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ID20960A - THE PROCESS OF MAKING ALDEHIDA COMPOUNDS - Google Patents

THE PROCESS OF MAKING ALDEHIDA COMPOUNDS

Info

Publication number
ID20960A
ID20960A IDP981248A ID981248A ID20960A ID 20960 A ID20960 A ID 20960A ID P981248 A IDP981248 A ID P981248A ID 981248 A ID981248 A ID 981248A ID 20960 A ID20960 A ID 20960A
Authority
ID
Indonesia
Prior art keywords
cobalticinium
compounds
aldehida
making
phosphine
Prior art date
Application number
IDP981248A
Other languages
Indonesian (id)
Inventor
Helmut Dr Bahrmann
Albrecht Prof Dr Salzer
Claudia Brasse
Original Assignee
Celanese Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Gmbh filed Critical Celanese Gmbh
Publication of ID20960A publication Critical patent/ID20960A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

The invention relates to the hydroformylation of olefins or of olefinically unsaturated compounds in the presence of an organic solution which serves as a catalyst and which contains at least one rhodium compound and at least one phosphine-substituted cobalticinium salt. The inventive method is characterised in that phosphine-substituted cobalticinium salts of general formula (I), wherein R<1> is the same or varies and is hydrogen or various substituents, are used. An aqueous solution of 1, 1'-bis(diphenylphosphino)-cobalticinium nitrate and a rhodium compound is suitable as a hydroformylation catalyst in a two phase process.
IDP981248A 1997-09-29 1998-09-17 THE PROCESS OF MAKING ALDEHIDA COMPOUNDS ID20960A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742907A DE19742907C2 (en) 1997-09-29 1997-09-29 Process for the preparation of aldehydes

Publications (1)

Publication Number Publication Date
ID20960A true ID20960A (en) 1999-04-01

Family

ID=7843960

Family Applications (1)

Application Number Title Priority Date Filing Date
IDP981248A ID20960A (en) 1997-09-29 1998-09-17 THE PROCESS OF MAKING ALDEHIDA COMPOUNDS

Country Status (8)

Country Link
EP (1) EP1019354B1 (en)
AT (1) ATE210109T1 (en)
AU (1) AU9626998A (en)
DE (2) DE19742907C2 (en)
ID (1) ID20960A (en)
TW (1) TW520356B (en)
WO (1) WO1999016737A1 (en)
ZA (1) ZA988806B (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4169861A (en) * 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
US4221744A (en) * 1978-12-01 1980-09-09 Celanese Corporation Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents
DE4040315A1 (en) * 1990-12-17 1992-06-25 Hoechst Ag METHOD FOR PRODUCING ALDEHYDES
DE69610844T2 (en) * 1995-08-25 2001-03-29 Dsm N.V., Heerlen HYDROFORMYLATION PROCESS.

Also Published As

Publication number Publication date
ATE210109T1 (en) 2001-12-15
DE19742907C2 (en) 2002-11-14
EP1019354B1 (en) 2001-12-05
WO1999016737A1 (en) 1999-04-08
TW520356B (en) 2003-02-11
AU9626998A (en) 1999-04-23
DE19742907A1 (en) 1999-04-01
ZA988806B (en) 1999-04-06
DE59802371D1 (en) 2002-01-17
EP1019354A1 (en) 2000-07-19

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