JP2000314079A - Cloth using inorganic coating material - Google Patents
Cloth using inorganic coating materialInfo
- Publication number
- JP2000314079A JP2000314079A JP11120612A JP12061299A JP2000314079A JP 2000314079 A JP2000314079 A JP 2000314079A JP 11120612 A JP11120612 A JP 11120612A JP 12061299 A JP12061299 A JP 12061299A JP 2000314079 A JP2000314079 A JP 2000314079A
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- inorganic paint
- flame
- yarn
- cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 123
- 238000000576 coating method Methods 0.000 title claims abstract description 26
- 239000011248 coating agent Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title abstract description 31
- 238000011282 treatment Methods 0.000 claims abstract description 33
- 238000005507 spraying Methods 0.000 claims abstract description 26
- 238000007639 printing Methods 0.000 claims abstract description 20
- 238000005470 impregnation Methods 0.000 claims abstract description 8
- 239000003973 paint Substances 0.000 claims description 80
- 230000001699 photocatalysis Effects 0.000 claims description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims description 17
- 238000010276 construction Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims 1
- 230000003000 nontoxic effect Effects 0.000 abstract description 16
- 238000003763 carbonization Methods 0.000 abstract description 8
- 238000002485 combustion reaction Methods 0.000 abstract description 7
- 238000010304 firing Methods 0.000 abstract 2
- 231100000614 poison Toxicity 0.000 abstract 1
- 230000007096 poisonous effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 51
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 27
- 239000000835 fiber Substances 0.000 description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 25
- 239000003063 flame retardant Substances 0.000 description 24
- 238000010586 diagram Methods 0.000 description 17
- 231100000252 nontoxic Toxicity 0.000 description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 14
- 239000000377 silicon dioxide Substances 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 12
- 239000004408 titanium dioxide Substances 0.000 description 12
- 230000005611 electricity Effects 0.000 description 10
- 230000003068 static effect Effects 0.000 description 9
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 description 8
- 239000011259 mixed solution Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 8
- 229910000165 zinc phosphate Inorganic materials 0.000 description 8
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 6
- 239000004115 Sodium Silicate Substances 0.000 description 6
- 239000003242 anti bacterial agent Substances 0.000 description 6
- 229910001431 copper ion Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000007654 immersion Methods 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 229910052911 sodium silicate Inorganic materials 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 4
- -1 aircraft Substances 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- 102100032392 Circadian-associated transcriptional repressor Human genes 0.000 description 3
- 101710130150 Circadian-associated transcriptional repressor Proteins 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000009986 fabric formation Methods 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000011491 glass wool Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 239000011490 mineral wool Substances 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 238000013032 photocatalytic reaction Methods 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241000283080 Proboscidea <mammal> Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、(無毒性完全)無機
質(水性セラミック)塗料を含浸・塗装して得られる布地に関
する。この布地の利用分野は、室内壁面、折半屋根裏打
材、航空機・車輛・交通輸送・船舶・エレヘ゛ータ等壁面材、
室内壁面材、防炎襖・戸・障子、ホール用床材等の壁材
(床材)関係、また間仕切り芯材関係、ク゛ラスウール・ロックウール
・アスヘ゛スト代替材、スレート補強材、硅酸カルシウム板補強材等の芯
材関係、ハ゜イフ゜シャフト充填物、スハ゜ッタリンク゛保護シート、防炎シート、
畳表裏打材、ヘ゛ット・マット裏打材、座布団、ソファー、クッション等
の敷物関係、家庭・レストラン・ホール・劇場・公的建物・工場
等の各種椅子、航空機・車輛・交通輸送・船舶等用の座
席、チャイルト゛シート、歯科治療台等の椅子関係、又はカーテン、
布製内装材・フィルター、防炎安全服、防炎手袋、防炎頭巾
等の衣服及び身回品関係、その他防炎機能材料、難燃機
能材料、光触媒機能材料、抗菌機能材料、蓄光機能材
料、等の各種材料関係など広い範囲に亘る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric obtained by impregnating and painting a (non-toxic, complete) inorganic (aqueous ceramic) paint. Areas of application of this fabric include indoor wall surfaces, folded roof lining materials, wall materials such as aircraft, vehicles, transportation, ships, and elephants,
Wall materials (floor materials) such as indoor wall materials, flameproof sliding doors / doors / shojis, floor materials for halls, etc., partition core materials, substitutes for glass wool, rock wool, and asbestos, slate reinforcing materials, calcium silicate plate reinforcement Core materials, high shaft fillings, shutter links, protective sheets, flameproof sheets, etc.
Tat-mat backing materials, Het / mat backing materials, cushions, rugs such as sofas and cushions, various chairs at home, restaurants, halls, theaters, public buildings, factories, etc., seats for aircraft, vehicles, transportation, ships, etc. , Child seats, chairs such as dental treatment tables, or curtains,
Cloth interior materials and filters, flameproof safety clothing, flameproof gloves, flameproof hoods and other clothing and personal accessories, other flameproof material, flame retardant material, photocatalytic material, antibacterial material, phosphorescent material, Etc. over a wide range such as various material relations.
【0002】[0002]
【従来の技術】従来、火災時に発生する有毒カ゛ス発生防
止、火災時の燃焼温度の抑制化、又は延焼防止等を目的
に自己消化性、難燃性の布地がある。またこの難燃性を
更に発展させた防炎性の布地が散見されている。しか
し、十分な成果をあげていないこと、及び炭化特性を備
えておらず、いわゆる形状保持特性を備えていないこ
と、等の課題が考えられる。2. Description of the Related Art Conventionally, there are self-extinguishing and flame-retardant fabrics for the purpose of preventing the generation of toxic gas generated during a fire, suppressing the combustion temperature during a fire, or preventing the spread of fire. In addition, flameproof fabrics that further develop this flame retardancy have been found. However, problems such as not achieving sufficient results, not having carbonization characteristics, and not having so-called shape retention characteristics are conceivable.
【0003】尚、先行文献の一例を挙げる。先ず、無機
質系の不燃性シートとして特開平6-922号の発明がある。こ
の発明は、ロックウール、ク゛ラスウール等の無機質繊維と繊維状ハ゛イン
タ゛ー樹脂で繊維シートを形成し、この繊維シートの表面に捺
染、フ゜リント等の手段で柄を表現する構成であって、無機
質繊維の不燃特性を発揮することを特徴とする。次にカ゛
ラス繊維でなる布生地体を使用した不燃性唐紙として特開
昭55-144160号の発明がある。この発明は、カ゛ラス繊維で
なる布生地体に、酸化アルミニウム、炭化硅素、その他無機質
の採色不燃性物質で色、又は模様をつけ、その上にフェノー
ル樹脂等の熱硬化性樹脂を塗布する構成であって、不燃
建材として役立つ不燃性唐紙を提供する。また難燃構造
のシート被覆材として、特開昭61-222411号の発明がある。
この発明は難燃性の張り布と、ホ゜リウレタン発泡材料のシートクッ
ション等でなるシートであって、張り布とシートクッション等との間に
難燃加工されたホ゜リウレタン発泡材料フィルムを介在させる構成
であって、発泡材料フィルムの炭化により、発泡材料クッション
の延焼防止を図る。[0003] An example of the prior art is given below. First, there is an invention of JP-A-6-922 as an inorganic noncombustible sheet. The present invention has a configuration in which a fiber sheet is formed from inorganic fibers such as rock wool and glass wool and a fibrous binder resin, and a pattern is expressed on the surface of the fiber sheet by means such as printing or printing. It is characterized by exhibiting characteristics. Japanese Patent Application Laid-Open No. 55-144160 discloses a non-combustible karagami using a cloth material made of glass fibers. The present invention provides a structure in which a cloth or cloth made of glass fibers is colored or patterned with aluminum oxide, silicon carbide, or other inorganic coloring noncombustible material, and a thermosetting resin such as a phenol resin is applied thereon. The present invention provides non-combustible karagami paper that is useful as a non-combustible building material. Further, as a sheet covering material having a flame-retardant structure, there is an invention disclosed in JP-A-61-222411.
The present invention is a sheet comprising a flame-retardant upholstery and a polyurethane foam material seat cushion or the like, wherein a flame-retardant polyurethane foam film is interposed between the upholstery and the seat cushion or the like. Thus, the spread of the foam material cushion is prevented by the carbonization of the foam material film.
【0004】[0004]
【発明が解決しようとする課題】前記文献の中には炭化
を図る手段として酸化アルミニウムを主体とした難燃性混合物
を使用する構成となっている。この酸化アルミニウム単独では
高温時に燃焼する虞が多分にあり、炭化にならない状況
となる。従って、防炎性に欠ける課題が考えられる。In the above document, a flame retardant mixture mainly composed of aluminum oxide is used as means for carbonizing. This aluminum oxide alone is likely to burn at high temperatures, and will not be carbonized. Therefore, a problem lacking in flame resistance is conceivable.
【0005】[0005]
【課題を解決するための手段】請求項1の発明は、無毒
性、難燃性及び/又は防炎性の布地を提供する。The invention of claim 1 provides a non-toxic, flame-retardant and / or flame-retardant fabric.
【0006】この発明は、布地に、無機質塗料を含浸、
塗付、噴霧又は捺染等の処理を行って、当該布地に難燃
性及び/又は防炎性を付与する構成とした無機質塗料を
用いた布地である。According to the present invention, a fabric is impregnated with an inorganic paint,
This is a fabric using an inorganic paint that is configured to impart flame retardancy and / or flame resistance to the fabric by performing a process such as coating, spraying, or printing.
【0007】請求項2の発明は、無毒性、難燃性及び/
又は防炎性並びに光触媒性の布地を提供する。The invention of claim 2 is non-toxic, flame-retardant and / or
Alternatively, it provides a flameproof and photocatalytic fabric.
【0008】この発明は、布地に、無機質塗料を含浸、
塗付、噴霧又は捺染等の処理、及び光触媒処理を行っ
て、当該布地に難燃性及び/又は防炎性並びに光触媒性
を付与する構成とした無機質塗料を用いた布地である。According to the present invention, a fabric is impregnated with an inorganic paint,
This is a fabric using an inorganic paint which is subjected to treatment such as coating, spraying or printing, and photocatalytic treatment to impart flame retardancy and / or flame resistance and photocatalytic property to the fabric.
【0009】請求項3の発明は、無毒性、難燃性及び/
又は防炎性並びに抗菌性の布地を提供する。The invention of claim 3 is non-toxic, flame-retardant and / or
Alternatively, it provides a flameproof and antibacterial fabric.
【0010】この発明は、布地に、無機質塗料を含浸、
塗付、噴霧又は捺染等の処理、及び抗菌処理を行って、
当該布地に難燃性及び/又は防炎性並びに抗菌性を付与
する構成とした無機質塗料を用いた布地である。According to the present invention, a fabric is impregnated with an inorganic paint,
Perform treatments such as coating, spraying or printing, and antibacterial treatment,
This is a fabric using an inorganic paint that is configured to impart flame retardancy and / or flame resistance and antibacterial property to the fabric.
【0011】請求項4の発明は、無毒性、難燃性及び/
又は防炎性等に優れた布地を提供する。The invention of claim 4 is non-toxic, flame-retardant and / or
Alternatively, the present invention provides a fabric excellent in flame resistance and the like.
【0012】この発明は、布地に、無機質塗料を含浸、
塗付、噴霧又は捺染等の処理を二回行う構成の無機質塗
料を用いた布地である。According to the present invention, a fabric is impregnated with an inorganic paint,
This is a fabric using an inorganic paint having a configuration in which coating, spraying, printing, and the like are performed twice.
【0013】請求項5の発明は、無毒性、難燃性及び/
又は防炎性の布地を提供する。The invention of claim 5 is non-toxic, flame-retardant and / or
Alternatively, a flameproof fabric is provided.
【0014】この発明は、布地構成用糸に、無機質塗料
を含浸、塗付、噴霧又は捺染等の処理を行って処理糸を
生成し、この処理糸を使用して布地を構成し、この布地
に難燃性及び/又は防炎性を付与する構成とした無機質
塗料を用いた布地である。According to the present invention, a yarn for fabric construction is subjected to a treatment such as impregnation, coating, spraying or printing with an inorganic paint to produce a treated yarn, and the treated yarn is used to constitute a fabric. This is a fabric using an inorganic paint that is configured to impart flame retardancy and / or flame resistance to the fabric.
【0015】請求項6の発明は、無毒性、難燃性及び/
又は防炎性並びに光触媒性の布地を提供する。The invention of claim 6 is non-toxic, flame-retardant and / or
Alternatively, it provides a flameproof and photocatalytic fabric.
【0016】この発明は、布地構成用糸に、無機質塗料
を含浸、塗付、噴霧又は捺染等の処理、及び光触媒処理
を行って処理糸を生成し、この処理糸を使用して布地を
構成し、この布地に難燃性及び/又は防炎性並びに光触
媒性を付与する構成とした無機質塗料を用いた布地であ
る。According to the present invention, a yarn for fabric formation is subjected to a treatment such as impregnation, coating, spraying or printing with an inorganic paint, and a photocatalytic treatment to produce a treated yarn, and the treated yarn is used to form a fabric. In addition, the fabric is made of an inorganic paint that is configured to impart flame retardancy and / or flame resistance and photocatalytic property to the fabric.
【0017】請求項7の発明は、無毒性、難燃性及び/
又は防炎性並びに抗菌性の布地を提供する。The invention of claim 7 is non-toxic, flame-retardant and / or
Alternatively, it provides a flameproof and antibacterial fabric.
【0018】この発明は、布地構成用糸に、無機質塗料
を含浸、塗付、噴霧又は捺染等の処理、及び抗菌処理を
行って処理糸を生成し、この処理糸を使用して布地を構
成し、この布地に難燃性及び/又は防炎性並びに抗菌性
を付与する構成とした無機質塗料を用いた布地である。According to the present invention, a treated yarn is formed by impregnating, coating, spraying or printing an inorganic paint on a yarn for fabric construction, and performing an antibacterial treatment to produce a treated yarn. The fabric is made of an inorganic paint that is configured to impart flame retardancy and / or flame resistance and antimicrobial properties to the fabric.
【0019】請求項8の発明は、無毒性、難燃性及び/
又は防炎性等に優れた布地を提供する。The invention of claim 8 is non-toxic, flame-retardant and / or
Alternatively, the present invention provides a fabric excellent in flame resistance and the like.
【0020】この発明は、布地構成用糸に、無機質塗料
を含浸、塗付、噴霧又は捺染等の処理を二回行う構成の
無機質塗料を用いた布地である。The present invention relates to a fabric using an inorganic paint having a structure in which the yarn for fabric construction is impregnated, coated, sprayed or printed twice with the inorganic paint.
【0021】[0021]
【発明の実施の形態】図1は燃焼試験を示す模式図であ
り、(イ)は試験方法の図、(ロ')、(ロ")は社内試験に基づ
く、炭化面積の程度を示しており、(ロ')が加工処理前の
羊毛の状態を、(ロ")は加工処理後の羊毛の状態を示して
いる。図1(ロ')は、かなり炭化がすすみ大きな穴となっ
ている。しかし、(ロ")は、炭化の程度が少なく小さな穴
となっている。図1の如く、布地1を略45°に設け、略10
mmの間隔をもってミクロハ゛ーナ又はメッケルハ゛ーナ等の火源2を設
け、約2分試験した。この結果、同図(ロ')は未処理の結
果であり、燃焼して穴開き11状態となるが、同図(ロ")は
残じん抑止剤を使用した結果であり、炭化部12となって
いる。従って、両者の相違は、明確である。尚、21は火
源2の炎の先端位置を示す。また図中に数字を挿入す
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a schematic diagram showing a combustion test, wherein (a) shows a diagram of a test method, and (b ') and (b ") show the degree of carbonized area based on an in-house test. (B) indicates the state of the wool before the processing, and (b ") indicates the state of the wool after the processing. FIG. 1 (b ') shows a large hole through which carbonization proceeds considerably. However, (b) is a small hole with a low degree of carbonization. As shown in FIG.
A fire source 2 such as a micro hole or a Meckel hole was provided at intervals of mm, and the test was performed for about 2 minutes. As a result, FIG. 2 (b ′) is the result of the untreated treatment, and is burned into the perforated state 11, while FIG. 2 (b ″) is the result of using the dust inhibitor, and Therefore, the difference between the two is clear: 21 indicates the position of the tip of the flame of the fire source 2. Also, a numeral is inserted in the figure.
【0022】尚、本出願人が代表取締役社長を勤めるクロ
ノ技研株式会社が愛知県の公的研究機関に依頼した炭化テ
゛ータを下記に示す。The carbonization data requested by a public research institute in Aichi Prefecture by Chrono Giken Co., Ltd., of which the applicant is the CEO, is shown below.
【0023】「表1」 "Table 1"
【0024】尚、残じん抑止剤を使用した社内実験と、
その資料を提供する。In addition, an in-house experiment using a detergency inhibitor,
Provide the material.
【0025】残じん抑止剤として、カ゛ラス微粉末の無機質
塗料を使用する。残じん抑止剤は、塗料の主剤に対し
て、Aは5重量%、Bは10重量%、Cは20重量%、Dは0重量
%、Eは10重量%、Fは1重量%、Gは3重量%であり、下
塗りとして無機質塗料を塗布(スフ゜レー等吹付け法、ハ゜テ゛ィ
ンク゛法“テ゛ィッフ゜法”、ロールコート法、フローコーティン ク゛法等)し、
この塗布後、仮乾燥(100℃×10分)する。上塗りとし
て無機質塗料を塗布し、この塗布後、本乾燥(100℃×5
5分“1-E、4-Eのサンフ゜ル”又は200℃×15分“他のサンフ゜
ル”)をする。尚、この残じん抑止剤として、セラミック系無
機質微粉末、耐火レンカ゛微粉末、シリカケ゛ル系微粉末等があ
り、粒径は0.1μm〜300μm(望ましくは0.5μm〜10μ
m)、混入量は2重量%〜40重量%(望ましくは5重量%
〜20重量%)とする。As a dust inhibitor, an inorganic coating material of glass fine powder is used. A: 5% by weight, B: 10% by weight, C: 20% by weight, D: 0% by weight, E: 10% by weight, F: 1% by weight, G Is 3% by weight, and an inorganic paint is applied as an undercoat (spraying method, spraying method, “tiff method”, roll coating method, flow coating method, etc.)
After this coating, it is temporarily dried (100 ° C. × 10 minutes). An inorganic paint is applied as a top coat, and after this application, main drying (100 ° C x 5
5 minutes “1-E, 4-E sample” or 200 ° C x 15 minutes “other sample”). Examples of the dust inhibitor include ceramic-based inorganic fine powder, refractory lenticular fine powder, and silica-keel-based fine powder, and have a particle size of 0.1 μm to 300 μm (preferably 0.5 μm to 10 μm).
m), the mixing amount is 2 wt% to 40 wt% (preferably 5 wt%
~ 20% by weight).
【0026】「表2」 "Table 2"
【0027】図2はアナターセ゛型二酸化チタンを含有する光触媒
型塗料による光触媒処理に基づく実験テ゛ータ(窒素酸化物
の除去性能試験)に使用した布地1を示しており、この
布地1にアナターセ゛型二酸化チタンを含有する下塗り層3及び上
塗り層4を設けた基材の図(イ)、(ロ)による実験テ゛ータを下記
に示す。この実験テ゛ータは、本出願人のクロノ技研株式会社
が愛知県の公的研究機関に依頼したものである。但し、
この実験テ゛ータは、下塗り層3を設けた基材の上に一般の
透明な上塗り層41を設けたので、十分な成果が得られな
かった。そこで、布地1にアナターセ゛型二酸化チタンを含有する
下塗り層3と、トッフ゜コート系塗料、クリアー型塗料等の透明性の
アナターセ゛型二酸化チタンを含有する上塗り層4を設けた基材の
図(ロ)を示す。この下塗り層3と、上塗り層4を設けた図
(ロ)では、前記実験テ゛ータを上回る結果が期待できる。FIG. 2 shows a fabric 1 used for an experimental data (a test for removing nitrogen oxides) based on a photocatalytic treatment with a photocatalytic paint containing anatase-type titanium dioxide. Experimental data of the base material provided with the undercoat layer 3 and the overcoat layer 4 containing (a) and (b) are shown below. This experimental data was submitted by the present applicant, Chrono Giken Co., Ltd., to a public research institution in Aichi Prefecture. However,
In this experimental data, since a general transparent overcoat layer 41 was provided on the substrate on which the undercoat layer 3 was provided, sufficient results were not obtained. Therefore, a base material provided with an undercoat layer 3 containing anatase-type titanium dioxide on a fabric 1 and an overcoat layer 4 containing a transparent anatase-type titanium dioxide such as a topcoat paint or a clear paint (b) Is shown. The figure provided with the undercoat layer 3 and the overcoat layer 4
In (b), a result exceeding the experimental data can be expected.
【0028】「表3」 "Table 3"
【0029】[0029]
【実施例】本発明の一実施例を説明する。An embodiment of the present invention will be described.
【0030】請求項1では、シリカソ゛ルを珪酸ソータ゛の1/3以下
の混合量とした珪酸ソータ゛とシリカソ゛ルとの混合液に、リン酸亜
鉛粉末を10〜35重量%、又はリン酸二水素アルミニウム液を6〜4
0重量%溶かして成る無機質塗料の溶剤に布地1を浸漬
し、この布地1に無機質塗料の溶剤を含浸させる構成と
する。この例では、繊維5(この繊維5は、天然繊維、化
学繊維、合成繊維、複合繊維、他の各種繊維が含まれ
る)の隙間に、当該無機質塗料の溶剤が浸透することが
大切であり、これにより難燃性及び/又は防炎性が確保
される。また静電気の発生要因が無くなり、この種の静
電気の発生は皆無である(後述する)。尚、浸漬に代
り、無機質塗料の溶剤の塗布、噴霧においても、前記と
同様な状況となれば同効が期待できる。図3の(イ)、(ロ)、
(ハ)、(ニ)で示す。綿100%の繊維5を顕微鏡1000倍にした図
であり、この(イ)は繊維5の図であり、6は繊維5の形状、
7は隙間を示す。(ロ)は繊維5に無機質塗料の溶剤でなる
下塗り層3を設けた図である。(ハ)は前記(ロ)を燃焼試験
した図であり、8は繊維5の炭化を示す。(ニ)は下塗り層3
を設けた繊維5にクリアー型塗料等の透明性の溶剤でなる上
塗り層4を設けた図である。According to the first aspect of the present invention, the mixed solution of the silica silicate and the silica silicate in which the silica sol is mixed in a mixing amount of 1/3 or less of the sodium silicate is added with 10 to 35% by weight of zinc phosphate powder or aluminum dihydrogen phosphate solution. 6-4
The fabric 1 is immersed in a solvent of the inorganic paint dissolved by 0% by weight, and the fabric 1 is impregnated with the solvent of the inorganic paint. In this example, it is important that the solvent of the inorganic paint permeates into the gaps between the fibers 5 (the fibers 5 include natural fibers, chemical fibers, synthetic fibers, composite fibers, and various other fibers). This ensures flame retardancy and / or flame resistance. In addition, there is no static electricity generation factor, and there is no generation of this kind of static electricity (described later). It should be noted that, instead of immersion, the same effect can be expected in the application and spraying of a solvent of an inorganic paint if the same situation as described above is achieved. (A), (b),
(C) and (d). This is a diagram in which a fiber 5 of 100% cotton is magnified 1000 times, and this (a) is a diagram of the fiber 5, and 6 is the shape of the fiber 5,
7 indicates a gap. (B) is a diagram in which an undercoat layer 3 made of a solvent of an inorganic paint is provided on the fiber 5. (C) is a diagram showing a combustion test of (B), and 8 shows carbonization of the fiber 5. (D) is undercoat layer 3
FIG. 2 is a view in which an overcoat layer 4 made of a transparent solvent such as a clear paint is provided on a fiber 5 provided with.
【0031】尚、静電気の発生要因を詳しく説明する。
この静電気の発生要因を皆無にするには、例えば、布地
1を構成する繊維5が、高絶縁性能、帯電抑止性等を発揮
すれば可能である。本発明は、繊維5の回りを下塗り層3
及び/又は上塗り層4が被覆するので、この下塗り層3及
び/又は上塗り層4の高絶縁性能、帯電抑止性等が発揮
される状態となり、帯電媒体の繊維5への通電がなく、
静電気の発生が回避できる。尚、本出願人のクロノ技研株
式会社が愛知県の公的研究機関に依頼した実験テ゛ータを、
下記に示す。The cause of the generation of static electricity will be described in detail.
To eliminate this static electricity generation factor, for example,
It is possible if the fibers 5 constituting 1 exhibit high insulation performance, antistatic properties and the like. The present invention provides the undercoat layer 3 around the fiber 5.
And / or the overcoat layer 4 covers, so that the undercoat layer 3 and / or the overcoat layer 4 exhibit high insulation performance, antistatic properties, etc., and there is no electricity to the fibers 5 of the charging medium,
Generation of static electricity can be avoided. The experimental data requested by the applicant, Chrono Giken Co., Ltd., to a public research institution in Aichi Prefecture,
Shown below.
【0032】また図5には、本工程のフローチャート図を示す
が、コース1、2が考えられる。先ず、コース1は、布地1を、下
塗り(色の限定なし)を行い下塗り層3を形成する。そ
の後、略50℃〜略300℃で略1分〜略10分をかけて乾燥処
理(以下同じ)する。尚、下塗りの方法は、布地1の物
性、材質、密度、厚み等を考慮して最適な方法を採用す
る(以下同じ)。次に、コース2は、布地1を水浸漬、湿潤
処理した後、下塗りを行い下塗り層3を形成する。その
後、乾燥処理する。他は前述の例と略同様である。FIG. 5 is a flow chart of this process, but courses 1 and 2 are conceivable. First, in the course 1, the fabric 1 is undercoated (no limitation in color) to form an undercoat layer 3. Thereafter, a drying treatment is carried out at about 50 ° C. to about 300 ° C. for about 1 minute to about 10 minutes (the same applies hereinafter). The method of undercoating employs an optimal method in consideration of the physical properties, material, density, thickness and the like of the fabric 1 (the same applies hereinafter). Next, in the course 2, after the fabric 1 is dipped in water and wet-treated, an undercoat is performed to form an undercoat layer 3. Thereafter, a drying treatment is performed. Others are substantially the same as the above-mentioned example.
【0033】「表4」 "Table 4"
【0034】請求項2では、シリカソ゛ルを珪酸ソータ゛の1/3以下
の混合量とした珪酸ソータ゛とシリカソ゛ルとの混合液に、リン酸亜
鉛粉末を10〜35重量%、又はリン酸二水素アルミニウム液を6〜4
0重量%溶かして成る無機質塗料の溶剤にアナターセ゛型二酸
化チタン溶剤を添加する。この溶剤に布地1を浸漬し、含浸
させる構成とする。この例では、繊維5の隙間に、当該
無機質塗料の溶剤にアナターセ゛型二酸化チタン溶剤を添加した
溶剤が浸透することが大切であり、これにより難燃性及
び/又は防炎性が確保される。また静電気の発生要因が
無くなる。尚、浸漬に代り、無機質塗料の溶剤にアナターセ゛
型二酸化チタン溶剤を添加した溶剤の塗布、噴霧において
も、前記と同様な状況となれば同効が期待できる。この
アナターセ゛型二酸化チタン溶剤に紫外線又は太陽光線等が照射
されることにより光触媒反応が進行し、活性酵素が生成
される。According to a second aspect of the present invention, the mixed solution of the silica silicate and the silica silicate in which the silica sol is mixed at a mixing amount of 1/3 or less of the sodium silicate is added with 10 to 35% by weight of zinc phosphate powder or aluminum dihydrogen phosphate solution. 6-4
An anatase-type titanium dioxide solvent is added to the solvent of the inorganic paint dissolved by 0% by weight. The fabric 1 is soaked and impregnated in this solvent. In this example, it is important that a solvent obtained by adding an anatase-type titanium dioxide solvent to the solvent of the inorganic paint permeates into the gaps between the fibers 5, thereby ensuring flame retardancy and / or flame resistance. In addition, the generation factor of static electricity is eliminated. It should be noted that, instead of immersion, the same effect can also be expected in the application and spraying of a solvent obtained by adding an anatase-type titanium dioxide solvent to the solvent of an inorganic paint, provided that the situation is the same as described above. By irradiating the anatase type titanium dioxide solvent with ultraviolet rays or sunlight, a photocatalytic reaction proceeds to generate active enzymes.
【0035】請求項3では、シリカソ゛ルを珪酸ソータ゛の1/3以下
の混合量とした珪酸ソータ゛とシリカソ゛ルとの混合液に、リン酸亜
鉛粉末を10〜35重量%、又はリン酸二水素アルミニウム液を6〜4
0重量%溶かして成る無機質塗料等の溶剤に、銀イオン、銅
イオン、亜鉛イオン等のイオン系無機質抗菌剤は0.5重量%〜8重
量%、亜鉛イオンは0.5重量%〜40重量%等のイオン系無機質
抗菌剤を0.5重量%〜40重量%(望ましくは、15重量%
〜25重量%)を添加する。この溶剤に布地1を浸漬又は
含浸させる構成とする。この例では、糸の隙間に、当該
無機質塗料等の溶剤に銀イオン、銅イオン、亜鉛イオン等のイオン系
無機質抗菌剤を添加した溶剤が浸透することが大切であ
り、これにより難燃性及び/又は防炎性が確保される。
尚、浸漬に代り、無機質塗料等の溶剤に銀イオン、銅イオン、
亜鉛イオン等のイオン系無機質抗菌剤を添加した溶剤の塗布、
噴霧においても、前記と同様な状況となれば同効が期待
できる。According to a third aspect of the present invention, the mixed solution of the silica silicate and the silica sol in which the silica sol is mixed at a mixing amount of 1/3 or less of the sodium silicate is added with 10 to 35% by weight of zinc phosphate powder or aluminum dihydrogen phosphate solution. 6-4
0.5% to 8% by weight of ionic inorganic antibacterial agents such as silver ion, copper ion and zinc ion and 0.5% to 40% by weight of zinc ion 0.5 to 40% by weight (preferably 15% by weight)
~ 25% by weight). The fabric 1 is soaked or impregnated in this solvent. In this example, it is important that a solvent obtained by adding an ionic inorganic antibacterial agent such as a silver ion, a copper ion, or a zinc ion to a solvent such as the inorganic paint penetrates into the gaps between the yarns, thereby providing flame retardancy and And / or flame resistance is ensured.
In addition, instead of immersion, silver ions, copper ions,
Application of a solvent containing an ionic inorganic antibacterial agent such as zinc ion,
In the case of spraying, the same effect can be expected under the same situation as described above.
【0036】請求項4の発明は、請求項1のシリカソ゛ルを珪酸
ソータ゛の1/3以下の混合量とした珪酸ソータ゛とシリカソ゛ルとの混
合液に、リン酸亜鉛粉末を10〜35重量%、又はリン酸二水素
アルミニウム液を6〜40重量%溶かして成る無機質塗料の溶剤
を再度浸漬し、この布地1に、無機質塗料の溶剤をオーハ゛ー
ラッフ゜の状態で含浸させる構成とする。この例では、繊維
5の隙間に、当該無機質塗料の溶剤の二重の難燃性及び
/又は防炎性等が確保される。この例は、図4の(イ)、
(ロ)、(ハ)、(ニ)で示す。テトロン50%とレーヨン50%の繊維5を顕微鏡
1000倍にした図である。この図の(イ)、(ロ)、(ハ)、(ニ)の符
号及び名称は、前記図3と同じである。勿論、繊維5の形
状6、隙間7の大小等は異なる。According to a fourth aspect of the present invention, there is provided a mixed solution of the silica silicate and the silica sol in which the silica sol of the first aspect is mixed with the silica silicate in a mixing amount of 1/3 or less, and 10 to 35% by weight of zinc phosphate powder, or The solvent of the inorganic paint formed by dissolving 6 to 40% by weight of the aluminum dihydrogen phosphate solution is immersed again, and the fabric 1 is impregnated with the solvent of the inorganic paint in an over-rough state. In this example, the fiber
In the gap 5, the double flame retardancy and / or flame resistance of the solvent of the inorganic paint is ensured. This example is shown in FIG.
(B), (c), and (d). Microscope 5 with 50% Tetron and 50% rayon
It is the figure which made 1000 times. The symbols and names of (a), (b), (c), and (d) in this figure are the same as those in FIG. Of course, the shape 6 of the fiber 5 and the size of the gap 7 are different.
【0037】また図6には、本工程のフローチャート図を示す
が、コース3、4が考えられる。先ず、コース3は、布地1を水浸
漬、湿潤処理した後、上塗りを行い上塗り層4を形成す
る。その後、乾燥処理する。他は前述の例と略同様であ
る。次に、コース4は、布地1を水浸漬、湿潤処理した後、
下塗りを行い下塗り層3を形成する。その後、略50℃〜
略100℃で略1分〜略8分をかけて中間乾燥又は加熱し、
上塗りを行い上塗り層4を形成する。その後、乾燥処理
する。他は前述の例と略同様である。FIG. 6 shows a flowchart of this process, but courses 3 and 4 can be considered. First, in the course 3, the fabric 1 is immersed in water and wet-treated, and then overcoated to form an overcoat layer 4. Thereafter, a drying treatment is performed. Others are substantially the same as the above-mentioned example. Next, course 4, after immersing the fabric 1 in water and performing a wet treatment,
An undercoat is performed to form an undercoat layer 3. After that, approximately 50 ° C ~
Intermediate drying or heating at about 100 ° C. for about 1 minute to about 8 minutes,
An overcoat is performed to form an overcoat layer 4. Thereafter, a drying treatment is performed. Others are substantially the same as the above-mentioned example.
【0038】尚、ストロンチューム、アルミネート系蓄光塗料(顔料)
を含浸又は塗布等して前記難燃性及び/又は防炎性等が
確保された布地1に、蓄光機能を付与することも可能で
あり、例えば、硫化亜鉛系螢光体、アルカリ土類アルミン酸螢光
体等を採用する。このような処理を施すことにより、夜
間、暗闇等での誘導、表示、警告等に役立つ特徴があ
る。また本発明の内容は、各種紙、紙成形品、紙材、鋼
材、フ゜ラスチック等の異質部材にも採用できる。Strontum, aluminate phosphorescent paint (pigment)
It is also possible to impart a luminous function to the fabric 1 in which the flame retardancy and / or flame resistance and the like are ensured by impregnating or applying, for example, a zinc sulfide-based phosphor, an alkaline earth alumina, etc. Use an acid phosphor or the like. By performing such processing, there is a feature that is useful for guidance, display, warning, and the like at night, in the dark, and the like. Further, the contents of the present invention can also be applied to heterogeneous members such as various papers, paper molded products, paper materials, steel materials, plastics and the like.
【0039】請求項5では、シリカソ゛ルを珪酸ソータ゛の1/3以下
の混合量とした珪酸ソータ゛とシリカソ゛ルとの混合液に、リン酸亜
鉛粉末を10〜35重量%、又はリン酸二水素アルミニウム液を6〜4
0重量%溶かして成る無機質塗料の溶剤に布地構成用糸
を浸漬し、この布地構成用糸に、無機質塗料の溶剤を含
浸させる構成とする。この例では、布地構成用糸の隙間
に、当該無機質塗料の溶剤が浸透することが大切であ
り、これにより難燃性及び/又は防炎性が確保される。
また静電気の発生要因が無くなり、この種の静電気の発
生要因は皆無である。尚、浸漬に代り、無機質塗料の溶
剤の塗布、噴霧においても、前記と同様な状況となれば
同効が期待できる。According to a fifth aspect of the present invention, the mixed solution of the silica silicate and the silica silicate in which the silica sol is mixed in a mixing amount of 1/3 or less of the sodium silicate is added with 10 to 35% by weight of zinc phosphate powder or aluminum dihydrogen phosphate. 6-4
The fabric-constituting yarn is immersed in a solvent for the inorganic paint dissolved by 0% by weight, and the fabric-constituting yarn is impregnated with the solvent for the inorganic paint. In this example, it is important that the solvent of the inorganic coating material penetrates into the gaps between the yarns for forming the fabric, thereby ensuring flame retardancy and / or flame resistance.
Further, there is no static electricity generation factor, and there is no such static electricity generation factor. It should be noted that, instead of immersion, the same effect can be expected in the application and spraying of a solvent of an inorganic paint if the same situation as described above is achieved.
【0040】請求項6では、シリカソ゛ルを珪酸ソータ゛の1/3以下
の混合量とした珪酸ソータ゛とシリカソ゛ルとの混合液に、リン酸亜
鉛粉末を10〜35重量%、又はリン酸二水素アルミニウム液を6〜4
0重量%溶かして成る無機質塗料の溶剤に布地構成用糸
を浸漬し、この布地構成用糸に、アナターセ゛型二酸化チタン溶
剤を添加した溶剤を含浸させる構成とする。この例で
は、布地構成用糸の隙間に、当該無機質塗料の溶剤にアナ
ターセ゛型二酸化チタン溶剤を添加した溶剤が浸透することが
大切であり、これにより難燃性及び/又は防炎性が確保
される。また静電気の発生要因が無くなる。尚、浸漬に
代り、無機質塗料の溶剤にアナターセ゛型二酸化チタン溶剤を添
加した溶剤の塗布、噴霧においても、前記と同様な状況
となれば同効が期待できる。このアナターセ゛型二酸化チタン溶
剤に紫外線又は太陽光線等が照射されることにより光触
媒反応が進行し、活性酵素が生成される。According to a sixth aspect of the present invention, the mixed solution of the silica silicate and the silica silicate having a mixing amount of the silica sol of 1/3 or less of the sodium silicate is added with 10 to 35% by weight of zinc phosphate powder or aluminum dihydrogen phosphate. 6-4
The fabric forming yarn is immersed in a solvent of an inorganic coating material dissolved by 0% by weight, and the fabric forming yarn is impregnated with a solvent to which an anatase type titanium dioxide solvent is added. In this example, it is important that a solvent obtained by adding an anatase-type titanium dioxide solvent to the solvent of the inorganic paint permeates into the gaps between the yarns for forming the fabric, thereby ensuring flame retardancy and / or flame resistance. You. In addition, the generation factor of static electricity is eliminated. It should be noted that, instead of immersion, the same effect can also be expected in the application and spraying of a solvent obtained by adding an anatase-type titanium dioxide solvent to the solvent of an inorganic paint, provided that the situation is the same as described above. By irradiating the anatase type titanium dioxide solvent with ultraviolet rays or sunlight, a photocatalytic reaction proceeds to generate active enzymes.
【0041】請求項7では、シリカソ゛ルを珪酸ソータ゛の1/3以下
の混合量とした珪酸ソータ゛とシリカソ゛ルとの混合液に、リン酸亜
鉛粉末を10〜35重量%、又はリン酸二水素アルミニウム液を6〜4
0重量%溶かして成る無機質塗料等の溶剤に布地構成用
糸を浸漬し、この布地構成用糸に銀イオン、銅イオン、亜鉛イオ
ン等のイオン系無機質抗菌剤を添加した溶剤を含浸させる構
成とする。この例では、布地構成用糸の隙間に、当該無
機質塗料等の溶剤に銀イオン、銅イオン、亜鉛イオン等のイオン系無
機質抗菌剤を添加した溶剤が浸透することが大切であ
り、これにより難燃性及び/又は防炎性が確保される。
尚、浸漬に代り、無機質塗料等の溶剤に銀イオン、銅イオン、
亜鉛イオン等のイオン系無機質抗菌剤を添加した溶剤の塗布、
噴霧においても、前記と同様な状況となれば同効が期待
できる。According to a seventh aspect of the present invention, the mixed solution of the silica silicate and the silica sol in which the silica sol is mixed in a mixing amount of 1/3 or less of the sodium silicate is added with 10 to 35% by weight of zinc phosphate powder or aluminum dihydrogen phosphate solution. 6-4
A fabric composition yarn is immersed in a solvent such as an inorganic paint dissolved by 0% by weight, and the fabric composition yarn is impregnated with a solvent to which an ionic inorganic antibacterial agent such as silver ion, copper ion, zinc ion or the like is added. I do. In this example, it is important that a solvent in which an ionic inorganic antibacterial agent such as silver ion, copper ion, or zinc ion is added to the solvent of the inorganic paint or the like penetrates into the gaps between the yarns for forming the fabric. Flammability and / or flame resistance are ensured.
In addition, instead of immersion, silver ions, copper ions,
Application of a solvent containing an ionic inorganic antibacterial agent such as zinc ion,
In the case of spraying, the same effect can be expected under the same situation as described above.
【0042】請求項8の発明は、請求項1のシリカソ゛ルを珪酸
ソータ゛の1/3以下の混合量とした珪酸ソータ゛とシリカソ゛ルとの混
合液に、リン酸亜鉛粉末を10〜35重量%、又はリン酸二水素
アルミニウム液を6〜40重量%溶かして成る無機質塗料の溶剤
に布地構成用糸を再度浸漬し、この布地構成用糸に無機
質塗料の溶剤をオーハ゛ーラッフ゜の状態で含浸させる構成とす
る。この例では、布地構成用糸の隙間に、当該無機質塗
料の溶剤の二重の難燃性及び/又は防炎性等が確保され
る。[0042] The invention of claim 8 is that, in the mixed solution of the silica silicate and the silica sol in which the silica sol of the claim 1 is mixed up to 1/3 or less of the silicate, the zinc phosphate powder is 10 to 35% by weight, or The fabric-forming yarn is immersed again in a solvent for the inorganic paint formed by dissolving 6 to 40% by weight of the aluminum dihydrogen phosphate solution, and the fabric-forming yarn is impregnated with the solvent for the inorganic paint in an over-ruff state. . In this example, double flame retardancy and / or flame resistance of the solvent of the inorganic paint are secured in the gaps between the yarns for fabric construction.
【0043】尚、蓄光塗料を含浸又は塗布等して前記難
燃性及び/又は防炎性等が確保された布地構成用糸とす
ることは、前述の例と略同様である。The method of impregnating or applying a luminous paint into a yarn for fabric construction in which the flame retardancy and / or flame resistance and the like are secured is substantially the same as the above-described example.
【0044】各構成例に、他の性能又は特性、例えば、
脱臭性能、抗菌性能、蓄光性能、等を付与するために
は、各種の溶剤を付加することもある。Each configuration example has other performance or characteristics, for example,
In order to provide deodorizing performance, antibacterial performance, luminous performance, etc., various solvents may be added.
【0045】また強伸度、剛軟性は、前記各種溶剤の塗
布量、塗布回数、乾燥・加熱温度等の調整で、用途及び
目的等により種々変更できる。また建材関係、車輛等の
分野でも利用できる。The strength and elongation can be variously changed by adjusting the application amount, the number of applications, the drying / heating temperature, etc. of the above-mentioned various solvents according to the use and purpose. It can also be used in fields such as building materials and vehicles.
【0046】「表5」 "Table 5"
【0047】[0047]
【発明の効果】請求項1の発明は、布地に、無機質塗料
を含浸、塗付、噴霧又は捺染等の処理を行って、当該布
地に難燃性及び/又は防炎性を付与する構成とした無機
質塗料を用いた布地である。従って、無毒性、難燃性及
び/又は防炎性の布地を提供できる。According to the first aspect of the present invention, the fabric is impregnated, coated, sprayed or printed with an inorganic paint to impart flame retardancy and / or flame resistance to the fabric. This is a fabric using the obtained inorganic paint. Accordingly, a non-toxic, flame-retardant and / or flame-resistant fabric can be provided.
【0048】請求項2の発明は、布地に、無機質塗料を
含浸、塗付、噴霧又は捺染等の処理、及び光触媒処理を
行って、当該布地に難燃性及び/又は防炎性並びに光触
媒性を付与する構成とした無機質塗料を用いた布地であ
る。従って、無毒性、難燃性及び/又は防炎性並びに光
触媒性の布地を提供できる。According to the invention of claim 2, the fabric is subjected to a treatment such as impregnation, coating, spraying or printing, and a photocatalyst treatment, and the fabric is subjected to flame retardant and / or flameproof and photocatalytic properties. This is a fabric using an inorganic paint having a configuration for imparting the same. Accordingly, non-toxic, flame-retardant and / or flame-retardant and photocatalytic fabrics can be provided.
【0049】請求項3の発明は、布地に、無機質塗料を
含浸、塗付、噴霧又は捺染等の処理、及び抗菌処理を行
って、当該布地に難燃性及び/又は防炎性並びに抗菌性
を付与する構成とした無機質塗料を用いた布地である。
従って、無毒性、難燃性及び/又は防炎性並びに抗菌性
の布地を提供できる。According to the invention of claim 3, the fabric is subjected to a treatment such as impregnation, coating, spraying or printing, and an antibacterial treatment, so that the fabric is flame retardant and / or flameproof and antibacterial. This is a fabric using an inorganic paint having a configuration for imparting the same.
Accordingly, non-toxic, flame-retardant and / or flame-resistant and antibacterial fabrics can be provided.
【0050】請求項4の発明は、布地に、無機質塗料を
含浸、塗付、噴霧又は捺染等の処理を二回行う構成の無
機質塗料を用いた布地である。従って、無毒性、難燃性
及び/又は防炎性等に優れた布地を提供できる。A fourth aspect of the present invention is a fabric using an inorganic paint having a configuration in which the fabric is impregnated, coated, sprayed or printed twice with the inorganic paint. Therefore, it is possible to provide a fabric excellent in non-toxicity, flame retardancy and / or flame resistance and the like.
【0051】請求項5の発明は、布地構成用糸に、無機
質塗料を含浸、塗付、噴霧又は捺染等の処理を行って処
理糸を生成し、この処理糸を使用して布地を構成し、こ
の布地に難燃性及び/又は防炎性を付与する構成とした
無機質塗料を用いた布地である。従って、無毒性、難燃
性及び/又は防炎性の布地を提供できる。According to a fifth aspect of the present invention, a yarn for fabric formation is subjected to a treatment such as impregnation, coating, spraying or printing with an inorganic paint to produce a treated yarn, and the treated yarn is used to constitute a fabric. And a fabric using an inorganic paint which is configured to impart flame retardancy and / or flame resistance to the fabric. Accordingly, a non-toxic, flame-retardant and / or flame-resistant fabric can be provided.
【0052】請求項6の発明は、布地構成用糸に、無機
質塗料を含浸、塗付、噴霧又は捺染等の処理、及び光触
媒処理を行って処理糸を生成し、この処理糸を使用して
布地を構成し、この布地に難燃性及び/又は防炎性並び
に光触媒性を付与する構成とした無機質塗料を用いた布
地である。従って、無毒性、難燃性及び/又は防炎性並
びに光触媒性の布地を提供できる。According to a sixth aspect of the present invention, a yarn for forming a fabric is impregnated with an inorganic paint, subjected to a treatment such as coating, spraying or printing, and a photocatalytic treatment to produce a treated yarn. This is a fabric using an inorganic paint that constitutes a fabric and is configured to impart flame retardancy and / or flame resistance and photocatalytic property to the fabric. Accordingly, non-toxic, flame-retardant and / or flame-retardant and photocatalytic fabrics can be provided.
【0053】請求項7の発明は、布地構成用糸に、無機
質塗料を含浸、塗付、噴霧又は捺染等の処理、及び抗菌
処理を行って処理糸を生成し、この処理糸を使用して布
地を構成し、この布地に難燃性及び/又は防炎性並びに
抗菌性を付与する構成とした無機質塗料を用いた布地で
ある。従って、無毒性、難燃性及び/又は防炎性並びに
抗菌性の布地を提供できる。According to a seventh aspect of the present invention, a yarn for fabric construction is subjected to a treatment such as impregnation, coating, spraying or printing, and an antibacterial treatment to produce a treated yarn, and the treated yarn is used. This is a fabric using an inorganic paint which constitutes the fabric and is configured to impart flame retardancy and / or flame resistance and antibacterial property to the fabric. Accordingly, non-toxic, flame-retardant and / or flame-resistant and antibacterial fabrics can be provided.
【0054】請求項8の発明は、布地構成用糸に、無機
質塗料を含浸、塗付、噴霧又は捺染等の処理を二回行う
構成の無機質塗料を用いた布地である。従って、無毒
性、難燃性及び/又は防炎性等に優れた布地を提供でき
る。An eighth aspect of the present invention is a fabric using an inorganic paint having a structure in which the yarn for fabric construction is impregnated, coated, sprayed or printed twice with the inorganic paint. Therefore, it is possible to provide a fabric excellent in non-toxicity, flame retardancy and / or flame resistance and the like.
【図1】図1は燃焼試験を示す模式図であり、(イ)は試験
方法の図、(ロ')が加工処理前の羊毛の状態を示す図、
(ロ")は加工処理後の羊毛の状態を示す図である。FIG. 1 is a schematic diagram showing a combustion test, (a) is a diagram of a test method, (b ′) is a diagram showing a state of wool before processing,
(B) is a diagram showing the state of wool after the processing.
【図2】図2はアナターセ゛型二酸化チタンを含有する光触媒型塗
料による光触媒処理に基づく実験テ゛ータに使用した基材を
それぞれ示す図である。FIG. 2 is a diagram showing substrates used for experimental data based on photocatalytic treatment with a photocatalytic coating containing anatase-type titanium dioxide, respectively.
【図3】図3の(イ)、(ロ)、(ハ)、(ニ)で示すのは、綿100%の繊
維を顕微鏡1000倍にした図であり、(イ)は繊維の図、(ロ)
は繊維に無機質塗料の溶剤でなる下塗り層を設けた図、
(ハ)は前記(ロ)を燃焼試験した図、(ニ)は下塗り層を設け
た繊維にクリアー型塗料等の透明性の溶剤でなる上塗り層を
設けた図である。る。3 (a), (b), (c), (d) of FIG. 3 is a diagram of 100% cotton fiber at a magnification of 1000 times, (a) is a diagram of the fiber, (B)
Is a diagram in which an undercoat layer made of a solvent of an inorganic paint is provided on the fiber,
(C) is a diagram obtained by performing a combustion test on (B), and (D) is a diagram in which a fiber having an undercoat layer is provided with an overcoat layer made of a transparent solvent such as a clear paint. You.
【図4】図4の(イ)、(ロ)、(ハ)、(ニ)で示すのは、テトロン50%とレー
ヨン50%の繊維を顕微鏡1000倍にした図であり、(イ)は繊維
の図、(ロ)は繊維に無機質塗料の溶剤でなる下塗り層を
設けた図、(ハ)は前記(ロ)を燃焼試験した図、(ニ)は下塗
り層を設けた繊維にクリアー型塗料等の透明性の溶剤でなる
上塗り層を設けた図である。FIG. 4 shows (a), (b), (c), and (d) the fibers of 50% tetron and 50% rayon at a magnification of 1000 times with a microscope. Figure of fiber, (b) is a figure in which an undercoat layer made of a solvent of an inorganic paint is provided on the fiber, (c) is a figure in which the above (b) is subjected to a combustion test, (d) is a clear type FIG. 3 is a diagram in which an overcoat layer made of a transparent solvent such as a paint is provided.
【図5】図5(イ)、(ロ)は、本工程の下塗りのフローチャート図を示
す。FIGS. 5 (a) and 5 (b) show flowcharts for undercoating in this step.
【図6】図6(イ)、(ロ)は、本工程の上塗りのフローチャート図を示
す。FIGS. 6 (a) and 6 (b) show a flowchart of the overcoating in this step.
1 布地 11 穴開き 12 炭化部 2 火源 21 先端位置 3 下塗り層 4 上塗り層 41 上塗り層 5 繊維 6 形状 7 隙間 8 炭化 1 Cloth 11 Perforated 12 Carbonized part 2 Fire source 21 Tip position 3 Undercoat layer 4 Overcoat layer 41 Overcoat layer 5 Fiber 6 Shape 7 Gap 8 Carbonization
Claims (8)
又は捺染等の処理を行って、当該布地に難燃性及び/又
は防炎性を付与する構成とした無機質塗料を用いた布
地。1. A fabric using an inorganic paint configured to impregnate, coat, spray or print an inorganic paint on the fabric to impart flame retardancy and / or flame resistance to the fabric. .
又は捺染等の処理、及び光触媒処理を行って、当該布地
に難燃性及び/又は防炎性並びに光触媒性を付与する構
成とした無機質塗料を用いた布地。2. A structure for impregnating, coating, spraying or printing an inorganic paint on a fabric, and performing a photocatalytic treatment to impart flame retardancy and / or flame resistance and photocatalytic property to the fabric. Fabrics made using inorganic paint.
又は捺染等の処理、及び抗菌処理を行って、当該布地に
難燃性及び/又は防炎性並びに抗菌性を付与する構成と
した無機質塗料を用いた布地。3. A structure for impregnating, coating, spraying or printing an inorganic paint on a fabric and performing an antibacterial treatment to impart flame retardancy and / or flame resistance and antibacterial property to the fabric. Fabrics made using inorganic paint.
又は捺染等の処理を二回行う構成の請求項1、2、又は請求
項3に記載の無機質塗料を用いた布地。4. A fabric using the inorganic paint according to claim 1, wherein the fabric is impregnated, coated, sprayed or printed twice with the inorganic paint.
付、噴霧又は捺染等の処理を行って処理糸を生成し、こ
の処理糸を使用して布地を構成し、この布地に難燃性及
び/又は防炎性を付与する構成とした無機質塗料を用い
た布地。5. A process for producing a treated yarn by impregnating, coating, spraying, or printing an inorganic paint on a fabric-constituting yarn to form a treated yarn. A fabric using an inorganic paint which is configured to impart flammability and / or flame resistance.
付、噴霧又は捺染等の処理、及び光触媒処理を行って処
理糸を生成し、この処理糸を使用して布地を構成し、こ
の布地に難燃性及び/又は防炎性並びに光触媒性を付与
する構成とした無機質塗料を用いた布地。6. A yarn for fabric construction is impregnated with an inorganic paint, applied, sprayed or printed, and subjected to a photocatalytic treatment to produce a treated yarn, and the treated yarn is used to constitute a fabric; A fabric using an inorganic paint which is configured to impart flame retardancy and / or flame resistance and photocatalytic property to the fabric.
付、噴霧又は捺染等の処理、及び抗菌処理を行って処理
糸を生成し、この処理糸を使用して布地を構成し、この
布地に難燃性及び/又は防炎性並びに抗菌性を付与する
構成とした無機質塗料を用いた布地。7. A yarn for fabric construction is impregnated with an inorganic paint, subjected to a treatment such as application, spraying or printing, and an antibacterial treatment to produce a treated yarn, and the treated yarn is used to constitute a fabric; A fabric using an inorganic paint which is configured to impart flame retardancy and / or flame resistance and antibacterial property to the fabric.
付、噴霧又は捺染等の処理を二回行う構成の請求項5、6
又は請求項7に記載の無機質塗料を用いた布地。8. The method according to claim 5, wherein the fabric forming yarn is subjected to two treatments such as impregnation, application, spraying or printing with an inorganic paint.
Or a fabric using the inorganic paint according to claim 7.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11120612A JP2000314079A (en) | 1999-04-27 | 1999-04-27 | Cloth using inorganic coating material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11120612A JP2000314079A (en) | 1999-04-27 | 1999-04-27 | Cloth using inorganic coating material |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2000314079A true JP2000314079A (en) | 2000-11-14 |
Family
ID=14790564
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11120612A Pending JP2000314079A (en) | 1999-04-27 | 1999-04-27 | Cloth using inorganic coating material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2000314079A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2790914A1 (en) * | 2011-12-16 | 2014-10-22 | Saint-Gobain Placo | Fire-proof illuminating web, fire-proof illuminating structure, their manufacturing processes and their use |
EP3916043A1 (en) * | 2020-05-21 | 2021-12-01 | Goodrich Corporation | Disinfecting touch surfaces within aircraft |
-
1999
- 1999-04-27 JP JP11120612A patent/JP2000314079A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2790914A1 (en) * | 2011-12-16 | 2014-10-22 | Saint-Gobain Placo | Fire-proof illuminating web, fire-proof illuminating structure, their manufacturing processes and their use |
EP3916043A1 (en) * | 2020-05-21 | 2021-12-01 | Goodrich Corporation | Disinfecting touch surfaces within aircraft |
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