IL107958A - Components of spherical catalysts for the polymerization of olefins in their preparation and catalysts containing them - Google Patents

Components of spherical catalysts for the polymerization of olefins in their preparation and catalysts containing them

Info

Publication number: IL107958A
Authority: IL; Israel
Prior art keywords: compound; alkyl; carbon atoms; polymerization; olefins
Prior art date: 1992-12-11

Application number

IL10795893A

Other languages

English (en)

Hebrew (he)

Other versions

IL107958A0 (en

Original Assignee

Montell Technology Company Bv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-11

Filing date

1993-12-09

Publication date

1998-09-24

1993-12-09 Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv

1994-04-12 Publication of IL107958A0 publication Critical patent/IL107958A0/xx

1998-09-24 Publication of IL107958A publication Critical patent/IL107958A/en

Links

238000006116 polymerization reaction Methods 0.000 title claims abstract description 26
150000001336 alkenes Chemical class 0.000 title claims abstract description 15
239000003054 catalyst Substances 0.000 title claims description 42
238000002360 preparation method Methods 0.000 title claims description 13
150000001875 compounds Chemical class 0.000 claims abstract description 38
238000000034 method Methods 0.000 claims abstract description 36
-1 magnesium halide Chemical class 0.000 claims abstract description 25
239000010936 titanium Substances 0.000 claims abstract description 23
239000011148 porous material Substances 0.000 claims abstract description 19
239000011777 magnesium Substances 0.000 claims abstract description 18
150000003609 titanium compounds Chemical class 0.000 claims abstract description 16
229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
229910052736 halogen Inorganic materials 0.000 claims abstract description 10
238000004438 BET method Methods 0.000 claims abstract description 8
150000002367 halogens Chemical class 0.000 claims abstract description 5
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 30
125000004432 carbon atom Chemical group C* 0.000 claims description 24
229910001629 magnesium chloride Inorganic materials 0.000 claims description 15
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 12
229910052719 titanium Inorganic materials 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 11
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 11
229910003074 TiCl4 Inorganic materials 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 10
125000000753 cycloalkyl group Chemical group 0.000 claims description 10
150000005840 aryl radicals Chemical class 0.000 claims description 9
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
239000004215 Carbon black (E152) Substances 0.000 claims description 8
229930195733 hydrocarbon Natural products 0.000 claims description 8
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 8
229910052753 mercury Inorganic materials 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 7
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
150000004756 silanes Chemical class 0.000 claims description 3
150000007513 acids Chemical class 0.000 claims description 2
150000001993 dienes Chemical class 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
150000002430 hydrocarbons Chemical class 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims 4
150000007860 aryl ester derivatives Chemical class 0.000 claims 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
229910052760 oxygen Inorganic materials 0.000 claims 1
239000001301 oxygen Substances 0.000 claims 1
239000007787 solid Substances 0.000 abstract description 11
239000011949 solid catalyst Substances 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 24
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 21
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 20
239000005977 Ethylene Substances 0.000 description 20
229920000642 polymer Polymers 0.000 description 16
238000011282 treatment Methods 0.000 description 15
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
238000003756 stirring Methods 0.000 description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
230000000877 morphologic effect Effects 0.000 description 6
239000002245 particle Substances 0.000 description 5
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
238000005406 washing Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
229920001903 high density polyethylene Polymers 0.000 description 4
239000004700 high-density polyethylene Substances 0.000 description 4
229920000092 linear low density polyethylene Polymers 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
239000004711 α-olefin Substances 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
229920005606 polypropylene copolymer Polymers 0.000 description 2
238000004062 sedimentation Methods 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
238000007669 thermal treatment Methods 0.000 description 2
IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
108010007666 IMP cyclohydrolase Proteins 0.000 description 1
102100020796 Inosine 5'-monophosphate cyclohydrolase Human genes 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
241000786363 Rhampholeon spectrum Species 0.000 description 1
229910003910 SiCl4 Inorganic materials 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
239000004708 Very-low-density polyethylene Substances 0.000 description 1
238000002083 X-ray spectrum Methods 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
150000008378 aryl ethers Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
229920001198 elastomeric copolymer Polymers 0.000 description 1
229920013728 elastomeric terpolymer Polymers 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
238000007429 general method Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000004707 linear low-density polyethylene Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000035939 shock Effects 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
238000012725 vapour phase polymerization Methods 0.000 description 1
229920001866 very low density polyethylene Polymers 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Emergency Medicine (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

IL10795893A 1992-12-11 1993-12-09 Components of spherical catalysts for the polymerization of olefins in their preparation and catalysts containing them IL107958A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ITMI922822A IT1256648B (it)	1992-12-11	1992-12-11	Componenti e catalizzatori per la polimerizzazione delle olefine

Publications (2)

Publication Number	Publication Date
IL107958A0 IL107958A0 (en)	1994-04-12
IL107958A true IL107958A (en)	1998-09-24

Family

ID=11364444

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL10795893A IL107958A (en)	1992-12-11	1993-12-09	Components of spherical catalysts for the polymerization of olefins in their preparation and catalysts containing them

Country Status (18)

Country	Link
US (1)	US6388028B2 (fi)
EP (1)	EP0601525B1 (fi)
JP (1)	JP4023833B2 (fi)
KR (1)	KR100289267B1 (fi)
CN (2)	CN1034580C (fi)
AT (1)	ATE176676T1 (fi)
AU (1)	AU673551B2 (fi)
BR (1)	BR9305019A (fi)
CA (1)	CA2111308A1 (fi)
DE (1)	DE69323478T2 (fi)
ES (1)	ES2129063T3 (fi)
FI (1)	FI112240B (fi)
IL (1)	IL107958A (fi)
IT (1)	IT1256648B (fi)
MX (1)	MX9307843A (fi)
NO (1)	NO302825B1 (fi)
RU (1)	RU2126420C1 (fi)
ZA (1)	ZA939210B (fi)

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1264679B1 (it)	1993-07-07	1996-10-04	Spherilene Srl	Catalizzatori per la (co)polimerizzazione di etilene
IT1275573B (it) *	1995-07-20	1997-08-07	Spherilene Spa	Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
KR100598444B1 (ko)	1998-03-05	2006-07-10	바셀 테크놀로지 캄파니 비이브이	폴리부텐-1 (공)중합체 및 그것의 제조방법
SG73622A1 (en) *	1998-03-11	2000-06-20	Sumitomo Chemical Co	Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
ATE258192T1 (de)	1998-05-06	2004-02-15	Basell Poliolefine Spa	Katalysatorbestandteile für die olefinpolymerisation
TW475934B (en)	1998-06-27	2002-02-11	Basell Technology Co Bv	Process for the production of Α-olefin polymer
IT1301990B1 (it)	1998-08-03	2000-07-20	Licio Zambon	Catalizzatori per la polimerizzazione delle olefine.
KR20010033872A (ko)	1998-11-04	2001-04-25	간디 지오프레이 에이치.	올레핀의 중합을 위한 성분 및 촉매
CN1128822C (zh)	1999-02-26	2003-11-26	中国石油化工集团公司	一种烯烃聚合催化剂载体的制备方法
KR20010043615A (ko)	1999-03-15	2001-05-25	바셀 테크놀로지 컴퍼니 비.브이.	올레핀 중합용 촉매성분 및 촉매
ID28200A (id)	1999-04-15	2001-05-10	Basell Technology Co Bv	Komponen katalis untuk polimerisasi olefin
HUP0200516A2 (en) *	1999-06-18	2002-07-29	Basell Technology Co Bv	Catalyst components for the polymerization of olefins and catalysts therefrom obtained
CN1170859C (zh)	1999-09-10	2004-10-13	巴塞尔技术有限公司	烯烃聚合催化剂
GB0001914D0 (en)	2000-01-27	2000-03-22	Borealis Polymers Oy	Catalyst
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1992
- 1992-12-11 IT ITMI922822A patent/IT1256648B/it active IP Right Grant
1993
- 1993-12-06 AT AT93119646T patent/ATE176676T1/de not_active IP Right Cessation
- 1993-12-06 EP EP93119646A patent/EP0601525B1/en not_active Expired - Lifetime
- 1993-12-06 ES ES93119646T patent/ES2129063T3/es not_active Expired - Lifetime
- 1993-12-06 DE DE69323478T patent/DE69323478T2/de not_active Expired - Lifetime
- 1993-12-08 RU RU93054528A patent/RU2126420C1/ru active
- 1993-12-08 ZA ZA939210A patent/ZA939210B/xx unknown
- 1993-12-08 JP JP30802093A patent/JP4023833B2/ja not_active Expired - Fee Related
- 1993-12-08 AU AU52295/93A patent/AU673551B2/en not_active Ceased
- 1993-12-09 IL IL10795893A patent/IL107958A/en not_active IP Right Cessation
- 1993-12-09 KR KR1019930027080A patent/KR100289267B1/ko not_active IP Right Cessation
- 1993-12-09 NO NO934496A patent/NO302825B1/no unknown
- 1993-12-10 FI FI935550A patent/FI112240B/fi not_active IP Right Cessation
- 1993-12-10 BR BR9305019A patent/BR9305019A/pt not_active IP Right Cessation
- 1993-12-10 MX MX9307843A patent/MX9307843A/es not_active IP Right Cessation
- 1993-12-11 CN CN93112859A patent/CN1034580C/zh not_active Expired - Fee Related
- 1993-12-13 CA CA002111308A patent/CA2111308A1/en not_active Abandoned
1995
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1997
- 1997-06-19 US US08/878,681 patent/US6388028B2/en not_active Expired - Lifetime

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Publication number	Publication date
CN1127262A (zh)	1996-07-24
ES2129063T3 (es)	1999-06-01
NO302825B1 (no)	1998-04-27
BR9305019A (pt)	1994-07-05
CN1034580C (zh)	1997-04-16
IL107958A0 (en)	1994-04-12
AU5229593A (en)	1994-06-23
ZA939210B (en)	1994-08-08
DE69323478T2 (de)	1999-08-19
AU673551B2 (en)	1996-11-14
KR100289267B1 (ko)	2001-05-02
RU2126420C1 (ru)	1999-02-20
JPH07300507A (ja)	1995-11-14
DE69323478D1 (de)	1999-03-25
US6388028B2 (en)	2002-05-14
ATE176676T1 (de)	1999-02-15
FI112240B (fi)	2003-11-14
ITMI922822A0 (it)	1992-12-11
CA2111308A1 (en)	1994-06-12
EP0601525A1 (en)	1994-06-15
CN1089622A (zh)	1994-07-20
NO934496D0 (no)	1993-12-09
IT1256648B (it)	1995-12-12
KR940014457A (ko)	1994-07-18
FI935550L (fi)	1994-06-12
EP0601525B1 (en)	1999-02-10
US20010011060A1 (en)	2001-08-02
CN1041525C (zh)	1999-01-06
FI935550A0 (fi)	1993-12-10
JP4023833B2 (ja)	2007-12-19
ITMI922822A1 (it)	1994-06-11
MX9307843A (es)	1994-07-29
NO934496L (no)	1994-06-13

Publication	Publication Date	Title
EP0601525B1 (en)	1999-02-10	Components and catalysts for the polymerization of olefins
AU655526B2 (en)	1994-12-22	Components and catalysts for the polymerization of olefins
KR100268816B1 (ko)	2000-10-16	올레핀 중합용 성분 및 촉매
KR100676661B1 (ko)	2007-01-31	올레핀 중합용 촉매 성분 및 이로부터 수득된 촉매
EP1032600B1 (en)	2002-10-09	Pre-polymerized catalyst components for the polymerization of olefins
US20030040427A1 (en)	2003-02-27	Pre-polymerized catalyst components for the polymerization of olefins
EP0601524B1 (en)	1998-07-22	Process for the preparation of (co)polymers of ethylene having a broad molecular weight distribution
EP1232193B1 (en)	2007-02-07	Catalyst for the polymerization of olefins
WO2004005359A1 (en)	2004-01-15	Catalyst system for the polymerization of olefins
EP0604846B1 (en)	1997-10-29	Components and catalysts for the polymerization of olefins
MXPA00003277A (en)	2001-05-07	Pre-polymerized catalyst components for the polymerization of olefins

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