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IE36704L - Lubricating oil additives¹¹use in lubricating oils - Google Patents

Lubricating oil additives¹¹use in lubricating oils

Info

Publication number
IE36704L
IE36704L IE711453A IE145371A IE36704L IE 36704 L IE36704 L IE 36704L IE 711453 A IE711453 A IE 711453A IE 145371 A IE145371 A IE 145371A IE 36704 L IE36704 L IE 36704L
Authority
IE
Ireland
Prior art keywords
sulphurized
alkylphenol
products
alkylphenols
neutralization
Prior art date
Application number
IE711453A
Other versions
IE36704B1 (en
Original Assignee
Chevron Res
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Res filed Critical Chevron Res
Publication of IE36704L publication Critical patent/IE36704L/en
Publication of IE36704B1 publication Critical patent/IE36704B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/16—Reaction products obtained by Mannich reactions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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    • C10M2207/16—Naphthenic acids
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    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
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    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
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    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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    • C10M2211/044—Acids; Salts or esters thereof
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1352760 Reaction products from sulphurized alkylphenols and Mannich bases CHEVRON RESEARCH CO 8 Dec 1971 [11 Dec 1970 4 Oct 1971] 57110/71 Heading C2C [Also in Division C5] The invention comprises the reaction product obtained by the neutralization with an alkaline earth metal oxide or hydroxide of a sulphurized alkylphenol containing at least 4% by weight of sulphur and a Mannich base containing at least 2% by weight of nitrogen and having a M.W. of at least 600 and prepared from a (C 1 - C 3 )alkylamine, an alkylphenol and HCHO, the neutralization being carried out in the presence of a hydroxylic solvent, at an elevated temperature so that molecular bonds are formed between the Mannich base and the sulphurized alkylphenol in addition to the ionic bridging bonds created by the alkaline earth metal. A substantial proportion of the products are believed to correspond with one of the formulae wherein A is B is α is 1 to 3, # is 0 or 1, x is 1 to 19, y is 1 to 9, n is 1 to 5; R is a (C 8 to C 36 ) straight or branchedchain saturated aliphatic hydrocarbon radical and R<SP>1</SP> is (C 1-3 )alkyl. Examples are given for the production of these products and for the preparation of the intermediate sulphurized alkylphenols and the Mannich bases. The reaction products are useful as dispersant detergent additives for lubricating oils. [GB1352760A]
IE1453/71A 1970-12-11 1971-11-17 Lubricating oil additives derived from mannich bases and sulphurised alkyl phenols IE36704B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9730070A 1970-12-11 1970-12-11
US18649471A 1971-10-04 1971-10-04

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IE36704L true IE36704L (en) 1972-06-11
IE36704B1 IE36704B1 (en) 1977-02-02

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IE1453/71A IE36704B1 (en) 1970-12-11 1971-11-17 Lubricating oil additives derived from mannich bases and sulphurised alkyl phenols

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US (1) US3741896A (en)
AU (1) AU445627B2 (en)
BE (1) BE776567A (en)
CA (1) CA987343A (en)
DE (1) DE2161121C2 (en)
DK (1) DK153165C (en)
FR (1) FR2117410A5 (en)
GB (1) GB1352760A (en)
IE (1) IE36704B1 (en)
IT (1) IT959354B (en)
NL (1) NL170305C (en)

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US4107141A (en) * 1975-10-10 1978-08-15 Vladimir Vasilievich Moiseev Method of preparing phenolamine resins
CA1094053A (en) * 1976-04-08 1981-01-20 John Crawford Lubricant additive formed by neutralisation of a sulphurised alkyl phenol and a mannich base
US4175044A (en) * 1977-01-03 1979-11-20 Chevron Research Company Mannich base composition and lubricating oil compositions containing same
US4157309A (en) * 1977-09-30 1979-06-05 Chevron Research Company Mannich base composition
US4178259A (en) * 1978-05-01 1979-12-11 Chevron Research Company Dispersant Mannich base compositions
US4828742A (en) * 1987-07-24 1989-05-09 Exxon Chemical Patents, Inc. Lactone-modified, mannich base dispersant additives useful in oleaginous compositions
US4913830A (en) * 1987-07-24 1990-04-03 Exxon Chemical Patents Inc. Lactone-modified, mannich base dispersant additives useful in oleaginous compositions
US5166439A (en) * 1989-11-24 1992-11-24 Ethyl Petroleum Additives, Inc. Composition containing a mannich base of a partially sulfurized hindered phenol mixture
AU651268B2 (en) * 1992-02-18 1994-07-14 Idemitsu Kosan Co. Ltd Mannich reaction product and process for producing the same and use of the product
US5554310A (en) * 1992-12-17 1996-09-10 Exxon Chemical Patents Inc. Trisubstituted unsaturated polymers
IL107927A0 (en) * 1992-12-17 1994-04-12 Exxon Chemical Patents Inc Oil soluble ethylene/1-butene copolymers and lubricating oils containing the same
US5814111A (en) * 1995-03-14 1998-09-29 Shell Oil Company Gasoline compositions
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
EP2272821B1 (en) * 2006-02-27 2019-12-04 Basf Se Trinuclear phenolic compounds

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US3372118A (en) * 1965-12-07 1968-03-05 Lubrizol Corp Process for preparing basic alkyl phenolic compositions
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Also Published As

Publication number Publication date
GB1352760A (en) 1974-05-08
IE36704B1 (en) 1977-02-02
US3741896A (en) 1973-06-26
NL7117004A (en) 1972-06-13
AU445627B2 (en) 1974-02-28
AU3663271A (en) 1973-06-14
CA987343A (en) 1976-04-13
DK153165B (en) 1988-06-20
DE2161121C2 (en) 1985-03-14
IT959354B (en) 1973-11-10
DE2161121A1 (en) 1972-07-06
DK153165C (en) 1988-11-07
BE776567A (en) 1972-06-12
FR2117410A5 (en) 1972-07-21
NL170305C (en) 1982-10-18

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