GB985484A - New triazine compounds - Google Patents
New triazine compoundsInfo
- Publication number
- GB985484A GB985484A GB43243/61A GB4324361A GB985484A GB 985484 A GB985484 A GB 985484A GB 43243/61 A GB43243/61 A GB 43243/61A GB 4324361 A GB4324361 A GB 4324361A GB 985484 A GB985484 A GB 985484A
- Authority
- GB
- United Kingdom
- Prior art keywords
- substituted
- alkoxy
- alkylthio
- aryloxy
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
- C07D251/20—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom with no nitrogen atoms directly attached to a ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B6/00—Anthracene dyes not provided for above
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/24—Anthracenes; Hydrogenated anthracenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention comprises triazine brightening agents of the formula <FORM:0985484/C2/1> wherein A represents a polycyclic aromatic group containing at least three condensed rings, R1 represents a chloro, substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group, and R2 represents a substituted amino, alkoxy, substituted alkoxy, aryloxy, alkythio, or substituted alkythio group. The above compounds may be prepared by reacting a triazine of the formula <FORM:0985484/C2/2> with one or more molecular proportions of an amine or substituted amine in the presence of an acid binding agent (which may be excess of amine reactant), or of the sodium derivative of an alcohol, substituted alcohol, phenol, mercaptan or substituted mercaptan. Specified polycyclic aromatic groups are those derived from pyrene, anthracene, acenaphthene and chrysene. Substituted amino groups include hydroxyalkylamino, sulphoarylamino, morpholino, alkylamino, arylamino, sulphatoalkylamino and acetoxyalkylamino groups. Substituted alkoxy groups include hydroxyalkoxy groups. Substituted alkylthio groups include carboxyalkylthio groups. The dichlorotriazine starting materials are prepared by reacting an appropriate hydrocarbon A-H with cyanuric chloride in the presence of anhydrous aluminium chloride.ALSO:Polymeric materials such as polyamides (e.g. nylon), polyesters (e.g. polyethylene terephthalate) and polyurethanes, are brightened by addition to the molton or plasticized form thereof of triazines of the formula:- <FORM:0985484/C3/1> wherein A represents a polycyclic aromatic group containing at least three condensed rings, R1 represents a chloro, substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group, and R2 represents a substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group.ALSO:Soaps or detergents such as fatty alcohol ethylene oxide condensates or sulphonated alkylnaphthalenes may contain triazine brightening agents of the formula <FORM:0985484/C4-C5/1> wherein A represents a polycyclic aromatic group containing at least three condensed rings, R1 represents a chloro, substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group, and R2 represents a substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group.ALSO:Paper and fibres formed from cotton, silk, wool, secondary cellulose acetate, cellulose triacetate, regenerated cellulose, nylon, polyethylene terephthalate, polyurethanes, polyacrylonitrile, hydrolysed polyacrylonitrile, poly (methyl methacrylate), polystyrene, polyethylene and polypropylene are brightened by treatment at temperatures of between 60 DEG C. and 100 DEG C. with an aqueous suspension of a triazine compound of the formula:- <FORM:0985484/D1-D2/1> wherein A represents a polycyclic aromatic group containing at least three condensed rings, R1 represents a chloro, substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group, and R2 represents a substituted amino, alkoxy, substituted alkoxy, aryloxy, alkylthio or substituted alkylthio group, or a water-soluble salt thereof. The materials to be brightened may alternatively be padded at room temperature with the aqueous suspension of brightening agent and subsequently dried by heating to between 150 DEG and 200 DEG C. in air for a short period such as 20 to 30 seconds. Specified polycyclic aromatic groups are those derived from pyrene, anthracene, acenaphthene and chrysene. Substituted amino groups include hydroxyalkyl-amino, sulphoarylamino, morpholino, alkylamino, arylamino, sulphatoalkylamino and acetoxyalkylamino. Substituted alkoxy groups include hydroxyalkoxy groups. Substituted alkylthio groups include carboxyalkylthio groups. The above brightening agents may be used in conjunction with other brightening agents, for example substituted 4,41-ditriazinylamino-stilbene-2, 21-disulphonic acids, and also in conjunction with soaps and detergents such as fatty alcohol ethylene oxide condensates and sulphonated alkylnaphthalenes.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB43243/61A GB985484A (en) | 1961-12-04 | 1961-12-04 | New triazine compounds |
| CH1417862A CH437324A (en) | 1961-12-04 | 1962-12-03 | Process for the preparation of new triazine compounds |
| CH1731166A CH443324A (en) | 1961-12-04 | 1962-12-03 | Process for the preparation of new triazine compounds |
| FR917547A FR1345260A (en) | 1961-12-04 | 1962-12-04 | New substituted polycyclo-triazines, production and applications |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB43243/61A GB985484A (en) | 1961-12-04 | 1961-12-04 | New triazine compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB985484A true GB985484A (en) | 1965-03-10 |
Family
ID=10427891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB43243/61A Expired GB985484A (en) | 1961-12-04 | 1961-12-04 | New triazine compounds |
Country Status (2)
| Country | Link |
|---|---|
| CH (2) | CH437324A (en) |
| GB (1) | GB985484A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0020817A1 (en) * | 1979-06-08 | 1981-01-07 | Bayer Ag | Process for the preparation of pyrene compounds |
| US4675402A (en) * | 1984-10-13 | 1987-06-23 | Hoechst Aktiengesellschaft | Process for the preparation of dialkoxytriazinylpyrenes |
| US10982391B2 (en) | 2016-06-01 | 2021-04-20 | Ecolab Usa Inc. | High-efficiency strength program used for making paper in higher charge demand system |
| CN116196898A (en) * | 2023-02-23 | 2023-06-02 | 郑州师范学院 | Nanometer ferroferric oxide-cyclodextrin hydrogel adsorbent and preparation method thereof |
-
1961
- 1961-12-04 GB GB43243/61A patent/GB985484A/en not_active Expired
-
1962
- 1962-12-03 CH CH1417862A patent/CH437324A/en unknown
- 1962-12-03 CH CH1731166A patent/CH443324A/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0020817A1 (en) * | 1979-06-08 | 1981-01-07 | Bayer Ag | Process for the preparation of pyrene compounds |
| US4675402A (en) * | 1984-10-13 | 1987-06-23 | Hoechst Aktiengesellschaft | Process for the preparation of dialkoxytriazinylpyrenes |
| US10982391B2 (en) | 2016-06-01 | 2021-04-20 | Ecolab Usa Inc. | High-efficiency strength program used for making paper in higher charge demand system |
| CN116196898A (en) * | 2023-02-23 | 2023-06-02 | 郑州师范学院 | Nanometer ferroferric oxide-cyclodextrin hydrogel adsorbent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CH443324A (en) | 1967-09-15 |
| CH437324A (en) | 1967-06-15 |
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