IT1282364B1 - Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefine - Google Patents
Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefineInfo
- Publication number
- IT1282364B1 IT1282364B1 IT96MI000057A ITMI960057A IT1282364B1 IT 1282364 B1 IT1282364 B1 IT 1282364B1 IT 96MI000057 A IT96MI000057 A IT 96MI000057A IT MI960057 A ITMI960057 A IT MI960057A IT 1282364 B1 IT1282364 B1 IT 1282364B1
- Authority
- IT
- Italy
- Prior art keywords
- olefins
- alpha
- polymerization
- catalyst
- contact
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000004711 α-olefin Substances 0.000 title abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001398 aluminium Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT96MI000057A IT1282364B1 (it) | 1996-01-16 | 1996-01-16 | Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefine |
| EP96119855A EP0785220B1 (en) | 1996-01-16 | 1996-12-11 | Supported metallocene catalyst for the (co)polymerization of alpha-olefins |
| AT96119855T ATE178076T1 (de) | 1996-01-16 | 1996-12-11 | Metallocen-trägerkatalysator für die alpha- olefinen-(co)polymerisation |
| ES96119855T ES2130737T3 (es) | 1996-01-16 | 1996-12-11 | Catalizador de metaloceno soportado para la (co)polimerizacion de alfa-olefinas. |
| DE69601857T DE69601857T2 (de) | 1996-01-16 | 1996-12-11 | Metallocen-Trägerkatalysator für die Alpha-Olefinen-(Co)Polymerisation |
| DK96119855T DK0785220T3 (da) | 1996-01-16 | 1996-12-11 | Båret metallocenkatalysator til (co)polymerisation af alfa-olefiner |
| US08/777,074 US5919723A (en) | 1996-01-16 | 1996-12-30 | Supported metallocene catalyst for the (co) polymerization of alpha-olefins |
| JP9005832A JPH09194523A (ja) | 1996-01-16 | 1997-01-16 | アルファ−オレフィン（共）重合用担持メタロセン触媒 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT96MI000057A IT1282364B1 (it) | 1996-01-16 | 1996-01-16 | Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI960057A0 ITMI960057A0 (it) | 1996-01-16 |
| ITMI960057A1 ITMI960057A1 (it) | 1997-07-16 |
| IT1282364B1 true IT1282364B1 (it) | 1998-03-20 |
Family
ID=11372911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT96MI000057A IT1282364B1 (it) | 1996-01-16 | 1996-01-16 | Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefine |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5919723A (it) |
| EP (1) | EP0785220B1 (it) |
| JP (1) | JPH09194523A (it) |
| AT (1) | ATE178076T1 (it) |
| DE (1) | DE69601857T2 (it) |
| DK (1) | DK0785220T3 (it) |
| ES (1) | ES2130737T3 (it) |
| IT (1) | IT1282364B1 (it) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19703478A1 (de) * | 1997-01-31 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung eines Matallocen-Katalysatorsystems |
| US6294494B1 (en) * | 1998-12-18 | 2001-09-25 | Phillips Petroleum Company | Olefin polymerization processes and products thereof |
| EP1190767A4 (en) * | 1999-05-06 | 2005-03-09 | Idemitsu Kosan Co | ADSORBENTS OF STYRENE POLYMERS |
| CN1217733C (zh) * | 1999-12-16 | 2005-09-07 | 菲利浦石油公司 | 有机金属化合物催化剂 |
| US20020037979A1 (en) * | 1999-12-28 | 2002-03-28 | Robert Charles Job | Mixed ziegler/metallocene catalysts for the production of bimodal polyolefins |
| WO2004055062A1 (en) * | 2002-12-17 | 2004-07-01 | O & D Trading Limited | Supported oftien polymerization catalyst |
| US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| EP2099873B1 (en) * | 2006-12-07 | 2015-11-04 | Grace GmbH & Co. KG | Matting agent |
| GB201012273D0 (en) * | 2010-07-22 | 2010-09-08 | Ineos Mfg Belguim Nv | Polymer compositon |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3135809A (en) * | 1960-07-21 | 1964-06-02 | Southern Res Inst | Isomerization process |
| CA1218181A (en) * | 1983-04-21 | 1987-02-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyethylene composition |
| TW198726B (it) * | 1989-12-29 | 1993-01-21 | Mitsui Petroleum Chemicals Ind | |
| IT1251463B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Catalizzatore per la (co)polimerizzazione dell'etilene |
| IT1250706B (it) * | 1991-07-25 | 1995-04-21 | Enichem Polimeri | Catalizzatore per la polimerizzazione di olefine |
| IT1255365B (it) * | 1992-09-15 | 1995-10-31 | Enichem Polimeri | Catalizzatore e procedimento per la polimerizzazione di alfa-olefine |
| IT1256603B (it) * | 1992-10-30 | 1995-12-12 | Enichem Polimeri | Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine |
| US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| ES2150529T3 (es) * | 1994-04-07 | 2000-12-01 | Bp Chem Int Ltd | Procedimiento de polimerizacion. |
| US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
-
1996
- 1996-01-16 IT IT96MI000057A patent/IT1282364B1/it active IP Right Grant
- 1996-12-11 AT AT96119855T patent/ATE178076T1/de active
- 1996-12-11 EP EP96119855A patent/EP0785220B1/en not_active Expired - Lifetime
- 1996-12-11 DE DE69601857T patent/DE69601857T2/de not_active Expired - Lifetime
- 1996-12-11 DK DK96119855T patent/DK0785220T3/da active
- 1996-12-11 ES ES96119855T patent/ES2130737T3/es not_active Expired - Lifetime
- 1996-12-30 US US08/777,074 patent/US5919723A/en not_active Expired - Lifetime
-
1997
- 1997-01-16 JP JP9005832A patent/JPH09194523A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69601857T2 (de) | 1999-07-29 |
| ES2130737T3 (es) | 1999-07-01 |
| ITMI960057A0 (it) | 1996-01-16 |
| DE69601857D1 (de) | 1999-04-29 |
| ITMI960057A1 (it) | 1997-07-16 |
| EP0785220B1 (en) | 1999-03-24 |
| EP0785220A1 (en) | 1997-07-23 |
| ATE178076T1 (de) | 1999-04-15 |
| DK0785220T3 (da) | 1999-07-19 |
| US5919723A (en) | 1999-07-06 |
| JPH09194523A (ja) | 1997-07-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted |