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IT1262524B - PROCEDURE FOR IMPROVING THE CHARACTERISTICS OF COMBUSTIBLE OILS, IN PARTICULAR OF BIOMASS PYROLYSIS OILS - Google Patents

PROCEDURE FOR IMPROVING THE CHARACTERISTICS OF COMBUSTIBLE OILS, IN PARTICULAR OF BIOMASS PYROLYSIS OILS

Info

Publication number
IT1262524B
IT1262524B ITFI930140A ITFI930140A IT1262524B IT 1262524 B IT1262524 B IT 1262524B IT FI930140 A ITFI930140 A IT FI930140A IT FI930140 A ITFI930140 A IT FI930140A IT 1262524 B IT1262524 B IT 1262524B
Authority
IT
Italy
Prior art keywords
oils
improving
pyrolysis
combustible
procedure
Prior art date
Application number
ITFI930140A
Other languages
Italian (it)
Inventor
Marco Maltagliati
Original Assignee
Marco Maltagliati
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Marco Maltagliati filed Critical Marco Maltagliati
Priority to ITFI930140A priority Critical patent/IT1262524B/en
Publication of ITFI930140A0 publication Critical patent/ITFI930140A0/en
Priority to BR9407146A priority patent/BR9407146A/en
Priority to PCT/IT1994/000120 priority patent/WO1995003374A1/en
Priority to EP94923048A priority patent/EP0710269A1/en
Priority to CN94192847A priority patent/CN1127518A/en
Priority to AU72750/94A priority patent/AU7275094A/en
Publication of ITFI930140A1 publication Critical patent/ITFI930140A1/en
Application granted granted Critical
Publication of IT1262524B publication Critical patent/IT1262524B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B01J19/085—Electron beams only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B19/00—Heating of coke ovens by electrical means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894—Processes carried out in the presence of a plasma
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Microbiology (AREA)
  • Fats And Perfumes (AREA)
  • Processing Of Solid Wastes (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invenzione riguarda un procedimento per il miglioramento delle caratteristiche chimico-fisiche e tecnologiche di oli combustibili in particolare di oli da pirolisi di biomasse secondo il quale gli oli derivati dalla pirolisi, in fase liquida o vapore vengono irradiati con elettroni di energie comprese tra 0.055 e 1 MeV. Preferibilmente gli elettroni necessari per l'irraggiamento vengono generati con un acceleratore elettrostatico di elettroni. Una sostanza ausiliaria fornitrice di idrogeno, quale il metano, eventualmente pre-irradiata, può essere iniettata nel flusso liquido o vapore di detti oli. L'invenzione riguarda anche un impianto perfezionato per la pirolisi di biomasse incorporante detta fase di irraggiamento con elettroni.(FIG.1).The invention relates to a process for improving the chemical-physical and technological characteristics of combustible oils, in particular of oils from pyrolysis of biomass, according to which the oils derived from pyrolysis, in the liquid or vapor phase, are irradiated with electrons of energies ranging from 0.055 and 1 MeV. Preferably the electrons needed for radiation are generated with an electrostatic electron accelerator. An auxiliary hydrogen supplying substance, such as methane, possibly pre-irradiated, can be injected into the liquid or vapor flow of said oils. The invention also relates to an improved plant for the pyrolysis of biomass incorporating said electron irradiation phase (FIG.1).

ITFI930140A 1993-07-23 1993-07-23 PROCEDURE FOR IMPROVING THE CHARACTERISTICS OF COMBUSTIBLE OILS, IN PARTICULAR OF BIOMASS PYROLYSIS OILS IT1262524B (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ITFI930140A IT1262524B (en) 1993-07-23 1993-07-23 PROCEDURE FOR IMPROVING THE CHARACTERISTICS OF COMBUSTIBLE OILS, IN PARTICULAR OF BIOMASS PYROLYSIS OILS
BR9407146A BR9407146A (en) 1993-07-23 1994-07-21 Process for processing fuels by electron irradiation
PCT/IT1994/000120 WO1995003374A1 (en) 1993-07-23 1994-07-21 Process for upgrading fuels by irradiation with electrons
EP94923048A EP0710269A1 (en) 1993-07-23 1994-07-21 Process for upgrading fuels by irradiation with electrons
CN94192847A CN1127518A (en) 1993-07-23 1994-07-21 A Method of Improving Fuel by Electron Irradiation
AU72750/94A AU7275094A (en) 1993-07-23 1994-07-21 Process for upgrading fuels by irradiation with electrons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITFI930140A IT1262524B (en) 1993-07-23 1993-07-23 PROCEDURE FOR IMPROVING THE CHARACTERISTICS OF COMBUSTIBLE OILS, IN PARTICULAR OF BIOMASS PYROLYSIS OILS

Publications (3)

Publication Number Publication Date
ITFI930140A0 ITFI930140A0 (en) 1993-07-23
ITFI930140A1 ITFI930140A1 (en) 1995-01-23
IT1262524B true IT1262524B (en) 1996-07-02

Family

ID=11350550

Family Applications (1)

Application Number Title Priority Date Filing Date
ITFI930140A IT1262524B (en) 1993-07-23 1993-07-23 PROCEDURE FOR IMPROVING THE CHARACTERISTICS OF COMBUSTIBLE OILS, IN PARTICULAR OF BIOMASS PYROLYSIS OILS

Country Status (6)

Country Link
EP (1) EP0710269A1 (en)
CN (1) CN1127518A (en)
AU (1) AU7275094A (en)
BR (1) BR9407146A (en)
IT (1) IT1262524B (en)
WO (1) WO1995003374A1 (en)

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DE4336503C2 (en) * 1993-10-26 1999-04-22 Deutsch Zentr Luft & Raumfahrt Device and method for performing endothermic chemical reactions
EP1061119A1 (en) 1999-06-17 2000-12-20 Abb Research Ltd. Dielectric barrier discharge cracking
ITTO20010372A1 (en) * 2001-04-13 2002-10-13 Silvio Perona DEPURATION AND REFINING PROCESS OF FLUIDS BY MEANS OF ACCELERATED ELECTRONS.
AT503517B1 (en) * 2002-11-04 2010-05-15 New Plasma Gmbh & Co Keg METHOD FOR ACTIVATING, ESPECIALLY GASOLATED, CARBON CONTAINING SUBSTANCES
SG10201609267QA (en) 2006-10-26 2017-01-27 Xyleco Inc Processing biomass
CA2740789C (en) * 2008-10-28 2018-01-02 Xyleco, Inc. Processing materials
CN102753655B (en) * 2010-01-04 2017-03-29 鲁道夫·安东尼奥·M·戈麦斯 Advanced Coal Upgrading Method for Power Stations
EP3354711A1 (en) 2011-03-29 2018-08-01 Fuelina Technologies, LLC Hybrid fuel
BR112015006992A2 (en) * 2012-10-10 2019-12-10 Xyleco Inc method of producing a treated biomass material, method and system for cooling multiple single type window blades of an electron beam accelerator
NZ706072A (en) * 2013-03-08 2018-12-21 Xyleco Inc Equipment protecting enclosures
CN103205291A (en) * 2013-04-02 2013-07-17 健雄职业技术学院 Novel composite diesel or heavy oil fuel of liquefied petroleum gas, and production technology of composite diesel or heavy oil fuel
CN103205294A (en) * 2013-04-02 2013-07-17 健雄职业技术学院 Composite gasoline fuel based on nano-coal and methane and production process of composite gasoline fuel
CN103205290A (en) * 2013-04-02 2013-07-17 健雄职业技术学院 Novel composite gasoline fuel of liquefied petroleum gas and production technology of composite gasoline fuel
CN103205295B (en) * 2013-04-02 2014-10-08 健雄职业技术学院 Composite diesel or heavy oil fuel of novel methane and production technology thereof
CN103205292A (en) * 2013-04-19 2013-07-17 杨泊宁 Production process and formula of novel methanol composite gasoline fuel
CN103484147B (en) * 2013-09-25 2015-08-05 西南石油大学 A kind of plasma-catalytic is worked in coordination with viscous crude and is fallen sticking method
BR112017011857B1 (en) 2014-12-03 2022-05-17 Drexel University Method for incorporating a gaseous hydrocarbon into a liquid hydrocarbon
CN106057267B (en) * 2015-05-28 2018-11-30 官爱平 Energy supposition substance modification platform and its method of modifying
CN108291159A (en) * 2015-11-23 2018-07-17 沙特基础工业全球技术有限公司 Method, gasoline elevator and gasoline for enhancing gasoline octane elevator
KR101772165B1 (en) * 2015-12-08 2017-08-28 연세대학교 원주산학협력단 Method for manufacturing biocrude-oil by torrefaction and fast pyrolysis
CN109632847B (en) * 2019-01-11 2022-05-24 杨军 Method for measuring ash content of coal by using X-ray of medical linear accelerator
CN114672335B (en) * 2022-04-25 2023-06-02 南京工业大学 A device for liquefying biomass with rotating tooth-shaped electrode discharge and heterogeneous catalyst

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CH614132A5 (en) * 1975-09-30 1979-11-15 Thagard Technology Co High temp. reactor
US4678860A (en) * 1985-10-04 1987-07-07 Arizona Board Of Regents Process of producing liquid hydrocarbon fuels from biomass
JPS62250933A (en) * 1986-04-24 1987-10-31 Ebara Corp Exhaust gas treatment method and device using electron beam irradiation
KR880010810A (en) * 1987-03-18 1988-10-24 제이.엘.더머 Waste disposal system
US5181998A (en) * 1989-12-27 1993-01-26 Exxon Research And Engineering Company Upgrading of low value hydrocarbons using a hydrogen donor and microwave radiation
US5256854A (en) * 1990-12-18 1993-10-26 Massachusetts Institute Of Technology Tunable plasma method and apparatus using radio frequency heating and electron beam irradiation

Also Published As

Publication number Publication date
ITFI930140A0 (en) 1993-07-23
WO1995003374A1 (en) 1995-02-02
CN1127518A (en) 1996-07-24
EP0710269A1 (en) 1996-05-08
AU7275094A (en) 1995-02-20
BR9407146A (en) 1996-09-17
ITFI930140A1 (en) 1995-01-23

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Legal Events

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TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19960628