IL103718A - Method of producing a three-dimensional profile in a body - Google Patents
Method of producing a three-dimensional profile in a bodyInfo
- Publication number
- IL103718A IL103718A IL10371892A IL10371892A IL103718A IL 103718 A IL103718 A IL 103718A IL 10371892 A IL10371892 A IL 10371892A IL 10371892 A IL10371892 A IL 10371892A IL 103718 A IL103718 A IL 103718A
- Authority
- IL
- Israel
- Prior art keywords
- layer
- stretchable
- body according
- profile
- mould
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/14—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
- B29C51/145—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets having at least one layer of textile or fibrous material combined with at least one plastics layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0094—Geometrical properties
- B29K2995/0097—Thickness
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Description
A METHOD OF PRODUCING A THREE-DIMENSIONAL PROFILE IN A BODY PRODUCTION EXPERTS LIMITED C: 15851 A method of producing a three-dimensional profile in a body The present invention relates to a method of producing a three-dimensional profile on an exterior surface of a body, which body is resilient and comprises a thermoplastic layer and a stretchable layer, and to the product of the method.
It is known to mould thermoplastic into particular predetermined shapes, and it is further known to cover the thermoplastic with a layer of material. However, the known methods of making three-dimensional bodies of this type, are limited in that the bodies which are formed cannot display complex or intricate profiles. Previously, if a three-dimensional profile with a complex or intricate profile was required, it was necessary to use injection moulding techniques. However, an injection moulding techniques could not produce articles with the look and feel of a thermoformed article .
According to the present invention there is provided a method of producing a three-dimensional profile on an exterior surface of a body, which body comprises a thermoplastics layer and a stretchable layer bonded to the exterior surface; the thermoplastics layer being thermoformed in a mould to produce the profile; the stretchable layer being such and being bonded over substantially the entire exterior surface of the thermoplastics layer, in such a way that the profile formed is highly defined.
The profile formed by the method of the present invention is capable of displaying sharp contours with the angle of the exterior surface changing greatly over a short distance of the surface. This enables the profile to be very detailed, that is highly defined. 103718/2 2 The precise thermoplastic used will vary depending upon the physical conditions employed during the thermoforming process. The thermoplastic must be of such a type that it can be moulded to the exact profile of the mould and after it has been moulded, the thermoplastic must be removable from the mould without permanent deformation of the profile formed by the mould. Preferably, when thermoforming process forms the profile, and the mould is removed, the thermoplastic is permanently deformed and does not have a tendency to spring into another shape. Preferably, the thermoplastics layer is a foam, preferably having a nominal density of between 20 and 40 Kg/m3, preferably between 29 and 36 Kg/ m3, and in a preferred embodiment 33 Kg m3, and the foam has a thickness of between 5 and 11 mm, preferably 8 mm, prior to moulding. The foam is preferably made of polyethylene.
Preferably, the thermoforming technigue comprises a low-temperature process, wherein the thermoplastics layer is only heated to between 180°C and 220°C, preferably 200°C. Preferably, the thermoplastics layer is preheated to its optimum temperature, before being placed in the mould for approximately ten seconds. The profile is formed within a mould in approximately one minute, the mould itself preferably being unheated.
The stretchable material is preferably an elastomeric material. The elastomeric material maybe lycra® (registered Trade Mark of DuPont) and may have a density between 50 and 250 gro m~^.
A third layer of material may be bonded to the face of the thermoplastics layer opposite from the stretchable layer. The third layer may be made from non-woven polypropylene which can weigh between 400 and 200 gm m . Alternatively, the third layer may be made from Nylon 6 , 6. The third layer of material may be used to mount the body onto another article such as a bag or an article of clothing.
It is often preferable to have all the stretchable layer and the third layer bonded to the thermoplastics layer to form a lamina prior to the thermoplastics layer being thermoformed. In a preferred embodiment the lamina is made before the stretchable layer is printed. In order to prevent the bonding between layers deteriorating during thermoforming, and that the stretchable layer does not adhere to the mould or be stretched in such a way to cause distortion of the desired profile after the body has been removed from the mould.
In order to achieve adequate bonding between the thermoplastic layer and the stretchable; layer so that a high definition profile is formed, the angle' of the warp and weft of the stretchable material must correspond to the surface structure of the thermoplastic layer. In the case where the thermoplastics layer comprises polyethylene foam and stretchable layer comprises lycra® (registered Trade Mark of DuPont) . Preferably, the stretchable layer is knitted and is preferably formed os a polyester/lycra® mix. The polyester may exceed 50%. of the mix. In a preferred embodiment the lycra® is made from, approximately, 91.75% Polyester and 8.25% Lycra®, ± 5% The material weighs between 140 and 180 gms m~2, preferably 160 gms m"2 and has about 28 CPC (Courses Per Centimetre) and about 16 WPC (Wales Per Centimetre) . The stretchable material is capable of stretching, approximately, 80% in length or width.
Preferably, a coloured image, such as a cartoon face, is formed on the profile. This image may be formed .on the stretchable layer after the stretchable layer is bonded to the thermoplastic layer and before moulding. The image may be formed with silk screen printing. The image formed by the silk screen printing may be deformed from the image that is desired on the profile, so that when the profile is formed by moulding the relative distance between these parts of the image are altered from the flat screen print, to produce the desired image in three-dimensions on the profile.
Alternatively the image may be applied to the body after the profile is formed by spraying or painting.
Preferred embodiments of the invention will now be described by way of example, with reference to the attached drawing, where: Figure 1, depicts a sectioned side view of a body formed by the present invention, attached to another article.
The body (10) includes a sheet-like layer in the form of a thermoplastic member, being deformed so to have a three-dimensional profile with an interior and an exterior surface, and is adapted to be attached to another article (5) about its periphery (4). The inside layer (3) of non-woven polypropylene is glued to the exterior surface of the body (5). The thermoplastic layer (2) is moulded to produce a high definition profile on its exterior face (2a). A stretchable layer (1) is connected to substantially all the thermoplastic layer and displays a high definition surface (la). Elastomers, such as lycra®, are used as the stretchable layer, as this fabric has very consistent and precise waft and weft angles which allow it to be bonded to the foam even after the foam (2) has been moulded to produce highly defined contours on its exterior surface ( 2a) .
The stretchable layer and the third layer are bonded to the thermoplastic layer before the profile is formed in the thermoplastics layer.
To form the highly defined profile: 1) A flat layer (2) of the foam is covered on one side with lycra® layer (1) and on the other side with a third layer (3), to form a flat laminate (10). The three layers (1, 2, 3) are adhered by means of a glue. The glue must have the ability of stretching with the two layers of material whilst maintaining the adhesion between the layers, for example XIRO. 103,718/2 A deformed image is printed onto the laminate by a silk screen process. The process involves placing a mask which over the laminate (10) and using a vacuum bed to adhere the mask to the laminate which needs to be sprayed. The deformed image is applied by spraying through the mask. It is also possible to use tampo (pad) printing, vacuum spraying, heat transfer, cold transfer, dye-sublimation or multi-colour thermoform printing methods, but techniques which involve rollers and/or pressing have been found not to work. It should be noted that the inks used in applying the deformed image cannot be dried by heat treatment as this would lead to distortion of the laminate due to expansion of materials therein, but the inks must also be stable during the ensuing thermoforming process.
The laminate (10) in then heated in a jig in order that the foam layer (2) reaches a high enough temperature to be thermoformed, normally about 200°C.
The heated laminate (10) is then placed in a press. The laminate (10) is then pressed between a mould, with the female mould on the lycra® layer (1) side of the laminate (10) and the male mould on the third layer (3) side of the laminate (10). The female mould produces an exterior three-dimensional image in the laminate (10). The male mould may be shaped to be an exact match for the female mould, or may comprise a substantially flat surface, or may comprise a substantially flat surface with opening that allow through projection( s ) to apply pressure to certain area(s) of the laminate during the pressing of the mould, approximately one minute.
The foam layer (2) expands when heated in the thermoforming process described above. The foam layer (2) expands mainly in one direction, but other expansions and/or contractions of the layer will normally also occur. Also, the lycra® layer (1) will stretch with the expansion of the foam layer (2). The present process produces a three-dimensional profile with a printed image. The various colours of the printed image in the finished article are required to be over certain predetermined parts of the three-dimensional profile. Therefore the deformed image printed on lycra® layer (1) of the laminate (10) is such that when foam layer (2) expands/contracts during the thermoforming process and the lycra® layer (1) stretches the image is contorted so that the required colours are precisely over the predetermined parts of the three-dimensional profile.
In order to calculate the required deformed image for any particular three-dimensional profile with a predetermined colour pattern, it is necessary to precisely calculate all the expansions and contractions which occur to the flat laminate (10) during the thermoforming process. It will also be realised that the lycra® layer (1) must not slip over the foam layer (2) during the thermoforming process and so the glue used between the layers must retain its adhesivity during the process. Also, the orientation of the lycra® layer (1) in relation to the foam layer (2) must be predetermined, both before and after the deformed image is applied, so that the expansion/contraction of the foam layer (2) occur in the calculated directions and magnitudes. Finally the laminate (10) must be pressed in the mould in a predetermined precise orientation so that the finished article has good definition in that the colours are precisely over the predetermined area of the three-dimensional profile.
Normally, the mould is made from cast aluminium. The inks used in this process are such that they do not stick to the mould, even when heated in-the thermoforming process. The body (10) will often have upto seven colours in precise areas of the three-dimensional profile. 103718/2 In this invention the following material . may be used: Fabric a ) Stretchable layer (1) of Fabric.
The fabric will be based on either Nylon Lycra® or Polyester Lycra®. Weight of material 50/250 gm per square metre. For example: White Polyester Lycra® .
Composition: Polyester 91.75% Lycra® 8.25% Weight: 160 gms/m2 (nominal) Course per cm 28 ' Wales per cm 16 Stretch: Length: 80% Width: 80% with a 3 kg load on an extensometer . i Third layer (3) of fabric.
Non-woven polypropylene, weight from 400 to 200 gm per square metre or similar. For example: Nylon - Black or White Composition: Nylon 66 100% Courses per cm 18 Wales per cm 17 Stretch: Length: 60% Width: 180% with a 3kg load on an extensometer. c Foam layer (2) The foam is expanded polyethylene foam, with Density range of 24 to 50 kg/m3, preferably 29 to 36 kg/m3. For example, the foam is a closed Cell Cross linked expanded Polyethylene foam, with nominal density 33 kg/m3 and thickness prior to moulding 8 mm.
Alternatively, polyurethane , polyvinyl chloride or polypropylene foams can be used, all of which will have a similar density range to that described above.
Adhesives The laminate will be flame retardant and will conform to BS5665 part 2, 1989.
For example, adhesives which can be used: a) Between Lycra® layer and foam layer XIRO -2060 - 30 gsm b) Between the nylon third layer and foam layer XIRO - 2000 - 25 gsm Printing Inks The printing inks or spraying inks will conform to E.C. standard and will be to non-toxic nature.
For example: SERICOL Black Flexitex Red Flexitex ARLER Black Marlertex Red Marlertex Moulding The moulding is produced by Compression Moulding/Thermo-forming. Normally, the mould is not heated and the laminate (10) is heated prior to being moulded, which ensures that the aluminium mould does not stick to the laminate (10). However, it would be possible to use a heated mould and heat the laminate (10) in the mould provided that suitable inks were used that would not adhere to the heated mould made form a suitable material.
Obviously, a body made by this technique can be used in a number of different applications, such as images attached to bags and the like, the body could comprise the sole of a shoe. The body formed can be used anywhere that requires a high definition profile, which previously could only be formed by using thermosetting plastics or the like. 103718/2 9 The body formed in the invention is often attached to an article of clothing or similar, such as bags, wallets or hats. In such circumstances it is very important that the body can be washed. Therefore, the choice of dyes or inks used in applying the image is limited, as the image must only fade a restricted amount on washing. Also, the materials from which the body is made must not shrink or loose shape when washed. It is preferred that the bodies conform with the relevant British Standard specification or equivalent Foreign country requirement. In the embodiments described above, the bodies have been .tested and found to be meet the required standards. The recommended washing and other care instructions being: to wash as a synthetic at 40oC, Do Not Bleach, Do Not Tumble Dry, Do Not Iron.
Also, the bodies should be able to withstand mechanical and physical abuse. The described embodiment has been tested in accordance with British Standard BS5665, Parts 1 and 2, and has passed the required tests.
Claims (34)
1. A method of producing a three-dimensional profile on an exterior surface of a lamina body, the method comprising bonding a stretchable layer over substantially all of an outer surface of a thermoplastic layer, the thermoplastic layer being thermoformed in a mould to produce the profile, characterized in that the angle of the exterior surface relative to a flat plane is capable of varying sharply to produce a highly defined profile and a desired image of a plurality of colors , is formed on the non-bonded surface of the stretchable layer so that said colors are precisely over predetermined areas of the profile.
2. A method according to claim 1, wherein the body includes a third layer comprising non-woven polypropylene; the thermoplastic layer comprises polyethylene foam; the stretchable layer is knitted; characterized in that the method comprises: a. a deformed image is printed onto the stretchable layer by a silk screen process; b. bonding the stretchable layer to the exterior surface of the thermoplastic layer and bonding the third layer to the inner surface of the thermoplastic layer, thereby forming the body; c. heating the thermoplastic layer to approximately 200 degrees C for approximately ten seconds; d. moulding the body in an unheated mould for approximately 1 minute, whereby the deformed image is transformed into a desired image. 103718/2
3. A method according to claim 1 or claim 2, wherein the thermoplastic layer is substantially 0.008m thick before thermo-forming and has a density of substantially 33 Kg m ; the stretchable layer is capable of stretching substantially 80% in length or width and comprises, approximately, 91.75% polyester and 8.25% Lycra® and weighs substantially 0.16 Kg π ^, and the stretchable layer has substantially 28 CPC (Courses per centime-ter); the third layer weighs between 0.2 and 0.4 Kg m .
4. A method of producing a three-dimensional profile on an exterior surface of a body according to claim 1 or claim 3, wherein the stretchable layer is bonded to the thermoplastic layer before the thermoplastic layer is thermoformed .
5. A method of producing a three-dimensional profile on an exterior surface of a body according to any one of claims 1, 3 or 4, wherein the thermoforming process comprises a low-temperature process in which the thermoplastic layer is heated to between 180 degrees C and 220 degrees, preferably 200 degrees.
6. A method of producing a three-dimensional profile on an exterior surface of a body according to any one of claims 1, 3, 4, or 5, wherein the thermoplastic layer is preheated to its optimum temperature, before being placed in the mould for approximately ten seconds.
7. A method of producing a three-dimensional profile on an exterior surface of a body according to any one of claims 1, 3, 4, 5, or 6, wherein the profile is 'formed within a mould in approximately one minute, and the mould is unheated. 103718/2
8. A method according to any one of the preceding claims, wherein, during the said thermoforming process, the stretchable layer does not adhere to the mould and is not stretched in such a way as to cause distortion of the desired profile after the body has been removed from the mould.
9. A method according to any one of claims 1 or 3 to 8, wherein the third layer is bonded to the thermoplastics layer prior to the thermoplastics layer being thermoformed .
10. A method according to any one of claims 1 to 9 , wherein the desired image comprises a colored image, such as a cartoon face, formed on the non-bonded surface of the stretchable layer.
11. A method according to claim 10, wherein the deformed image is formed before the stretchable layer is bonded to the thermoplastic layer.
12. A method according to claim 10 or claim 11, wherein the said image is produced by silk screen printing.
13. A method according to claim 12, wherein the deformed image printed onto the stretchable layer is transformed into said desired image after the said thermoforming process.
14. A method according to claim 10, wherein the image is formed after the body has been moulded by spraying or painting. 103718/2
15. A body including a three-dimensional profile on an exterior surface of the body, which body comprises a stretchable layer and a thermoplastic layer which includes an inner and an outer surface, the thermoplastic layer being thermoformed in a mould to produce the profile, wherein the stretchable layer is bonded over substantially the entire outer surface of the thermoplastic layer and the profile is adapted so that the angle of the profile relative to a flat plane is capable of varying sharply.
16. A body according to claim 15, wherein the thermoplastic comprises a foam which, subsequent to the removal of the mould, retains the precise shape formed in a mould during the thermo-forming process.
17. A body according to claim 16, wherein the foam has a -3 density of between 20 and 40 Kg m J, preferably 33 Kg m .
18. A body according to claim 16 or 17, wherein the thermoplastic layer is between 5 and 11 mm thick, preferably 8 mm thick, prior to being thermoformed.
19. A body according to any one of claims 16 to 18, wherein the foam consists of polyethylene.
20. A body according to any one of claims 15 to 19, wherein the stretchable layer includes an elastomeric material.
21. A claim 20, wherein the elastomeric material is Lyc a (^R) ( registered Trade Mark of Dupont).
22. A body according to claim 21 or claim 22, wherein the elastomeric material has a density between 50 and 250 gm m . 103718/3
23. A body according to any one of claims 20 to 22, wherein the stretchable layer comprises an elastomeric material combined with a second material.
24. A body according to claim 23, wherein the second material is a polyester.
25. A body according to any one of claims 15 to 24, wherein the stretchable layer is knitted or woven.
26. A body according to claim 25, wherein the stretchable layer is woven and the angle of the warp and weft of the stretchable material corresponds to the surface structure of the thermoplastic layer.
27. A body according to claim 25, wherein the stretchable layer is knitted and comprises a polyester/Lycrs^ mix, in which the polyester exceeds 50% of the mix.
28. A body according to claim 25, wherein said mix com-prises, approximately, 91.75% polyester and 8.25% Lycra^.
29. A body according to claim 27 or claim 28, wherein the stretchable material weighs between 140 to 180 gms m , prefera-bly 160 gms m .
30. A body according to any one of claims 27 to 29, wherein the stretchable material comprises substantially 28 CPC (Courses per centimetre) and about 16 WPC (Wales per centimetre).
31. A body according to any one of claims 15 to 30, wherein the stretchable material is capable of stretching substantially 80% in length or width. 103718/1
32. A body according to any one of claims 15 to 31, wherein the body includes a third layer of material bonded to the inner surface of the thermoplastic layer.
33. A body according to claim 32, wherein the third layer is made from non-woven polypropylene which weighs between 400 and 200 gm m~2.
34. A body according to claim 32 or claim 33, wherein the body is connected via the third layer to an article, such as a bag or an article of clothing. For the Applicant,
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919124076A GB9124076D0 (en) | 1991-11-13 | 1991-11-13 | A method of producing a three-dimensional profile in a body |
Publications (2)
Publication Number | Publication Date |
---|---|
IL103718A0 IL103718A0 (en) | 1993-04-04 |
IL103718A true IL103718A (en) | 1995-10-31 |
Family
ID=10704539
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IL10371892A IL103718A (en) | 1991-11-13 | 1992-11-11 | Method of producing a three-dimensional profile in a body |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0623069A1 (en) |
JP (1) | JPH08501990A (en) |
AU (1) | AU2890192A (en) |
GB (1) | GB9124076D0 (en) |
IL (1) | IL103718A (en) |
WO (1) | WO1993009930A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2112744B1 (en) * | 1994-12-02 | 1998-12-01 | Porta Miguel Alives | PROCEDURE AND ARRANGEMENT FOR MODELING A THREE-DIMENSIONAL FORM ON A FABRIC. |
IT1317226B1 (en) * | 2000-04-12 | 2003-05-27 | Preformati B M C Srl | SHAPED BODY WITH A CURVED SURFACE ON WHICH IMAGES ARE REPRODUCED AND PROCEDURE FOR ITS PREPARATION |
ES2523496B2 (en) * | 2013-05-22 | 2015-08-14 | Antonio Moron De Blas, Sl | PROCEDURE FOR OBTAINING A THERMOCONFORMED ARTICLE |
ES2572731B2 (en) * | 2014-12-01 | 2016-11-16 | Antonio Morón De Blas Sl | Procedure for obtaining a thermoformed item, perfected |
US11997999B2 (en) * | 2018-10-17 | 2024-06-04 | Bushnell Holdings, Inc. | 3D articles and methods of making such articles |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3652359A (en) * | 1967-09-11 | 1972-03-28 | Stauffer Chemical Co | Process of forming upholstery |
DE2365203B2 (en) * | 1973-12-31 | 1977-02-03 | Dynamit Nobel Ag, 5210 Troisdorf | PRODUCTION OF MULTI-LAYER SHEETS, PLATES, MOLDED PARTS |
US4287143A (en) * | 1979-03-19 | 1981-09-01 | Sears Manufacturing Company | Cloth molding process |
-
1991
- 1991-11-13 GB GB919124076A patent/GB9124076D0/en active Pending
-
1992
- 1992-11-02 EP EP92922702A patent/EP0623069A1/en not_active Withdrawn
- 1992-11-02 JP JP5509053A patent/JPH08501990A/en active Pending
- 1992-11-02 AU AU28901/92A patent/AU2890192A/en not_active Abandoned
- 1992-11-02 WO PCT/GB1992/002009 patent/WO1993009930A1/en not_active Application Discontinuation
- 1992-11-11 IL IL10371892A patent/IL103718A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU2890192A (en) | 1993-06-15 |
EP0623069A1 (en) | 1994-11-09 |
IL103718A0 (en) | 1993-04-04 |
JPH08501990A (en) | 1996-03-05 |
GB9124076D0 (en) | 1992-01-02 |
WO1993009930A1 (en) | 1993-05-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4588629A (en) | Embossed fabrics to give contrasting colors | |
US4110139A (en) | Process for preparing bands or belts, particularly suitable for use as watch bands | |
KR100239311B1 (en) | Thermoforming process of luggage case and thermoplastic shell | |
US7066853B2 (en) | Method for manufacturing an inflatable ball and a ball made with the method | |
US5783133A (en) | Method for making a multilayer molded article | |
JPH09123267A (en) | Three-dimensional molding using urethane elastomer and manufacture thereof | |
IL103718A (en) | Method of producing a three-dimensional profile in a body | |
KR100390025B1 (en) | Three-dimensional printed fabric molded article and manufacturing method | |
JP2696374B2 (en) | Manufacturing equipment for synthetic resin molded products with skin material partially adhered | |
EP0500033B1 (en) | Process for producing multilayer molded article | |
US3507729A (en) | Contoured ornamentation of laminated resilient materials | |
JPS6328781B2 (en) | ||
JPH0470132B2 (en) | ||
CA1278427C (en) | Doll's head and method of fabrication | |
US5868801A (en) | Method for applying a pattern on to a thermoplastic workpiece and an object produced according to the method | |
JPH0247332B2 (en) | ||
JP3575062B2 (en) | Method for producing molded article having surface irregularities and method for producing patterned molded article | |
JPS62181111A (en) | Manufacture of composite molded form | |
JPS61220822A (en) | Manufacture of formed body bonded partially with skin member | |
JP3081977B2 (en) | Manufacturing method of multilayer molded products | |
JPS6141301B2 (en) | ||
GB2161094A (en) | Embossed fabrics | |
JPS5921305B2 (en) | Heat press molding method for laminated sheet of synthetic resin leather cover and synthetic resin foam | |
JPH01295812A (en) | Patterned injection molded product and manufacture thereof | |
ITMI20000804A1 (en) | SHAPED BODY WITH A CURVED SURFACE ON WHICH IMAGES ARE REPRODUCED AND PROCEDURE FOR ITS PREPARATION |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FF | Patent granted | ||
RH | Patent void |