groups can be included. Was For example, a long chain aliphatic group having about 12 or more carbon atoms may be saturated or unsaturated. . R¹, R^Two, R^ThreeAnd R^FourIs preferably independently selected from C1 to about C22 alkyl It is. Countless examples of cationic surfactants useful in this invention include the following CT FA name: quaternium-8, quaternium-14, quaternium-18, quaternium-18 meth There are substances with sulfate, quaternium-24 and mixtures thereof.   Among the cationic surfactants of the general formula (I), preferred are at least one in the molecule. Containing two alkyl chains having 16 or more carbon atoms. This kind of good A myriad of examples of suitable cationic surfactants include, for example, INCROQUAT from Croda.  TMC-80, a buhenyl-trime available from Sanyo Chemical under the trade name ECONOL TM22 Tyl-ammonium-chloride; for example, CA-2350 from Nikko Chemicals Cetyl-trimethyl-ammonium chloride available under the trade name; C-alkyl-trimethyl-ammonium chloride, dialkyl (14-18) -dim Tyl-ammonium-chloride, ditallow-alkyl-dimethyl-ammonium-chloride Chloride, dihydrogenated tallow-alkyl-dimethyl-ammonium-chloride, disis Tearyl-dimethyl-ammonium chloride, dicetyl-dimethyl-ammonium Mu-chloride, di (buhenyl / arachidyl) -dimethyl-ammonium-chloride , Dibuhenyl-dimethyl-ammonium-chloride, stearyl-dimethyl-ben Jil-ammonium-chloride, stearyl-propylene glycol-phosphate Tri-dimethyl-ammonium-chloride, stearoyl-amidopropyl Dimethyl-benzyl-ammonium-chloride, stearoyl-amidopropyl Dimethyl- (myristyl acetate) -ammonium chloride and N- ( There are thearoyl-cholamino-formyl-methyl) -pyridinium-chloride.   Cationic surfactants substituted with hydrophilic groups are also suitable, in which case the substituent One or more aromatic groups at least one of which is present as a substituent or linking group in the base chain; Contains aromatic, ether, ester, amide, or amino moieties, and contains And R¹-R^FourIs at least one of alkoxy (preferably C1-C3 alkoxy) B), polyoxyalkylene (preferably C1-C3 polyoxyalkylene), From killamides, hydroxyalkyls, alkyl esters and combinations thereof It contains one or more selected hydrophilic moieties. Katio substituted with this hydrophilic group The non-ionic surfactant comprises 2 to about 10 non-ionic hydrophilic moieties located in the range described above. Minutes. Cationic surfactants substituted with suitable hydrophilic groups include And those of formulas (II) to (VIII) shown below: Wherein n is from 8 to about 28, x + y is from 2 to about 40, and Z is¹Is short-chain alkyl , Preferably C1-C3 alkyl, more preferably methyl or (CH_TwoCH_TwoO)_zH Where x + y + z is up to 60 and X forms the anion defined above. Salt Wherein m is 1-5, R^Five, R⁶And R⁷One or more are independently C1-C30 al Kills and the rest CH_TwoCH_TwoOH and R⁸, R⁹And R^TenOne or two One is independently C1-C30 alkyl and the rest is CH_TwoCH_TwoOH and X is A salt forming the anion described above,Wherein the chemical formulas (IV) and (V) are each independently Z^TwoIs alkyl, preferably C1-C3 Alkyl, more preferably methyl, and Z^ThreeIs short-chain hydroxyalkyl, preferably Suitably hydroxymethyl or hydroxyethyl, p and q are independently 2-4 An integer of preferably 2 to 3, more preferably 2;¹¹And R¹²Are replaced independently or Is an unsubstituted hydrocarbyl, preferably C12-C20 alkyl or alkenyl. And X is a salt forming an anion as defined above: Where R¹³Is a hydrocarbyl, preferably C1-C3 alkyl, more preferably methyl And Z^FourAnd Z^FiveAre independently short chain hydrocarbyls, preferably C2-C4 alkyl or Or alkenyl, more preferably ethyl, and a is from 2 to about 40, preferably from about 7 to X is about 30 and X is a salt forming the anion defined above: Where R¹⁴And R¹⁵Is independently C1-C3 alkyl, preferably methyl, Z⁶Is C12-C22 hydrocarbyl, alkyl-carboxy or alkylamide; And A is a protein, preferably collagen, keratin, milk protein, silk, large Bean protein, wheat protein or their hydrolysis products, and X is a salt forming an anion as defined above:Wherein b is 2 or 3;¹⁶And R¹⁷Is independently C1-C3 hydrocarbyls, Preferably it is methyl and X is a salt which forms an anion defined in the earth . Countless examples of cationic surfactants substituted with hydrophilic groups useful in this invention Some have the following CTFA names: quaternium-16, quatern ium-26, quaternium-27, quaternium-30, quaternium-33, quaternium-43, quat ernium-52, quaternium-53, quaternium-56, quaternium-60, quaternium-61, q uaternium-62, quaternium-70, quaternium-71, quaternium-72, quaternium-75 , Quaternium-76 hydrolyzed collagen, quaternium-77, quaternium-78, quater nium-79 hydrolyzed collagen, quaternium-79 hydrolyzed keratin, quaternium-7 9 Hydrolyzed milk protein, quaternium-79 hydrolyzed silk, quaternium-79 hydrolyzed Soy protein, quaternium-79 hydrolyzed wheat protein, quaternium-80, q uaternium-81, quaternium-82, quaternium-83, quaternium-84 and their It is a mixture.   Very suitable anionic surfactants having hydrophilic substituents include dialkyl alcohols. Mido-ethyl-hydroxyethylmonium salt, dialkylamido-ethyl-dimonium Salt, dialkiloyl-ethyl-hydroxyethylmonium salt, dialkiloyl- There are ethyl-dimonium salts and their mixtures. These are, for example, Commercially available under the trade name, i.e., VARISOFT 110 from Witco Chemical, VARIQUAT K1215 and 638, MACKPRO KLP, MACKPRO WLW, MACKPRO MLP from McIntyre , MACKPRO NSP, MACKPRO NLW, MACKPRO VNP, MACKPRO NLP, MACKPRO S LP, ETHOQUAD 18/25, ETHOQUAD 0 / 12PG, ETHOQUA DC / 25, ETHOQUAD S from Akzo / 25 and ETHODUOQUAD, DEHYQUAT SP from Henkel and AT from ICI USA LAS G265.   Salts of primary, secondary and tertiary aliphatic amines are also suitable cationic surfactants. is there. The alkyl groups of such amines have about 12 to about 22 carbon atoms and It may or may not be replaced. Particularly useful are amide-substituted tertiary aliphatic amines. It is a kind. Such amines useful in this specification include stearamide-propionate. Dimethylamine, stearamide-propyldiethylamine, stearamide-ethyl Diethylamine, stearamide-ethyldimethylamine, palmitamide-propyl Dimethylamine, palmitamide-propyldiethylamine, palmitamide-ethyl Diethylamine, buhenamide-propyldimethylamine, buhenamide-pro Pill diethylamine, buhenamide-ethyldiethylamine, buhenamide-ethyl Dimethylamine, arachidamide-propyldimethylamine, arachidamide- Propyldiethylamine, arachidamide-ethyldiethylamine, arachidole There are mido-ethyldimethylamine and diethylaminoethylstearamide. Dimethyl stearamine, dimethyl soiamine, soiamine, myristylamine, Tridecylamine, ethylstearylamine, N-tallowpropane-diamine, Toxic (using 5 moles of ethylene oxide)-stearylamine, dihydroxy Also useful are tilstearylamine and alkidylbuhenylamine. these Amines include L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, and fumaric acid. Acid, tartaric acid, citric acid, L-glutamic hydrogen chloride and mixtures thereof Any acid, more preferably used in combination with L-glutamic acid, lactic acid and citric acid Can be Cationic amine surfactant contained in those usable in the present invention Sexual agents are described in Nach, published June 23, 1981, one of the references of this specification. No. 4,275,055 to Tigal et al.   The cationic surfactant used in this specification includes a plurality of ammonium quaternary parts. There are also minute or amino moieties or mixtures thereof.Cationic polymer   The hair conditioning composition of the present invention further comprises a cationic conditioner. One or more cationic polymers can be included as a shocking agent. This light The term "polymer" as used in the textbook refers to one type of monomer or two types. Includes materials made by polymerizing more than one type of monomer.   Preferably, the cationic polymer is a water-soluble cationic polymer. "water A “soluble” cationic polymer is a meat that is sufficiently soluble in water and has a concentration of 0.1% at 25 ° C. Means a polymer that forms an almost transparent aqueous solution (water is distilled water or equivalent) in the eyes I do. Preferred polymers have a concentration of 0.5%, more preferably at a concentration of 1.0%. Dissolves in minutes to form a nearly clear aqueous solution.   The cationic polymers of this specification generally have a weight average molecular weight of about 5,000 or less. Above, usually more than about 10,000 and less than about 10 million. Preferably, the molecular weight is between about 100,000 and About 2 million. These cationic polymers generally have a quaternary ammonium moiety. Nitrogen-containing cationic, such as amino or cationic amino moieties and mixtures thereof Have a part.   The cationic charge density is preferably about 0.1 meq./gr. As described above, more preferably, about 1. 5meq./gr. As described above, even more preferably, 1.1 meq./gr. Above, still preferably 1 . 2meq./gr. That is all. The cationic charge density of the cationic polymer is determined by Kjelda It can be measured by the hl method. One skilled in the art will recognize that the charge density of You should be aware that it depends on the isoelectric point of the amino group. Charge density is planned It must be within the upper limits at the pH of the intended application.   As long as the water solubility criteria are met, Any anionic counterion can be used. Suitable counterions include halides (Cl, Br, I or F, preferably Cl, Br or I), sulfate and And methyl sulfate. This list is not so limited, so Others can also be used.   Nitrogen-containing cationic moieties are generally used for cationic hair conditioning. It is present as a substituent on only a small portion of all monomer units of the polymer. Accordingly And the cationic polymer is a quaternary ammonium or cationic amine-substituted Units and in this specification are referred to as spacer monomer units. Other non-cationic units such as copolymers and terpolymers. You. Such polymers are known in the art and are described in Estrin, Crosely, Hay. nes edited CTFA Cosmetic Ingredient Dictionary, 3rd edition (The Cosmet ic, Toiletry, and Fragrance Association, Inc., Washington, D.C., 1982) You can see it in various ways.   Suitable cationic polymers include, for example, acrylamide, methacrylamid , Alkyl and dialkyl-acrylamides, alkyl and dialkyl- Methacrylamides, alkyl-acrylates, alkyl-methacrylates, vinyl Water-soluble spacer monomers such as le-caprolactone and vinyl-pyrrolidone With vinyl monomers having a cationic amine or quaternary ammonium group There are copolymers. The alkyl and dialkyl substituted monomers are preferably C1- It has a C7 alkyl group, more preferably a C1-C3 alkyl group. Appropriate space Other monomers include vinyl-esters and vinyl-alcohols (polyvinyl alcohol). Made by hydrolyzing le-acetate), maleic anhydride, propylene-glyco And ethylene-glycol.   Cationic amines can be primary, secondary or primary depending on the particular chemical species and pH of the composition. Is one of tertiary amines. Generally, secondary and tertiary amines are preferred Yes, tertiary amines are particularly preferred.   Amine-substituted vinyl monomers can be polymerized in the form of an amine, and then Optionally, it can be converted to ammonium by a quaternization reaction. Amines are also Following limer formation, quaternization can be similarly performed. For example, a tertiary amine group is Can be quaternized by a reaction using a salt of the chemical formula R′X. Where R ' Is a short-chain alkyl, preferably C1-C7 alkyl, more preferably C1-C3 alkyl, X is an anion that forms a water-soluble salt with quaternary ammonium.   Suitable cationic amino and quaternary ammonium monomers include, for example, Alkylaminoalkyl-acrylate, dialkylaminoalkyl-methacrylate Monoalkylaminoalkyl-acrylate, monoalkylaminoalkyl M-methacrylate, trialkyl-methacryloxyalkyl-ammonium salt , Trialkyl-acryloxyalkyl-ammonium salts, diallyl (allyl)- Vinyl compounds substituted with quaternary ammonium salts, and - Vinyl-imidazolium, alkyl-vinyl-pyridinium, alkyl-vinyl-pi Such as pyridinium, imidazolium and quaternary pyrrolidone There are vinyl quaternary ammonium monomers having a cationic nitrogen-containing ring. This The alkyl portion of these monomers is preferably a lower alkyl such as C1-C3 alkyl. And more preferably C1 and C2 alkyl. Suitable for use in this specification. Amine-substituted vinyl monomers include dialkylaminoalkyl-acrylic , Dialkylaminoalkyl-methacrylate, dialkylaminoalkyl- Acrylamide and dialkylaminoalkyl-methacrylamide Here, the alkyl group is preferably a C1-C7 hydrocarbyl, more preferably a C1-C3 alkyl. It is Luquil.   The cationic polymers herein are amine- and / or quaternary ammonium. Monomer units derived from substituted monomers and / or compatible May include a mixture of precursor monomers.   Suitable cationic hair conditioning polymers include, for example, LUVI Under the brand name QUAT (for example, LUVIQUAT FC 370), BASF Wyandotte Corp. Commercially available from Parsippany, NJ, 1-vinyl-2-pyrro Copolymers of ridone and 1-vinyl-3-methylimidazolium salt (for example, Ride salt) (The Cosmetic, Toiletry, and Fragrance Association, "CTF A "in the industry is called Polyquaternium-16); trade name GAFQUAT (Eg, GAFQUAT 755N) at Gaf Corp. (Wayne, NJ, USA) 1-vinyl-2-pyrrolidone and dimethylaminoethyl-meth Acrylate copolymers (Polyquaternium-11 is referred to by the industry as CTFA) In this industry (CTFA), for example, Polyquaternium- 6 and Polyquaternium-7, dimethyl diallyl (allyl) ammonium- Chloride homopolymer, acrylamide and dimethyl diallyl (allyl) ann Cationic diallyl quaternary anions containing monium-chloride copolymers A monium-containing polymer; and U.S. Pat. The unsaturated carboxylic acids having 3 to 5 carbon atoms described in Aminoalkyl-esters of polymers and copolymers Mineral salts.   Suitable cationic polymers include, among others, Polyquater in the industry (CTFA). Methacrylamide acrylate, called nium-47, having the structural formula shown below Amphoteric consisting of pill-trimethylammonium chloride and methyl acrylate There are terpolymers. Examples of suitable commercial materials include Calgon Corp. N supplied by : N ': n "is MERQUAT 2001 with a ratio of 45:45:10.   Other cationic polymers that can be used include cationic cellulose derivatives and And polysaccharide polymers such as cationic starch derivatives.   Suitable cationic polysaccharide polymer materials for use herein include the following: There are school ceremonies: In the formula, A represents an anhydrous glucose residue such as starch or cellulose, and anhydroglucose residue. R is an alkylene-oxyalkylene, polyoxyalkylene, hydro Each group of xyalkylene or a combination thereof;¹, R^TwoAnd R^ThreeIs independent To alkyl, allyl (aryl), alkyl allyl (aryl), allyl (aryl) alkyl , Alkoxyalkyl or alkoxyaryl (aryl), each group Containing up to about 18 carbon atoms and the total number of carbon atoms in each cation moiety (ie, R¹, R^TwoAnd R^ThreeIs preferably about 20 or less; and X is an anionic counter ion as described above.   Cationic cellulose from Amerchol (Edison, NJ, USA) In the industry (CTFA) called Polyquarternium 10, trimethyl-an As a salt of hydroxyethyl-cellulose reacted with a monium-substituted epoxide, It can be used as JR and LR series polymers. Another kind Cationic cellulose is called Polyquarternium 24 in the industry (CTFA). Hydroxy reacted with lauryl-dimethyl-ammonium substituted epoxide There are polymeric quaternary ammonium salts of ethyl-cellulose. These substances are Amerchol under the trade name Polymer LM-200 (Edison, NJ, USA) Available from   Other cationic polymers that can be used include guar-hydroxypropyl tri Monium chloride (commercially available from Celanese as its Jaguar R series) Guar gum derivatives). Other substances include nitrogen Quaternary cellulose-esters (eg, one of the references in this specification). U.S. Pat. No. 3,962,418), and etherified cellulose. Starch (see, for example, US Pat. No. 3,958,581, one of the references of this specification) Has been described).Betaine conditioning agent   The present invention includes a solids content of about 0.2 to about 10%, preferably about 0.5 to about 5% by weight. Contains an in conditioning agent. Betaine Ko useful in this specification Conditioning agents include those of the general formulas (1) and (2), preferably (1): Where R¹Is COOM or CH (OH) CH_TwoSO_ThreeM, preferably COOM; R^TwoWhen R^ThreeIs independently hydrogen, alkyl of 1 to about 4 carbon atoms, CH_TwoCOOM, CH_TwoC H_TwoOH, CH_TwoCH_TwoOCH_TwoCH_TwoCOOM or (CH_TwoCH_TwoO)_xH (where x is an integer from about 1 to about 25), preferably methyl or ethyl;^FourIs hydrogen Or alkyl having 1 to about 4 carbon atoms, preferably hydrogen;^FiveIs linear or Branched, saturated or unsaturated alkyl having about 16 to about 30 carbon atoms, preferably Y is a straight-chain saturated or unsaturated alkyl having about 16 to about 22 carbon atoms; M is alkyl of 1 to about 4 carbon atoms, preferably methyl; m is 1 to about 7, preferably Is an integer from 1 to about 4; n is 1 or 0; M is hydrogen or an alkali metal; An alkaline earth metal or ammonium, and Where R⁶Is a saturated or unsaturated alkyl having about 16 to about 30 carbon atoms, Kenyl or hydroxy-alkyl, preferably saturated or unsaturated, having about 16 to about 22 alkyl; Y is a nitrogen, phosphorus or sulfur atom; R⁷Is an alkyl or monohydroxyalkyl group containing from 1 to about 4 carbon atoms P is 1 when Y is a sulfur atom and Y is a nitrogen or phosphorus atom 2 if R; R⁸Is an alkylene or monohydride containing 1 to 4 carbon atoms Z is carboxylate, sulfonate, sulfate , Phosphonate or phosphate; and M is as defined previously. is there.   Examples of betaine conditioning agents useful in this specification include cetyl dimethyl Rucarboxymethyl betaine, stearyl dimethyl carboxymethyl betaine, Isostearyl dimethyl carboxymethyl betaine, buenyl dimethylcarboxy Cimethylbetaine, oleyldimethylcarboxymethylbetaine, stearyl- Bis- (2-hydroxypropyl) carboxymethylbetaine, oleyldimethyl- γ-carboxypropyl betaine and stearyl dihydroxyethyl betaine Alkylbetaines such as cetylamidodimethylcarboxymethyl-betaine , Isostearylamidopropyl-betaine, isostearylamidodimethylca Ruboxymethyl-betaine and stearylamidodimethylcarboxypropyl- Amido-betaines such as betaine; stearylamide dimethyl carboxysul Amidosulfobetaines such as propylbetaine; stearyldimethylsulfo Sulfobetaines such as propylbetaine; stearyldimethylpropylsalt And amide sultaines. Used in this statement Commercially available substances suitable for cleaning include the brand name Rikabion A-700. Stearyl-dimethyl-betaine available from Nippon Chemical, Rikabion A-300 Oleyl-dimethyl-betaine, available from Shin Nippon Chemical under the trade name, and AnonAB  Stearyl-dihydroxy-betaine available from NOF under the trade name 202 There is.Aqueous carrier   The compositions of the present invention include an aqueous carrier. Carrier concentration and type Should be selected for compatibility with other ingredients and other properties desired for the product. You.   Carriers useful in this invention include water and lower alkyl-alcohols and polyhydric alcohols. There are aqueous solutions of alcohols. Lower alkyl-alcohols useful in this specification Include monohydric alcohols having 1 to 6 carbon atoms, more preferably ethanol And isopropanol. Polyhydric alcohols useful in this specification include propylene Len-glycol, hexylene-glycol, glycerin and propane-dio There is.   Preferably, the aqueous carrier is substantially water. Deionized water is preferably used. Ore Natural water containing physical cations can also be used depending on the properties of the product. General In addition, the composition of the present invention contains about 20 to about 95%, preferably about 30 to about 92%, And more preferably from about 50 to about 90% water.Additional detersive surfactant   The composition of the present invention further comprises a second anionic surfactant, an amphoteric surfactant. , Zwitterionic surfactants, nonionic surfactants and mixtures thereof. Additional detersive surfactants selected from the group may be included. Additional washing The concentration and type of cleansing surfactants may vary depending on compatibility with other ingredients and the product. The selection is made in consideration of other characteristics.   In a preferred embodiment, the additional detersive surfactant comprises a second anionic Surfactants are included, and more preferably, amphoteric surfactants are further included. Even better In a preferred embodiment, the additional detersive surfactant is an alkyl-sulphate Contains almost no surfactant.   As used herein, the term detersive surfactant refers to these surfactants. The surfactant is mainly an emulsifying surfactant, that is, it has an emulsifying effect and has a purifying ability. It is intended to distinguish low surfactants. Most surfactants are cleansable And has both emulsifying properties. It is an emulsifying surfactant If it has sufficient cleaning capacity to be used in the specification of It is not intended to be excluded from the compositions of this invention.   If additional detersive surfactant is present, this surfactant will The total concentration of the detersive surfactant and the multi-hydrophilic anionic surfactant is equal to the composition About 5% to about 75%, preferably about 8% to about 50%, and more preferably about 1% by weight of 0 to about 30%.Second anionic surfactant   Anionic surfactants useful in this specification include alkyl-sulfates and There are ruquil-ether-sulphate. Each of these substances has the following chemical formula Has                     ROSO_ThreeM                     RO (C_TwoH_FourO)_xSO_ThreeM Wherein R is alkyl or alkenyl having from about 8 to about 30 carbon atoms; x is from 1 to about 10 and M is hydrogen or ammonium or alkanol Cations such as monium (eg, triethanolammonium), monovalent metals Cations (eg, sodium and potassium) or polyvalent metal cations (eg, For example, magnesium and calcium). Preferably, M is an anionic surfactant The components need to be selected to be water-soluble. Anionic surfactant or field Surfactants have a Kraft temperature of about 15 ° C or less, preferably about 10 ° C or less, and more preferably. It must be suitably selected to be below about 0 ° C. Anionic surfactants are It is also preferred that it be soluble in the compositions herein.   Krafft temperature depends on the solubility of the ionic surfactant, the crystal lattice energy and the heat of hydration. Is the point at which the solubility becomes discontinuous as the temperature increases. Corresponds to a surge. Each surfactant has its own Kraft temperature ing. Kraft temperature for ionic surfactants is generally well recognized in the art. ing. For example, in 1988, one of the references of this specification, VCH Publis hers, Inc. Myers and Drew, "The Science of Surfactants" published by (New York) And Technology ”(ISBN 0-89573-399-0) at pages 82-85.   Alkyl-sulphate and alkyl-ether-sulphate odors mentioned above Preferably, R is about 12 to about 18 carbon atoms in both compounds . Alkyl-ether-sulphates usually have about 8 to about 24 carbon atoms. As a condensation product of monohydric alcohols and ethylene oxide. these Alcohols are derived from fats, such as coconut oil, coconut oil, tallow, etc. However, they can be synthesized. Lauryl obtained from coconut oil or coconut oil -Alcohols and straight-chain alcohols are preferred in this specification. This kind of Arco To a molar ratio of 1 to about 10, especially 3, with ethylene oxide. For example, molecular species having an average of 3 moles of ethylene oxide per mole of alcohol Is sulfated and neutralized.   Specific examples of alkyl-ether-sulfates that can be used in the present invention include: Coconut-alkyl-triethylene-glycol-ether-sulfate, taro C-alkyl-triethylene-glycol-ether-sulfate and tallow-a Sodium and ammonium salts of alkyl-hexaoxyethylene-sulfate is there. Highly preferred alkyl-ether-sulfates are from about 12 to about 16 Average alkyl chain length of carbon atoms and average degree of ethoxylation of 1 to about 4 moles of ethylene oxide A mixture of compounds having the formula: Mixtures of this type may have from 0 to about 20 % C12-13 compound, about 60 to about 100% by weight C14-15-16 compound, 0 to about 2% 0% by weight of a C17-18-19 compound, about 3 to about 30% by weight of a compound having a zero degree of ethoxylation, About 45 to about 90% by weight of a compound having a degree of ethoxylation of about 1 to about 4, about 10 to about 25% by weight Having a degree of ethoxylation of from about 4 to about 8 and from about 0.1 to about 15% by weight of ethoxy. Compounds having a degree of conversion greater than about 8 are also included.   Suitable anionic surfactants include other organic, sulfuric acid reaction products of the general formula: There are water-soluble salts of:                         R¹-SO_Three-M Where R¹Is a straight or branched chain, saturated or unsaturated, having 8 to 24 carbon atoms, preferably Suitably selected from the group consisting of about 10 to about 18 aliphatic hydrocarbon groups, and M is As described earlier in this section. Examples of this type of surfactant include Having from about 8 to about 24, preferably from about 12 to about 18, carbon atoms; Methane series hydrocarbons including o- and n-paraffins, bleaching and water content Sulfonating agents obtained by well-known sulfonation methods including_Three, (Sulfuric acid). Preferably an alkali metal and an Monium, sulfonated C10-18 n-paraffins.   Anionic surfactants also include oleic acids having about 10 to about 24 carbon atoms. There are fin-sulfonates. The term "olefin-sulfonate" is Describes that alpha-olefins can be sulfone with uncomplexed sulfur trioxide. Followed by hydrolysis of the sulfones formed in the reaction to give the corresponding hydroxy- Neutralizing the acid reaction mixture under conditions that make it an alkane sulfonate Used to mean a compound that can Sulfur trioxide can be liquid or gaseous Often, but not necessarily, when used as a liquid, , Liquid SO_TwoWhen diluted with chlorinated hydrocarbons or used in gaseous form Is air, nitrogen, gaseous SO_ThreeIt is diluted with. Olefin-sulfonates The derived α-olefin comprises about 12 to about 24 carbon atoms, preferably about 14 to about 24 carbon atoms. about Mono-olefins having 16 carbon atoms. Preferably they are linear Olefins. True alkene-sulfonates and a proportion of hydroxy-a In addition to lucane sulfonates, these olefin-sulfonates also have Conditions, ratio of reactants, characteristics of starting olefins and impurities of olefin raw materials and Other substances such as alkene-disulfonates due to side reactions during the sulfonation reaction In trace amounts. Specific α-olefin-sulfonate mixtures of the above type Is based on the Pf published on July 25, 1967, one of the references in this specification. This is described in more detail in U.S. Pat. No. 3,332,880 to Laumer and Kessler.   Other suitable anionic surfactants include the esterification of fatty acids with isethionic acid And a reaction product neutralized with sodium hydroxide. The fatty acids used here include: For example, fatty acids derived from coconut or coconut oil, or methyl- Uride's fatty acid (eg, coconut-derived fatty acid) amide sodium Or potassium salts. Other similar anionic surfactants are described in this specification. U.S. Pat.Nos. 2,486,921, 2,486,922 and 2,39, which are incorporated by reference. No. 6,278.   Another surfactant suitable for use in the shampoo compositions herein is β -Alkyloxy-alkane-sulfonates. The chemical formula of these compounds is As follows: Where R¹Is a straight chain alkyl group having about 6 to about 20 carbon atoms;^TwoIs about A lower alkyl group having from 1 to preferably about 3 carbon atoms, and M is as described earlier in this specification. Shampoo set of this specification Many other anionic surfactants suitable for use in compositions are described in this specification. H., part of the literature. C. Publishing Co. Published by McCutcheon "Emulsifiers and Detergents" described in 1989 Anual, and U.S. Patent No. 3,929,678 .   Another suitable anionic surfactant is an amino acid surfactant. this is , The basic chemical structure of an amino acid compound, ie, one of the natural amino acids Surfactant containing components.   Anionic surfactants suitable for use in these shampoo compositions include: laureth ammonium sulfate, laureth triethylamine sulfate, laureth sulfate trie Tanolamine, laureth monoethanolamine sulfate, laureth diethanol sulfate Amines, lauric-sodium monoglyceride sulfate, laureth sodium sulfate, laureth potassium sulfate, tridecyl-sodium benzenesulfonate, dodecyl- Sodium benzenesulfonate, N-cocoylalaninate, N-acyl-N-methyl Le-β-alaninate, sodium lauryl sarcosine, cocoyl-sarcosine , Lauroyl-taurate, lauroyl-lactylate, N-acyl-potassium-g Lysine, lauroamphohydroxy-propylsulfonate, cocoglyceride-sa Lufate, lauroyl-isethionate, lauroamphoacetate and its There is a mixture of these.Amphoteric surfactant   Amphoteric surfactants useful herein include zwitterionic surfactants in the art. There is something called an activator. Amphoteric surfactants useful in this specification include aliphatic There are derivatives of secondary and tertiary amines, where the aliphatic groups are straight-chain or branched. Aliphatic substituents containing alkyl branched and having from about 8 to about 18 carbon atoms And the amphoteric surfactant is an anionic water-soluble group, for example, Carboxy, sulfonate, sulfate, phosphate or phosphonate Contains. The amphoteric surfactants with excellent cleaning properties have only 14 carbon atoms Is known to have an alkyl chain consisting of 16 or more carbon atoms Those having an alkyl chain of usually have poor cleaning properties. But generated during synthesis Carbon sources because of the difficulty and cost of purifying these and other by-products Interfaces containing a small percentage of by-products with 16 or 18 alkyls It is common in the art to use a mixture of activators. However, if the number of carbon atoms is 1 Such by-products having 6 or 18 alkyls are contained in very low concentrations. , Usually less than about 0.2% by weight of the composition.   Amphoteric surfactants useful in this specification include aliphatic quaternary ammonium, phosphonic acid And sulfonium compounds, in which aliphatic The groups are straight or branched and one of the aliphatic substituents has about 8 to about 18 carbon atoms. And these compounds have an anionic water-soluble group, for example, carboxy, Contains sulfonates, sulfates, phosphates or phosphonates. The general formula of these compounds is as follows: Where R^TwoRepresents from about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxide moieties and Alkyl, alkenyl, or hydroxy-alkyl of 0 to about 1 glyceryl moiety R is selected from the group consisting of nitrogen, phosphorus and sulfur atoms;^Three Is an alkyl or monohydroxyalkyl group containing 1 to about 3 carbon atoms X is 1 when Y is a sulfur atom, and X is a nitrogen or phosphorus atom; Is 2; R^FourIs an alkylene or monohydroxy containing 1 to about 4 carbon atoms Sialkylene and Z is carboxylate, sulfonate, sulfate , Phosphate and phosphonate groups.   Examples of amphoteric surfactants include sultaines and amidosultaines. Amide Saltes including saltines include, for example, cocodimethylpropylsalt In, stearyl dimethylpropylsaltein, lauryl-bis- (2-hydroxy Ethyl) propylsaltein, and cocamidodimethylpropylsaltein , Stearylamidodimethylpropylsaltein, laurylamido-bis- (2-h There are amide sultaines such as droxyethyl) propyl sultaine. C8-C1 8Hydrocarbylamidopropylhydroxysultaines, especially C8-C14 hydride Locarbylamidopropylhydroxysultaines (eg, lauryl ami DOPROXY HYDROXYSALTEIN ) Are suitable. Other saltins are No. 3,950,417, which is one of the references in the specification of U.S. Pat.   Suitable amphoteric surfactants include, in addition, aminoalkanoates of the formula                     RNH (CH_Two)_nCO_TwoM And iminodialkanoates of the following chemical formula,                     RN [(CH_Two)_mCO_TwoM]_Two And mixtures thereof, wherein n and m are numbers from 1 to about 4, and R is C8-C 22 alkyl or alkenyl, and M is H, alkali metal, alkaline earth metal , Ammonium or alkanol ammonium.   Other suitable amphoteric surfactants include those represented by the following formula: Where R¹Is C8-C22, preferably C8-C16 alkyl or alkenyl;^Two And R^ThreeIndependently of hydrogen,     -CH_TwoCO_TwoM     -CH_TwoCH_TwoOH     -CH_TwoCH_TwoOCH_TwoCH_TwoCOOM     -(CH_TwoCH_TwoO)_mH (m is an integer from 1 to about 25) Selected from the group consisting of: R^FourIs hydrogen, -CH_TwoCH_TwoOH or       -CH_TwoCH_TwoOCH_TwoCH_TwoCOOM Z is CO_TwoM or CH_TwoCOOM; n is 2 or 3, preferably 2. M is an alkali metal (eg, lithium, sodium, potassium), Li-earth metals (beryllium, magnesium, calcium, strontium, barium Or a cation such as ammonium. This type of surfactant is imida It may be classified as a zoline-type surfactant, but not necessarily directly. Or indirectly, it is not necessary to be guided through an imidazoline intermediate. It is necessary. A suitable substance of this type is sold under the trade name MIRANOL and is A mixture of miscellaneous species,^TwoFor species that can have hydrogen in the It is understood that protonated and unprotonated ones can exist. ing. All such variations and species are encompassed by the above chemical formula. Is understood.   Examples of surfactants of the above formula are monocarboxylates and dicarboxylates. It is a kind. Examples of these substances include cocoamphocarboxypropionate, Cocoamphocarboxypropionic acid, cocoamphocarboxyglycinate ( Cocoamphoacetate) and cocoamphoacetate There is a   Commercially available amphoteric surfactants include Miranol C2M Conc. N.P., Miranol C2M Conc. O. P., Miranol C2M SF, Miranol CM Special (Milanor), Alkateric 2CIB (A lkari Chemicals), Amphoterge W-2 (Lonza), Monteric CDX-38, Monteri c CSH-32 (Mona Industries), Rewoteric AM-2C (Rewo Chemical Group) ) And Schercotic MS-2 (Scher Chemicals) There is   Betaine surfactant suitable for use in the conditioning composition; That is, zwitterionic surfactants include those represented by the following chemical formula: Where R¹Is COOM and CH (OH) CH_TwoSO_ThreeSelect from M; R^TwoIs lower alkyl Or hydroxyalkyl; R^ThreeIs lower alkyl or hydroxyalkyl And R^FourIs selected from hydrogen and lower alkyl;^FiveIs higher alkyl or al Y is lower alkyl, preferably methyl; m is 2-7, preferably Is an integer from 2 to 3; n is an integer 1 or 0; M is hydrogen or an alkali metal; The cations mentioned above, such as alkaline earth metals or ammonium. "Low The terms "alkyl" and "hydroxyalkyl" are, for example, methyl, ethyl. Propyl, isopropyl, hydroxypropyl, hydroxyethyl, etc. A chain or branched chain saturated aliphatic hydrocarbon group or substituted hydrocarbon group is meant. "High The term "primary alkyl or alkenyl" refers to, for example, lauryl, cetyl, Straight or branched having about 8 to about 20 carbon atoms, such as teaaryl, oleyl and the like The chain (ie, “higher alkyl”) and unsaturated (ie, “higher alkenyl”) ") Means an aliphatic hydrocarbon group. For "higher alkyl or alkenyl" The term includes one or more intermediate bonds, such as ether or polyether bonds, or One or more non-functionalities, such as hydroxyl or halogen groups, where the groups remain hydrophobic It is to be understood that mixtures of radicals containing the substituents are included.   Examples of surfactant betaines of the above formula wherein n is zero useful in this specification include: , Cocodimethylcarboxymethyl-betaine, lauryldimethylcarboxymethyl Le-betaine, lauryldimethyl-α-carboxyethyl-betaine, cetyl dimethy Rucarboxymethyl-betaine, lauryl-bis- (2-hydroxylethyl) -car Boxymethyl-betaine, stearyl-bis- (2-hydroxypropyl) -carbo Xymethyl-betaine, oleyldimethyl-γ-carboxypropyl-betaine, la Uryl-bis- (2-hydroxypropyl) -α-carboxyethyl-betaine There are alkyl betaines. A representative example of sulfobetaines is Coco Dimethi Rusulfopropyl-betaine, stearyldimethylsulfopropyl-betaine, la Uryl-bis- (2-hydroxyethyl) -sulfopropyl-betaine.   Amido-betaines and amides useful in these conditioning agent compositions Specific examples of ruhobetaines include cocamidodimethylcarboxymethyl-beta , Laurylamide dimethylcarboxymethyl-betaine, cetylamide dimethyl Rucarboxymethyl-betaine, laurylamide-bis- (2-hydroxylethyl) -Carboxymethyl-betaine, cocamido-bis- (2-hydroxylethyl) -carbo There are amidocarboxybetaines, such as xymethyl-betaine. Amido sulfo Representative betaines include cocamidodimethylsulfopropyl-betaine, Stearyl amide dimethyl sulfopropyl-betaine, lauryl amide-bis- (2 -Hydroxyethyl) -sulfopropyl-betaine.Nonionic surfactant   The shampoo compositions of the present invention can include a non-ionic surfactant. Non Ionic surfactants include aliphatic or alkylaromatic organic hydrophobic compounds These compounds formed by the condensation of a hydrophilic alkylene-oxide group with is there.   A myriad of examples suitable for use in these shampoo compositions include: Something like:   (1) Polyethylene-oxide condensates of alkylphenols, for example, Alkyl having an alkyl group of about 6 to about 20 carbon atoms in the chain or branch A reaction product of phenols and ethylene oxide. From about 10 to about 60 moles per mole of metal;   (2) The product obtained from the reaction between propylene oxide and ethylenediamine and ethylene oxide Derived from the condensation of len;   (3) linear or branched aliphatic alcohols having about 8 to about 18 carbon atoms Of ethylene oxide with ethylene oxide, for example per mole of coconut-alcohol Coconut-alcohol with about 10 to about 30 moles of ethylene oxide and ethylene oxide The coconut-alcohol fraction, a condensate of ren, contains about 10 to about 14 charcoals. Having an elementary atom;   (4) Chemical formula [R¹R^TwoR^ThreeN → O] long-chain tertiary amine-oxides, wherein R¹ Are alkyl, alkenyl or monohydroxy groups having from about 8 to about 18 carbon atoms. A dialkyl group, 0 to about 10 ethylene oxide moieties, and 0 to about 1 glycerol. A Ryl moiety is included and R^TwoAnd R^ThreeInclude methyl, ethyl, propyl, hydroxy About 1 to about 3 carbon atoms, such as And from 0 to about 1 hydroxy group;   (5) Long-chain tertiary phosphine-oxides of the formula [RR′R ”P → O], wherein R represents an alkyl group, alkenyl group or monohydroalkyl group having about 8 to about 18 carbon atoms. A xy-alkyl group, from 0 to about 10 ethylene oxide moieties, and from 0 to about 1 A seryl moiety is included, and R 'and R "each contain from about 1 to about 3 carbon atoms. An alkyl group or a monohydroxyalkyl group;   (6) long chain dialkyl sulfoxides, which contain from about 1 to about 3 carbon atoms. Including short chain alkyl groups (usually methyl) or hydroxyalkyl groups and one A long hydrophobic chain is included, wherein the long hydrophobic chain comprises from about 8 to about 20 carbon atoms. Alkyl, alkenyl, hydroxy-alkyl or keto-alkyl groups, 0- From about 10 ethylene oxide moieties and from 0 to about 1 glyceryl moieties. The   (7) alkyl-polysaccharide (APS) surfactants (eg, alkyl-polyglycols) Cids), examples of which are one of the references in this specification, which contain from about 6 to about 30 carbon atoms. Polysaccharides as hydrophobic groups having atoms and hydrophilic groups (eg, polyglycosides) No. 4,565,647, which discloses APS surfactants having And optionally a polyalkylene-oxide linking the hydrophobic and hydrophilic moieties Groups may be present, and the alkyl group (ie, the hydrophobic moiety) may be saturated or unsaturated. Sum, branched or unbranched, and substituents (eg, hydroxy or Suitable materials are alkyl-polyglycosides, with or without It is commercially available from Henkel, ICI America and Seppic;   (8) Chemical formula RO (CH_TwoCH_Two)_nPolyoxyethylene-alkyl-ether such as H And the chemical formula R (O) OCH_TwoCH (OH) CH_Two(OCH_TwoCH_Two)_nPolyester such as OH Tylene-glycol (PEG) glyceryl fatty acid esters (where n is 1 to about 200 Preferably about 20 to about 100, and R is an alkyl having about 8 to about 22 carbon atoms. ).Antidandruff agent   The compositions of the present invention may further include a safe and effective amount of an antidandruff agent. You. Antidandruff agents, when used, are typically present in an amount of about 0.1 to about 5% by weight of the composition, Preferably, it is used at a concentration of about 0.3 to about 5%.   Although there is no theoretical basis, the polyhydrophilic anionic surfactant of the present invention and a cation Drops created by the conditioned conditioning agent can cure the dandruff agent of this specification to the hair. It is also believed that they can be effectively captured and captured on the surface.   Pyrithione salts are useful herein. A suitable bilithion salt is 1-hid Roxy-2-pyridinethione is a heavy metal salt that includes zinc, tin, and cadmium. Mium, magnesium, aluminum and zirconium. Technical field The zinc salt of 1-hydroxy-2-pyridinethione, called zinc pyrithione in Suitable, and the particle size should be less than about 20 microns, from about 1 to about 10 microns. Is more preferred. Suitable commercially available pyrithione salts herein There is Zinc Pyrithione available from Olin.   Selenium sulfides are useful herein. The selenium sulfides in this specification include And a cyclic structure (Se having x and y being integers and x + y = 8)_xS_y ). Preferably, the particle size of the selenium sulfide is less than about 15μ, more preferably Is less than about 10μ. Particle size is measured using a laser light scattering device such as a Malvern 3600 instrument. Can be measured at the same time.   Sulfur and octopirox, salts and derivatives thereof are also useful herein.   The above mentioned dandruff agents can be used alone or in combination with other dandruff agents. You.Additional conditioning agent   The compositions of this invention may further comprise from about 0.05 to about 20%, preferably from about 0.1 to about 1%. 0%, and more preferably about 0.5% to about 10%, of a silicone compound, Selected from the group consisting of solids, oily compounds, nonionic polymers and mixtures thereof Additional conditioning agents may be included.Silicone compound   Additional conditioning agents used in this specification include silicone compounds. is there. The silicone compounds in this specification may be volatile, soluble or insoluble, or insoluble. There are volatile, soluble or insoluble silicone conditioning agents. "Soluble "Means that the silicone compound mixes with the carrier of the composition to form the same phase It means you can do it. "Insoluble" means that the silicone Form a discrete or discontinuous phase with the carrier, such as an emulsion or suspension. Means The silicone compounds of this specification include those known in the art, including emulsion polymerization. It can be made by any appropriate method known in the field. The silicone compound further comprises It can be present in the composition of the invention in the form of an emulsion. Note that this Emulsions are made by mechanical mixing or emulsion polymerization during the synthesis stage. Emulsification In polymerization, anionic surfactant, nonionic surfactant, cationic surfactant Surfactants selected from agents and their mixtures can be used if necessary You.   The viscosity of the silicone compound used in this specification is at 25 ° C., preferably about 1,00 0 to about 2,000,000 centistokes, more preferably about 10,000 to about 1,800,000 centimeters Stokes, even more preferably from about 100,000 to about 1,500,000 centistokes. You. Viscosity is one of the references in this specification, Dow Cornin of July 20, 1970. g Using a glass capillary viscometer described in Corporate Test Method CTM0004. Can be measured. High molecular weight silicone compounds can be made by emulsion polymerization. You. Suitable silicone fluids include polyalkyl-siloxanes, polyallyl (ary l) -siloxanes, polyalkylallyl (aryl) -siloxanes, ponoethers- There are siloxane-copolymers and mixtures thereof. Hair, conditioner Other non-volatile silicone compounds having aging characteristics can also be used.   The silicone compounds in this specification include polyalkyls having the following general formula (I): Or polyaryl-siloxanes: Wherein R is alkyl or aryl and x is from about 7 to about 8,000 It is an integer. “A” represents a group that blocks the end of the silicone chain. Siloxa An aliphatic group or allyl substituted on the (R) chain or at the end (A) of the siloxane chain ( aryl) groups are used to make the resulting silicone fluid, dispersible and irritating at room temperature. Non-toxic and not harmful when applied to hair and / or skin, this composition Compatible with other components of the product and is chemically stable under normal use and storage conditions. Any structure can be used as long as it can be deposited on the hair and conditioned the hair. Suitable A groups include hydroxy, methyl, methoxy, ethoxy, propoxy and There is aryloxy. The two R groups on the silicon atom may be the same or different groups. Represent. Preferably, the two R groups are the same group. Suitable R groups include methyl, ethyl Phenyl, propyl, phenyl, methylphenyl and phenylmethyl. Suitable Silicone compounds include polydimethyl-siloxane, polydiethyl-siloxane and And polymethylphenyl-siloxane. Polydime, also called dimethicone Tyl-siloxane is particularly preferred. Available polyalkyl-siloxanes Is, for example, polydimethyl-siloxane. These silicone compounds For example, General Electric Co. From the company's Viscasil R and SF96 series And Dow Corning's Dow Corning 200 series.   Polyalkylaryl-siloxane fluids that can be used include, for example, There are also trimethylphenyl-siloxanes. These siloxanes are, for example, G eneral Electric Co. From SF 1075 methylphenyl fluid or from Dow Corni Available from ng to 556 beauty grade fluid.   Particularly suitable for increasing the gloss of hair are those having a refractive index of 1.46 or more, especially 1. 52 or more polyallylated silyls such as polyphenylated polyethyl-silicone It is a corn compound. When using such a silicone compound having a high refractive index, To reduce the surface tension and increase the film forming ability of the substance, It must be mixed with a spreading agent such as a surfactant or silicone resin. These substances Is also called dimethicone or polyols.   Silicone compounds that can be used include, for example, There is methylsiloxane (but ethylene oxide or ethylene oxide and Mixtures of pyrene can also be used). The concentrations of ethylene oxide and propylene oxide It must be low enough so as not to interfere with the dispersion characteristics of the cone.   Other silicone compounds include amino-substituted substances. Suitable alkylamino Some substituted silicone compounds can be represented by the following structural formula (II): In the formula, R is methyl or OH, x and y are integers depending on the molecular weight, The child size is almost 5,000 to 10,000. This polymer is also called “Amodimethicone” Have been.   Suitable amino-substituted silicone fluids include those represented by Formula (III): There is: (R₁)_aG_3-a-Si-(-OSiG_Two)_n-(-OSiG_b(R₁)_2-b)_m-OSig_3-a(R₁)_a( III) Wherein G is selected from the group consisting of hydrogen, phenyl, OH, and C1-C8 alkyl; A is suitably methyl; a represents 0 or an integer from 1 to 3, preferably 0; Is 0 or 1, preferably 1; the sum n + m is a number from 1 to 2,000, preferably from 50 to 150 Yes; n is a number from 0 to 1,999, preferably 49 to 149; m is 1 to 2,000, preferably An integer from 1 to 10; R₁Is the chemical formula C_qH_2qL is a monovalent group, wherein q is 2 to 8 Is an integer and L is selected from the following group:           -N (R_Two) CH_Two-CH_Two-N (R_Two)_Two                     -N (R_Two)_Two                     -N (R_Two)_ThreeA^-                     -N (R_Two) CH_Two-CH_Two-NR_TwoH_TwoA^- Where R_TwoIs selected from the group consisting of hydrogen, phenyl, benzyl, and saturated hydrocarbon groups. And preferably an alkyl group containing from 1 to 20 carbon atoms;^-Is Harai Dion.   Particularly preferred amino-substituted silicones corresponding to formula (III) are: The following chemical formula (IV ) Is a polymer also called "trimethylsilyl-amodimethicone": Where n and m are selected according to the exact molecular weight of the desired compound.   Another amino-substituted silicone polymer that can be used is represented by the following chemical formula (V). Is:Where R^ThreeIs a monovalent hydrocarbon radical having 1 to 18 carbon atoms, preferably methyl Any alkyl or alkenyl group;^FourIs a hydrocarbon group, preferably C1-C18 An alkylene group, or C1-C18, and more preferably C1-C8 alkylene A xy group; Q^-Is a halide ion, preferably chloride; r is 2- S is a statistical average of 20-200, preferably a statistical average of 20; The average value is preferably 20 to 50. A suitable polymer of this type is "UCAR SILICON Available from Union Carbide under the name E ALE 56.   Literature disclosing suitable non-volatile dispersed silicone compounds include Geen's U.S. No. 2,826,551, U.S. Pat.No. 3,964,500 to Drakoff issued Jun. 22, 1976 No. 4,364,837 to Pader, and British Patent to Woolston (GB-A-849,433). And all of these patents are part of the references in this specification. Also, This is also one of the references, "Siliconization" distributed by Petrarch Systems in 1984. Compounds (which include a wide range of suitable silicone compounds (including but not limited to Is not)).   Another non-volatile dispersion silicone that is particularly useful is insoluble silicone rubber. It is. As used herein, the term "silicone rubber" is defined as having a viscosity at 25 ° C. Means a polyorganosiloxane material that is 1,000,000 centistokes or more . The silicone rubber described in this specification is compatible with the silicone compounds described above. Some parts overlap. This overlap restricts these substances. It is not intended to be. Silicone rubber, Petrarch and 1979 U.S. Pat. No. 4,152,416 issued to Spitzer et al. On May 1, and published in 1968. -Noll and Walter, published by Academic Press in York And other references, including "Chemistry and Teclmology of Silicones" Described. General Electric Silicone Rubber Product Sheets SE 30, S E33, SE54 and SE76 also describe silicone rubber. these All documents are part of the references in this specification. Mass of "silicone rubber" The molecular weight is about 200,000 or more, generally from about 200,000 to about 1,000,000. concrete Examples are polydimethyl-siloxane, poly (dimethyl-siloxane methylvinyl) -Siloxane) copolymer, poly (dimethyl-siloxane diphenyl-siloxane) Methylvinyl-siloxane) copolymers and mixtures thereof.   Also useful are silicone resins, which are highly crosslinked polymeric siloxanes. Frame The bridge can be combined with monofunctional or bifunctional or both silanes during the production of the silicone resin. This is done by adding trifunctional and tetrafunctional silanes. Well known in the art The degree of crosslinking required to obtain a silicone resin is Varies depending on the individual silane units incorporated into the resin. Generally, dry Sufficient concentration of tri- and tetra-functional siloxaes to form a stiff film Containing silicone monomer units (and therefore a sufficient degree of crosslinking) The quality is considered a silicone resin. The ratio of oxygen atoms to silicon atoms depends on the individual silicon It is an index of the degree of crosslinking of the carbon material. At least about 1.1 oxygen atoms per silicon atom The silicone material having is generally the silicone resin of this specification. oxygen: Preferably, the atomic ratio of silicon is at least about 1.2: 1.0. Silicone tree Silanes used in the production of fats include monomethyl-dimethyl-trimethyl- Monophenyl-diphenyl-methylphenyl-monovinyl and methyl vinyl There are le-chlorosilanes and tetrachlorosilane, the most commonly used These are methyl-substituted silanes. A suitable resin is GE SS4230 from General Electric. And SS4267. One commercially available silicone resin is Generally, they are supplied in dissolved form in low viscosity volatile or non-volatile silicone fluids. I have. As will be apparent to those skilled in the art, the silicone resin used in this specification And is added to the composition in dissolved form. Theoretical basis However, silicone resins enhance the deposition of other silicone compounds on the hair, resulting in high refraction. It is believed that the gloss of the hair can be improved together with the specific volume.   Other useful silicone resins include polymethylsilsequioxane, a CTFA There is a silicone resin powder, such as the substance given the name, which is Available commercially from corn as Tospearl.   The method for producing these silicone compounds is one of the references in this specification. , Encyclopedia of Polymer Sci published by John Wiley & Sons in 1989. ence and Engineering, Vol. 15, 2nd edition, pp. 204-308.   Silicone materials, especially silicone resins, are known to those skilled in the art as "MDTQ" nomenclature. And a well-known shorthand naming system. In this system , Silicone is composed of various siloxane monomers and units that make up silicone. Described by In short,     The symbol M is a mono (ie, 1) functional unit (CH_Three)_ThreeSiO_0.5Represents       D is a di (2) functional unit (CH_Three)_TwoStands for SiO,       T is a tri (3) functional unit (CH_Three) SiO_1.5Represents       Q is quadri-, ie, tetra (4) functional unit SiO_TwoRepresents Prime of unit symbol, for example, M ', D', T ', Q' is a substituent other than methyl And each must be specified specifically. Another substituent is vinyl And phenyls, amines, and hydroxys. Various types of silicone By subscript to the symbol indicating the total number of knits (or their average), or The molar ratio of various units is specifically shown as a ratio in combination with the molecular weight. Complete the description of silicone materials in the MDTQ system. Silicone resin T, Q, T 'and / or Q for D, D', M and / or M 'in Is relatively high, indicating a relatively high degree of crosslinking. . However, as mentioned earlier, the overall degree of crosslinking can be indicated by the ratio of oxygen to silicon. Can be.   The silicone resin used in this specification includes MQ, MT, MTQ, MDT And MDTQ resins are preferred. Therefore, suitable silicone substituents are methyl It is. Particularly suitable are those with an M: Q ratio of about 0.5: 1.0 to about 1.5: 1.0, An MQ resin having an average molecular weight of the fat of about 1,000 to about 10,000.   Commercially available silicone compounds that are very suitable in this specification include D- Dimethicone with a trade name of 130, Cetyl-Dimethicone with a trade name of DC2502 Stearyl-Dimethicone, trade name DC2503, DC1664 and DC1784 Emulsified polydimethyl-siloxanes with trade names, and DC2-2845 trade names Some alkyl graft copolymer silicone emulsions (these are All available from Dow Corning) and one of the references in this specification. Emulsifying weight available from Toshiba Silicone as described in GB Application No. 2,303,857 There is dimethiconol combined.High melting point compound   These compositions comprise fatty alcohols, fatty acids, fatty alcohol derivatives Of fatty acids, fatty acid derivatives, hydrocarbons, steroids and their mixtures And a high melting point compound having a melting point of about 25 ° C. or more selected from the above. theory For no good reason, these high-melting compounds cover the surface of hair, reduce friction, As a result, it is believed that the hair has a smooth feel and is easy to comb. This The compounds disclosed in this section of the specification of For example, some aliphatic alcohol derivatives are also classified as fatty acid derivatives. Those skilled in the art will recognize that similarities are possible. However, certain classifications are not There is no intention to constrain the thing and it is done for convenience of classification and naming. further Depending on the number and position of double bonds and the length and position of the branch, One skilled in the art will recognize that the melting point of certain compounds may be less than about 25 ° C. I know. We do not intend to include such low melting compounds in this section. Countless examples of high melting compounds are available at International Cosmetic Ingredient Dictiona ry, 5th edition, 1993, and CTFA Cosmetic Ingredient Handbook, 2nd edition , 1992, both of which are part of the references in this specification.   Aliphatic alcohols useful herein are about 14 to about 30, preferably about 16 It has from about 22 carbon atoms. These aliphatic alcohols are straight-chain or Or a branched-chain alcohol or a saturated or unsaturated alcohol. Aliphatic al Countless examples of coal include cetyl-alcohol, stearyl-alcohol, There are nil-alcohols and their mixtures.   Fatty acids useful herein are about 10 to about 30, preferably about 12 to about 22 And more preferably those having from about 16 to about 22 carbon atoms. these The fatty acids of may be linear or branched acids, or saturated or unsaturated acids. Also this Includes diacids, triacids and other polyacids as long as they meet the requirements of the specification. You. Salts of these fatty acids are also included in this specification. Countless examples of fatty acids include , Lauric acid, palmitic acid, stearic acid, buchenic acid, sebacic acid and the like There is a mixture of these.   Aliphatic alcohol and fatty acid derivatives useful in this specification include aliphatic Alcohol alkyl-ethers, alkoxy-aliphatic alcohols, alcohols Alkyl-ethers of xy-aliphatic alcohols, esthetics of aliphatic alcohols Esters, fatty acid esters of compounds having an esterifiable hydroxy group, hydroxy There are disubstituted fatty acids and mixtures thereof. Aliphatic alcohol derivatives and fats Countless examples of fatty acid derivatives include methyl-stearyl-ether; cetyl-alcohol. Are ethylene-glycol-ethers, and the number in the name is Ceteth series such as ceteth-1 to ceteth-45 indicating the number of len-glycol moieties Compounds, which are ethylene-glycol-ethers of steareth-alcohol , The number in the name indicates the number of ethylene-glycol moieties present compounds of the steareth series, such as h-1 to steareth-10; ceteareth-alcohol ( That is, aliphatic alcohols containing mainly cetyl-alcohol and stearyl-alcohol Mixture of alcohols), ethylene-glycol-ethers, the number in the name Indicates the number of ethylene-glycol moieties present ceteareth-1 to ceteareth -10; C1-C30 alkyl-ether of ceteth, steareth and ceteareth just mentioned Classes: Polyoxyethylene ethers of Buhenyl-alcohol; Ethyl stearee , Cetyl-stearate, cetyl-palmitate, stearyl-stearate , Myristyl-myristate, polyoxyethylene-cetyl-ether-steary G, polyoxyethylene-stearyl-ether-stearate, polyoxyethylene Len-lauryl-ether-stearate, ethylene glycol-monostearate , Polyoxyethylene-monostearate, polyoxyethylene-distearate , Propylene glycol-monostearate, propylene glycol-disteare Salt, trimethylolpropane-distearate, sorbitan-stearate, Liglyceryl-stearate, glyceryl-monostearate, glyceryl-dis There are tearates, glyceryl-tristearate and mixtures thereof.   Hydrocarbons useful herein include compounds having about 20 or more carbon atoms. There is.   Steroids useful herein include compounds such as cholesterol.   High melting point compounds consisting of a single compound of high purity are preferred. Pure Cetyl-Alcoe Pure fat selected from the group consisting of toluene, stearyl-alcohol and buenyl-alcohol Single compounds of fatty alcohols are very suitable. "Pure" refers to the compound It means that the purity is about 90% or more, preferably about 95% or more. These high A single compound of purity will make it easier for consumers to rinse their hair when rinsing the composition No.   Commercially available high melting compounds useful in this specification include Shin Nippon Chemical (Osaka) ) And the NAA series available from NOF (Tokyo). Cetyl-alcohol, stearyl-alcohol, buheni with the brand name Leeds 1-DOCOSANOL available from WAKO (Tokyo) Pure Buhenyl-Alcohol; NEO-FAT, Witco available from Akzo (Chicago, USA) Corp. (HYSTRENE, available from Dublin, Ohio, USA) Various fatty acids with the trade name DERMA available from Genoa (Ria, Genoa); Cholesterol with the brand name NIKKOL AGUASOME LA, available from Nikko There is.Oily compound   These compositions comprise a first oily compound, a second oily compound and mixtures thereof. It contains an oily compound having a melting point of about 25 ° C. selected from the above. In this specification Useful oily compounds may be volatile or non-volatile. No theory, oily The compound penetrates the hair and alters the hydroxy bonds of the hair, resulting in softness and softness of the hair. It is believed to provide softness. Oily compounds include those described in this specification. There are either the first oily compound or the second oily compound. First oil compound and second oil It is preferred to use a mixture of the compounds. The oil compounds in this section and described above It is different from the high melting point compound. Countless examples of oily compounds include Internationala l Cosmetic Ingredient Dictionary, 5th edition, 1993, and CTFA Cosmeti c Ingredient Handbook, 2nd edition, 1992, (both references in this specification Part).   First oily compound   The aliphatic alcohols useful herein are about 10 to about 30, preferably about 1 Those having 2 to about 22 and more preferably about 16 to about 22 carbon atoms is there. These aliphatic alcohols may be straight-chain or branched-chain alcohols, It may be a saturated or unsaturated alcohol, but is preferably an unsaturated alcohol. Countless examples of these compounds include oleyl-alcohol, palmitole-aqua Alcohol, isostearyl-alcohol, isocetyl-alcohol, undecano Octyl-dodecanol, octyl-decanol, octyl-alcohol, There are Prilic-alcohol, decyl-alcohol and lauryl-alcohol .   Fatty acids useful herein are about 10 to about 30, preferably about 12 to about 22. And more preferably those having from about 16 to about 22 carbon atoms. this These aliphatics may be linear or branched acids, or saturated or unsaturated acids. . Suitable fatty acids include, for example, oleic acid, linoleic acid, isostearin Acid, linolenic acid, ethyl-linolenic acid, ethyl-linolenic acid, arachidonic acid And ricinolinic acid.   Fatty acid derivatives and fatty alcohol derivatives specified in this specification include: For example, esters of aliphatic alcohols, alkoxy fatty acid alcohols, fats Alkyl-ethers of aliphatic alcohols, alkoxy alcohols There are alkyl-ethers and mixtures thereof. Fatty acid derivatives and fatty alcohols Numerous examples of methyl derivatives include, for example, methyl-linoleate, ethyl-linolenate Isopropyl-linoleate, isodecyl-oleate, isopropyl-oleate Eate, ethyl-oleate, octyldodecyl-oleate, oleyl-olee , Decyl-oleate, butyl-oleate, methyl-oleate, octyl Dodecyl-stearate, octyldodecyl-isostearate, octyldodeci Le-isopalmitate, octyl-isoperargonate, octyl-perargonate G, hexyl-isostearate, isopropyl-isostearate, isodecyl -Isononanoate, oleth-2, pentaerythritol-tetraoleate, pen Taerythritol-tetraisostearate, trimethylpropane-trioleate And trimethylpropane-triisostearate.   The first commercially available oily compounds useful in this specification include those from Shin Nippon Chemical Oleyl-alcohol, luxury alcohol with the trade name UNJECOL 90BHR available Pentaerythri with the trade names KAKPTI and KAKTTI, available from Chiba Thor-tetraisostearate and trimethylpropane-triisoste Allate, Pentaerys with the same trade name as the compound available from Nippon Chemical Litol-tetraoleate, a product called ENUJERUBU available from Shin Nippon Chemical Trimethylpropane-trioleate with name, SCHERCEMOL available from Scher  From various liquid esters and higher alcohols with the trade name of series Hexyl-isostearate and ZPIS products with HIS trade name available There is isopropyl-isostearate, which has a name.   Second oily compound   The second oily compounds useful herein include linear, cyclic and branched chain hydrocarbons. These may be saturated or unsaturated as long as the melting point is about 25 ° C. these Of hydrocarbons are from about 12 to about 40, preferably from about 12 to about 30, and more preferably Suitably it has about 12 to about 22 carbon atoms. C2-6 alkenyl, monomer Alkenyl such as polymers of the above, polymer hydrocarbons of monomers are also included in this specification include. These polymers may be linear or branched polymers. Linear polymers are relatively short in length and have the total number of carbon atoms mentioned above. Branch The chain length of the chain polymer is quite long. The number average molecular weight of this type of substance varies widely And usually about 500 or less, preferably about 200 to about 400, and more preferably about 300 to about 350. Various grades of mineral oil are also useful herein. Ore Oil is a liquid mixture of hydrocarbons obtained from petroleum. Of appropriate hydrocarbon material Specific examples include paraffin oil, mineral oil, dodecane, isododecane, hexadecane , Isohexadecane, eicosene, isoeicosene, tridecane, tetradecane , Polybutene, polyisobutene and mixtures thereof. Used in this statement Suitable for use are mineral oil, isododecane, isohexadecane, polyptene, Lysobutene and mixtures thereof.   Commercially available second oil compounds useful herein include Presperse (US PERMETHYL99A available from South Plainfield, NJ , PERMETHYL 101A, PERMETHYL 1082, Isoeicosen, Amoco INDOPOL H-100, available from Chemicals (Chicago, Illinois, USA) BENOL available from Witco, a copolymer of isobutene and n-butene Eoon Chemical Co., a mineral oil with a trade name (Houses, Texas, USA Mobil Chemic, an isoparaffin with the trade name ISOPAR available from Ton) al Co. Α-Olefin-oligomer with the trade name PURESYN 6 from M and M obil Chemical Co. With the brand name MOBIL ESTER P43 from There is propane-tricaprylate / tricaplate.Nonionic polymer   Nonionic polymers useful herein include cellulose derivatives, hydrophobically modified Cellulose derivatives, ethylene oxide polymers and ethylene oxide / propylene oxide There are polymers based on A suitable nonionic polymer is called BENECEL Methyl cellulose with trade name, hydroxyethyl with trade name NATROSOL -Cellulose, hydroxypropyl with the brand name KLUCEL-Cellulose, POLY Cellulose containing cetyl-hydroxyethyl-cellulose with the trade name SURF 67 Derivative. All of these cellulose derivatives were supplied by Herculus. Have been paid. Suitable nonionic polymers include, but are not limited to, CARBOWAX PEGs, POLYOX  Ethylene oxide / propylene oxide with trade names WASR and UCON FLUIDS There are polymers on which to base. All of these polymers were supplied by Amerchol. Have been paid.   Polyalkylene-glycols   These compounds are designed to give hair a soft, moisturizing feel It is especially useful for certain compositions. If necessary, polyalkylene-glycol Is usually from about 0.025 to about 1.5%, preferably from about 0.05 to about 1.5%, by concentration of the composition. 1%, and more preferably from about 0.1 to about 0.5%.   The general formula of the polyalkylene-glycol is: Wherein R is selected from H, methyl and mixtures thereof. If R is H , These substances are polymers of ethylene oxide, and these are polyethylene-oxygen Sa Also referred to as the id, polyoxyethylene and polyethylene-glycol. R is In the case of methyl, these substances are polymers of propylene oxide, Lipropylene-oxide, polyoxypropylene and polypropylene-glyco Also known as When R is methyl, the obtained polymer has various positional isomers. It is also known that the body can exist.   In the above structural formula, n is an average value of about 1,500 to about 25,000, preferably about 2,500 to about 20,0. 00, and more preferably from about 3,500 to about 15,000.   Polyethylene-glycols, polymers useful in this specification are those wherein R is H and n is PEG-2H with average value of about 2,000 (PEG-2M is obtained from Union Carbide PEG-5M with an average value of 000 (PEG-5M is available from Union Carbide) R is H and n has an average value of about 7,000. PEG-7M (PEG-7M is a Polyox WSR available from Union Carbide) And R is H and n has an average value of about 14,000 (PEG-14M is there.   Other useful polymers include polypropylene-glycol and polyethylene-glycol. There is a mixture of coal / polypropylene-glycol.Additional ingredients   The compositions of the present invention can be selected from a variety of options depending on the desired properties of the final product by those skilled in the art. Additional components may be included. Additional components include, for example, polyvalent metal cations, There are ginseng inhibitors, ethoxy-glucose derivatives and other additional ingredients.Polyvalent metal cation   Suitable polyvalent metal cations include divalent and trivalent metals, with divalent metals being preferred. You. Typical metal cations include magnesium, calcium, zinc and copper Alkaline earth metals and trivalent metals such as aluminum and iron. Calcium and ma Gnesium is preferred.   Polyvalent metal cations can be added as inorganic salts, organic salts or hydroxides . The polyvalent metal cation is added as a salt with the anionic surfactant described above. You can also.   The polyvalent metal cation is preferably added as an inorganic or organic salt. Inorganic salt Include chloride, bromide, iodide, nitrate or sulfate; chloride or sulfate Is more preferred. Organic salts include L-glutamate, lactate, malate, sac Sinate, acetate, fumarate, L-glutamate, and tartar There is a   Anionic surfactant is used as a method for incorporating a polyvalent metal cation into the composition of this specification. When polyvalent salts of a surfactant are used, only a part of the anionic surfactant is used in a polyvalent form. It is important to note that the remaining anionic surfactant must be added in monovalent form. It will be clear to the trader.   The hardness of the conditioning shampoo composition is ethylene-diamine-tetra It can be measured by a standard method such as an acetic acid (EDTA) titration method. ED In the TA titration method, the composition contains a dye or other coloring substance, and the color change If it interferes with sensing, the hardness is measured with a composition that is free of dyes, etc. Need to beSettling inhibitor   In particular, when containing high viscosity and / or large particle size silicone compounds In this case, a suspending agent is a suitable additional component. The suspending agent, if present, It is dispersed in the product. The suspending agent is generally present at about 0% by weight of the composition. 0.1 to about 10%, and more usually about 0.3 to about 5.0%.   Suitable suspending agents include ethylene-glycol-stearates (mono- and Acyl derivatives such as di-stearate), alkyl (C16-C22) dimethyl- Amine-oxides (eg, stearyl-dimethyl-amine-oxide) There are any amine-oxides, and mixtures thereof. For shampoo compositions In use, these suitable suspending agents are present in the composition in crystalline form. I do. These suspending agents are described in U.S. Pat. No. 4,741,855.   Suitable suspending agents include, other than preferably, about 16 to about 22, more preferably about 1 to about 22. There are alkanol-amides of fatty acids having 6 to about 18 carbon atoms. That Preferred examples include stearic-monoethanolamide, coco monoethanolamide. , Stearic-diethanolamide, stearic-monoisopropanol There are amide and stearic-monoethanolamide-stearate.   Suitable suspending agents include N, N-dihydrocarbyl-amide-benzoic acid and And their soluble salts (eg, Na and K salts), especially the N, N-di- (Hydrogenated) C16, C18, and tallow-amide-benzoic acids. These are Step an Co. (Northfield, Illinois, USA).   Other suitable suspending agents include xanthan gum. Silicone-containing chassis The use of xanthan gum as a suspending agent in a pump composition, for example, It is described in U.S. Pat. No. 4,788,006, one of the references of this specification. The combination of long-chain acyl derivatives and xanthan rubber is also a precipitant in shampoo compositions. It can be used as an anti-adhesion agent. This type of combination is one of the references in this specification. No. 4,704,272.   Other suitable suspending agents include carboxyvinyl-polymers. these Preferred among the polymers are U.S. Pat. No. 8,053, cross-linked by using allyl sucrose It is a copolymer of crylic acid. Examples of these polymers include carbomer, These are allyl-ether of pentaerythritol, allyl of sucrose Crosslinking with (allyl) -ether or allyl-ether of propylene Acrylic acid homopolymer. Neutralizers are required, for example, amino- Cyl-propanol, triethanol-amine or sodium hydroxide are examples is there.   Suitable suspending agents that can be used in the composition include, but are not limited to, hydroxyethyl- Cellulose, hydroxymethyl-cellulose, hydroxypropyl-cellulose Water-soluble or water-soluble colloidal polymers, like any cellulose-ethers And guar gum, polyvinyl-alcohol, polyvinyl-pyrrolidone, hydroxy Like substances such as cypropyl-guar gum, starch and starch derivatives, Some can give gel-like viscosity.Ethoxy-glucose derivative   To increase the viscosity of the composition and to stabilize the composition phase at high and low temperatures Particularly preferred additional components are ethoxy-glucose derivatives. Ethoxy-glucose Derivatives may, if desired, be present in an amount of about 0.1 to about 10% by weight of the composition, and more usually Is added at a concentration of about 0.3 to about 5.0%.   Suitable ethoxy-glucose derivatives include methyl gluceth-10, methyl gluceth -20, PEG-120 methylglucose-dioleate, PPG-10 methylglucose-ate There are Teru and PPG-20 methyl glucose-ether. Very suitable in this specification Another commercially available substance is methyl gluceth, which has the trade name GLUCAM E-10. -10, PEG-120 methylglucose-diole with the trade name Glucamate DOE-120 Eat, PPG-10 with the trade name GLUCAM P-10 And GLUCAM P-20 with PPG-20 methyl glucose-ether , All of which are available from Amerchol.Other additional ingredients   A wide variety of other additional ingredients can be added to the compositions of the present invention. these Has hydrolyzed collagen available under the trade name Peptein 2000 from Hormel. Emix-d, available from Eisai, other conditioning agents, such as There is a vitamin E, panthenol available from Roche, paten available from Roche Nthenyl-ethyl-ether, hydrolyzed keratin, proteins, plant extracts and Nutrients; emulsifying surfactants for dispersing water-insoluble components in the carrier; Polymer, cationic fixing polymer, anionic fixing polymer, nonionic Hair sticking polymers such as sticking polymers and silicone graft copolymers ー; Polystyryl stilbenes, triazine stilbenes, hydroxycoumarin , Aminocoumarins, triazoles, pyrazolines, oxazoles, pyre Brighteners such as benzenes, porphyrins and imidazoles; benzyl-alcohol , Methyl-paraben, propyl-paraben and imidazolidinyl-urea Preservatives: citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide PH adjusters such as sodium and sodium carbonate; potassium acetate and sodium chloride Common salts, such as chromium; a brightener such as FD & C or D & C dye; hydrogen peroxide; Hair oxidizing (bleaching) agents such as perborates and persulfates; thioglycolates Which hair reducing agents; fragrances; metals such as ethylenediamine-tetraacetic acid-disodium On-blocking agents; UV and infrared shielding and absorption, such as octyl-salicylate There are agents. Optional components of this kind generally comprise, individually, by weight of the composition, about 0.01. To about 10.0%, preferably from about 0.05 to about 5.0%.                                 Example   The following examples further describe and demonstrate embodiments within the scope of the present invention. You. These examples are illustrative and depart from the spirit and scope of the invention. Many modifications can be made without the You shouldn't. Ingredients are identified by chemical name and CTFA name or otherwise below Stipulated. Definition ^* 1 Amisoft CT-12S obtained from Ajinomoto^* 2 Emcol 4400-1 obtained from witco^* 3 Asparak obtained from Mitsubishi^* 4 Nisan Anon LA obtained from Nippon Yushi^* 5 Tego Betaine F obtained from TH Goldschmidt^* 6 Econo TM22 obtained from Sanyo Chemical^* 7 Varisoft 110 obtained from witco^* 8 UCare Polymer JR400 obtained from Amerchol^* 9 Quatrisoft Polymer LM-200 obtained from Amerchol^* Merquat 2001 obtained from 10 Calgon^* 11 Particle size about 200nm obtained from Toshiba Silicone         1,000,000 cp dimethiconol emulsion^* 12 About 200nm particle size obtained from Toshiba Silicone         500,000cp dimethiconol emulsion^* 13 SE-76 dimethicone rubber obtained from General Electric Silicone         40 (rubber) / 60 (fluid) weight ratio blend^* 14 Particle size of about 300nm obtained from DowCorning         60,000csk Polydimethyl-siloxane emulsion (DC1664)^* 15 Silicone alkyl grafts obtained from Dow Corning         Copolymer DC2502^* 16 Alkyl graft copolymer from Dow Corning         Silicone emulsion DC2-2845^* 17 GlucaJnate DOE-120 obtained from Amerchol^* 18 Rikabion A-700 obtained from Shin Nippon Chemical^* 19 Rikabion A-300 obtained from Shin Nippon Chemical^* 20 Anon AB 202 obtained from NOF^* 21 GLUCAM E-20 obtained from Amerchol^* 22 Available from Olin^* 23 Peptein 2000 obtained from Hormel^* 24 Emix-d obtained from Roche^* 25 Available from Roche^* 26 Available from RochePreparation method   The shampoo compositions of Examples 1 to 16 shown above are well known in the art. It can be made by known ordinary methods. The appropriate method is described below I do.   The polymer and surfactant are dispersed in water to form a uniform mixture. This mixture Except for silicone emulsions (if necessary), flavors and salts, Add the ingredients and stir the resulting mixture. If a silicone blend is present Silicone emulsions can be used as silicone blends, Made with surfactant and some water. Cool the resulting mixture through a heat exchanger And then add the silicone emulsion, flavor and salt. The resulting composition Put things in a bottle to make a hair shampoo composition. On the one hand, water and surfactant And other solids that need to be melted for quick mixing into the shampoo For example, they can be mixed together at an elevated temperature of about 70 ° C. or higher. Additional ingredients It can be added to this hot premix or the cooled premix. this Heat the ingredients and mix them thoroughly at the elevated temperature, then add the high shear mill and heat Cool to room temperature through exchanger. If necessary, emulsify in concentrated surfactant at room temperature The silicone obtained is added to the cooling mixture. Examples from 1 to 16 include many There are advantages. For example, the feeling of squeaky hair during or after rinsing Improved bulk, smoothness and combability, plus dry conditioning The fruits are improving as a whole.   The examples and embodiments described in this specification are for illustrative purposes only, and Various modifications will occur to those skilled in the art without departing from the spirit and scope of the invention. It will be appreciated that morphology is suggested.

────────────────────────────────────────────────── ─── Continuation of front page    (81) Designated countries EP (AT, BE, CH, DE, DK, ES, FI, FR, GB, GR, IE, IT, L U, MC, NL, PT, SE), OA (BF, BJ, CF) , CG, CI, CM, GA, GN, ML, MR, NE, SN, TD, TG), AP (GH, KE, LS, MW, S D, SZ, UG, ZW), EA (AM, AZ, BY, KG) , KZ, MD, RU, TJ, TM), AL, AM, AT , AU, AZ, BA, BB, BG, BR, BY, CA, CH, CN, CU, CZ, DE, DK, EE, ES, F I, GB, GE, GH, HU, ID, IL, IS, JP , KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MD, MG, MK, MN, M W, MX, NO, NZ, PL, PT, RO, RU, SD , SE, SG, SI, SK, SL, TJ, TM, TR, TT, UA, UG, US, UZ, VN, YU, ZW

Claims (1)

[Claims] 1. A conditioning shampoo composition comprising: (a) about 0.05 to about 50% by weight of a polyhydrophilic anionic surfactant; and (b) a cationic surfactant, a cationic polymer, and mixtures thereof. A conditioning shampoo composition comprising: about 0.05 to about 20% by weight of a cationic conditioning agent selected from: (c) about 0.2 to about 10% by weight of a betaine conditioning agent; and (d) an aqueous carrier. object. 2. The conditioning shampoo composition according to claim 1, wherein the polyhydrophilic anionic surfactant contains at least one carboxy group in a molecule. 3. A conditioning shampoo composition according to claim 1, further comprising an additional detersive surfactant. 4. 4. The conditioning shampoo composition of claim 3, wherein the additional detersive surfactant comprises a second anionic surfactant and an amphoteric surfactant, and wherein the polyhydrophilic surfactant comprises A conditioning shampoo composition wherein the sum of the anionic surfactant and said detersive surfactant is from about 5% to about 75% by weight of the composition. 5. A conditioning shampoo composition according to claim 4, wherein the composition is substantially free of alkyl-sulfate surfactants. 6. A conditioning shampoo composition according to claim 1, wherein said cationic surfactant comprises at least one alkyl chain having at least 16 carbon atoms in the molecule. 7. A conditioning shampoo composition according to claim 1, wherein said cationic polymer is selected from Polyquaternium 10, Polyquaternium 24 and mixtures thereof. 8. The conditioning shampoo composition according to claim 1, wherein the betaine conditioning agent is selected from general formulas (1) and (2) and a mixture thereof: Wherein R ¹ is COOM or CH (OH) CH ₂ SO ₃ M; R ² and R ³ are independently hydrogen, alkyl having 1 to about 4 carbon atoms, CH ₂ COOM, CH ₂ CH ₂ OH _{, C H 2 CH 2 OCH 2} CH 2 COOM or _{(CH 2 CH 2 O) x} H ( wherein, X is 1 to about 25 integer) be; R ⁴ is hydrogen or from 1 to about 4 carbon atoms R ⁵ is straight or branched chain, saturated or unsaturated alkyl having about 16 to about 30 carbon atoms; Y is alkyl having 1 to about 4 carbon atoms; Is an integer from 1 to about 7; n is 1 or 0; and M is hydrogen or an alkali metal, alkaline earth metal or ammonium, and Wherein, R ⁶ is a saturated or unsaturated carbon atoms from about 16 to about 30 alkyl, alkenyl or hydroxy - an alkyl; Y is an atom of nitrogen, phosphorus or sulfur; R ⁷ is from 1 to about an alkyl group or monohydroxyalkyl group containing 1 to 4 carbon atoms; p is Y is 1 if a sulfur atom, Y is 2 when a nitrogen or phosphorus atom; R ⁸ is 1 Z is carboxylate, sulfonate, sulfate, phosphonate or phosphate; and M is as previously defined. 9. 9. The conditioning shampoo composition according to claim 8, wherein the betaine conditioning agent has the general formula (1). 10. A conditioning shampoo composition according to claim 1, further comprising about 0.1 to about 5% by weight of an antidandruff agent. 11. The conditioning shampoo composition according to any one of claims 1 to 10, further comprising a silicone compound, a high melting point compound, an oily compound, a nonionic polymer, and a mixture thereof. A conditioning shampoo composition comprising about 0.05 to about 20% by weight of an additional conditioning agent selected from: