GB984083A - Process for the optical brightening of cellulose textile material and the brightenedmaterial - Google Patents
Process for the optical brightening of cellulose textile material and the brightenedmaterialInfo
- Publication number
- GB984083A GB984083A GB38667/62A GB3866762A GB984083A GB 984083 A GB984083 A GB 984083A GB 38667/62 A GB38667/62 A GB 38667/62A GB 3866762 A GB3866762 A GB 3866762A GB 984083 A GB984083 A GB 984083A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylamino
- hydroxy
- methyl
- methoxy
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 3
- 239000004753 textile Substances 0.000 title abstract 2
- 238000005282 brightening Methods 0.000 title 1
- 229920002678 cellulose Polymers 0.000 title 1
- 239000001913 cellulose Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 230000003287 optical effect Effects 0.000 title 1
- -1 monocyclic aromatic radicals Chemical class 0.000 abstract 17
- 125000000623 heterocyclic group Chemical group 0.000 abstract 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 abstract 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 1
- SYKNUAWMBRIEKB-UHFFFAOYSA-N [Cl].[Br] Chemical compound [Cl].[Br] SYKNUAWMBRIEKB-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000001246 bromo group Chemical group Br* 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 abstract 1
- 125000006232 ethoxy propyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000011888 foil Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000002112 pyrrolidino group Chemical group [*]N1C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical group CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 abstract 1
- 125000001302 tertiary amino group Chemical group 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
Abstract
Cellulosic textile materials, e.g. cotton and regenerated cellulosic fabrics are optically brightened by impregnating them with the solution of a salt of at least one compound of the formula <FORM:0984083/D1-D2/1> in which A1, A2, A3 and A4 are hydrogen or aliphatic, cycloaliphatic, araliphatic, heterocyclic or monocyclic aromatic radicals or each pair A1 and A2 and/or A3 and A4 together with the amino nitrogen represent saturated heterocycles and X1 and X2 are halogen or hydroxyl, alkoxy, primary amino or secondary or tertiary amino groups having aliphatic, araliphatic, cycloaliphatic or aromatic nitrogen substituents which together with the nitrogen and if desired other hetero atoms may form saturated heterocycles, storing them for at least 15 minutes in a moist condition and then drying them. A1, A2, A3 and A4 may be methyl, ethyl, propyl, isopropyl, normal, secondary or tertiarybutyl, hydroxyethyl, hydroxy propyl, methoxy ethyl, ethoxyethyl, methoxy propyl, ethoxy propyl, cyclohexyl, benzyl, pyrimidyl-(2), phenyl sulphophenyl, methyl sulphophenyl, dimethyl sulphonyl or chlorosulphophenyl groups or if A1 and A2 and/or A3 and A4 together with the amino nitrogen atoms form saturated heterocycles these may be pyrrolidine, piperidine or morpholine rings. X1 and X2 may be chlorine bromine, hydroxy, methoxy, ethoxy, b -hydroxyethoxy, b -methoxyethoxy, b -ethoxyethoxy, amino, mono or bis-(methylol) amino, methylamino, ethylamino, propylamino, b -hydroxy ethylamino, b -hydroxypropyl amino, b -cyano ethylamino, carboxy methylamino, dimethyl or diethylamino, bis b -hydroxy ethylamino, bis b -hydroxy propylamino, trimethylol methylamino, N-methyl-N-ethylamino, N-methyl-N-b -hydroxy ethylamino, N-ethyl-N-b -hydroxy ethylamino, N-methyl-N-b -hydroxy-propylamino, N-ethyl-N-b -hydroxypropylamino, b , g -dihydroxy propylamino, N-methylcarboxy methylamino, 2-methoxy ethylamino, N-methyl-2-methoxy ethylamino, 2-ethoxy ethylamino, b -methoxy propylamino, cyclohexylamino, N-ethylcyclohexylamino, benzylamino, N-b -hydroxy ethyl benzylamino, N-b -cyanoethyl cyclohexylamino, phenylamino, o, m or p methyl phenylamino, 3, 5-, 2, 5- or 3, 4 dimethyl phenylamino, m or p methoxy, m or p ethoxy, m or p chloro, m or p bromo, m or p sulpho, m or p sulphamyl or m or p carboxyphenylamino, 2, 5 dimethyl-4-sulphophenylamino, 4-chloro-3-carboxy phenylamino, piperidino, morpholino or pyrrolidino groups. The impregnation bath which may also contain sodium chloride may be maintained at 20 DEG -60 DEG C. and the impregnated material may be stored in the moist state at room or elevated temperatures while rolled up and covered with a plastic foil.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1188061A CH377307A (en) | 1961-10-13 | 1961-10-13 | Process for the optical brightening of cellulose fibers |
CH153062A CH406124A (en) | 1961-10-13 | 1962-02-08 | Process for the optical brightening of cellulose fibers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB984083A true GB984083A (en) | 1965-02-24 |
Family
ID=25687916
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB38667/62A Expired GB984083A (en) | 1961-10-13 | 1962-10-12 | Process for the optical brightening of cellulose textile material and the brightenedmaterial |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE623561A (en) |
CH (1) | CH406124A (en) |
GB (1) | GB984083A (en) |
-
1962
- 1962-02-08 CH CH153062A patent/CH406124A/en unknown
- 1962-10-12 GB GB38667/62A patent/GB984083A/en not_active Expired
- 1962-10-12 BE BE623561A patent/BE623561A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CH406124A (en) | 1965-10-15 |
BE623561A (en) | 1963-04-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3781278A (en) | Novel p-phenylstilbyl heterocyclic and naphthyl-vinylphenylene heterocyclic optical brighteners | |
DE59409837D1 (en) | Stabilized polymers containing o-hydroxyphenyl-s-triazines | |
GB1200644A (en) | Process for strengthening a fibrous material | |
ES430709A1 (en) | 1-(Imidazolyl-1)-2-aryloxy-3-hydroxy-alkanes | |
GB867262A (en) | Improvements in the stabilization of polyester fibres to ultra-violet light | |
GB984083A (en) | Process for the optical brightening of cellulose textile material and the brightenedmaterial | |
NO810878L (en) | PROCEDURE FOR THE PREPARATION OF PHARMACOLOGICAL ACTIVE 1,1-DIPHENYL-2- (1,2,4-TRIAZOL-L-YL) ETHANOLE DERIVATIVES | |
CH462095A (en) | Use of new azole compounds as optical brightening agents outside the textile industry | |
ES389279A1 (en) | N-{11 2-(diphenylmethoxy)ethyl{11 -n-methylcinnamylamine and the salts thereof | |
GB888209A (en) | 2:5-di[-benzimidazyl-(2)]-furanes | |
ES407913A1 (en) | Pyrimidin-6 yl acethydroxamic acids | |
US4400294A (en) | Mixtures of optical brighteners | |
ES255967A1 (en) | Process for treating cellulosic textile materials with bis(beta-methoxyethyl) sulfone | |
GB1033385A (en) | Di-arylene azolyl styrene compounds and their use as optical brightening agents | |
GB1073836A (en) | Benzoxathiazine derivatives | |
GB967110A (en) | Process for the optical brightening of cellulose material and the material brightened thereby | |
GB1234344A (en) | ||
ES421767A2 (en) | A PROCEDURE FOR THE PREPARATION OF 5-SULFAMYL-BENZOIC ACIDS REPLACED IN POSITION 2. | |
US3446805A (en) | 7-aryltriazolyl-3-aryl-carbostyrils | |
GB982196A (en) | Process for the optical brightening of cellulose material and material brightened thereby | |
GB908229A (en) | Bis-(triazinylamino)-stilbene disulphonic acid brightening agents | |
DK163584D0 (en) | 2-AMINOETHYL-PYRIDINE OR-PYRAZINE DERIVATIVES | |
GB982082A (en) | Process for dyeing and padding hydrophobic materials | |
US3028253A (en) | X c chj | |
GB1254687A (en) | Process for the continuous dyeing of synthetic fibre materials |