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GB982114A - Fibrillatable artificial fibre - Google Patents

Fibrillatable artificial fibre

Info

Publication number
GB982114A
GB982114A GB1614261A GB1614261A GB982114A GB 982114 A GB982114 A GB 982114A GB 1614261 A GB1614261 A GB 1614261A GB 1614261 A GB1614261 A GB 1614261A GB 982114 A GB982114 A GB 982114A
Authority
GB
United Kingdom
Prior art keywords
fibre
fibres
forming polymer
forming
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1614261A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of GB982114A publication Critical patent/GB982114A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00Special paper or cardboard not otherwise provided for
    • D21H5/12Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
    • D21H5/1236Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of fibres which have been treated to render them suitable for sheet formation, e.g. fibrillatable fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/42Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/423Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by fibrillation of films or filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08Composition of the spinning solution or the bath
    • D01F2/10Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/18Highly hydrated, swollen or fibrillatable fibres

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

An artificial organic partially degraded hybrid fibre formed of a fibre-forming polymer having a fine structure including crystalline and amorphous regions, contains a hybridizing substance comprising at least one chemically different amorphous polymer capable of disrupting the fine structure of the fibre-forming polymer during fibre formation. The partially degraded fibre has the same weight as the parent undegraded fibre and, when beaten in water, forms fibrils with diameters of the order of from 50 <\>r to 7500 <\>r. The term "hybrid" is defined as a fibre-forming mixture containing a fibre-forming polymer and one or more chemically different amorphous polymers which is or are capable of solidifying during the conditions under which a fibre is formed and is or are capable of disrupting the fine structure of the fibre-forming polymer during the formation of the fibre. The fibres may be composed wholly or partially of natural or synthetic organic high polymers. The fibre-forming polymer may be regenerated cellulose and the chemically different amorphous polymer may be an alkali soluble, water-insoluble hydroxyethyl, hydroxypropyl or carboxyethyl cellulose or it may be a polyacrylate. The hybridizing substance need not be a fibre-forming material per se. When the fibre-forming polymer is regenerated cellulose the partial degrading of the fibres may be effected by treating the fibres with a dilute aqueous solution of hydrochloric or sulphuric acid and the so-treated fibres may be beaten in an aqueous medium or water to fibrillate and disperse the fibres, the fibres may be collected to form a water-laid web and the web may be dried. The dispersed fibres may be mixed with other fibres and the mixture formed into a web, or the dispersed fibres may be separated from the water before mixing them with other fibres and forming a web from the mixture. The hybridizing or extraneous substance is intimately mixed with the spinning liquid which is then spun into filaments and the filaments processed in a conventional manner. The proportion of the hybridizing substance added is preferably about 25 to 75% based on the weight of the fibre-forming polymer. Specification 934,786 is referred to.ALSO:Paper is made from an artificial organic partially degraded hybrid fibre formed of a fibre-forming polymer having a fine structure including crystalline and amorphous regions containing a hybridizing substance comprising at least one chemically different amorphous polymer capable of disrupting the fine structure of the fibre-forming polymer during fibre formation. The partially degraded fibre has the same weight as the parent undegraded fibre and, when beaten in water, forms fibrils with diameters of the order of from 50A to 7500 . The term "hybrid" is defined as a fibre-forming mixture containing a fibre-forming polymer and one or more chemically different amorphous polymers which is or are capable of solidifying during the conditions under which a fibre is formed and is or are capable of disrupting the fine structure of the fibre-forming polymer during the formation of the fibre. The fibres may be composed wholly or partially of natural or synthetic organic high polymers. The fibre-forming polymer may be regenerated cellulose and the chemically different amorphous polymer may be an alkali-soluble, water-insoluble hydroxyethyl, hydroxypropyl or carboxyethyl cellulose or it may be a polyacrylate. The fibre-forming polymer may be nylon. The hybridizing substance need not be a fibre-forming material per se. When the fibre-forming polymer is regenerated cellulose, the partial degrading of the fibres may be effected by treating the fibres with a dilute aqueous solution of hydrochloric or sulphuric acid and the so treated fibres may be beaten in an aqueous medium or water to fibrillate and disperse the fibres, the fibres may be collected to form a water-laid web and the web may be dried. The dispersed fibres may be mixed with other fibres and the mixture formed into a web, or the dispersed fibres may be separated from the water before mixing them with other fibres and forming a web from the mixture. The hybridizing or extraneous substance is intimately mixed with the spinning liquid which is then spun into filaments and the filaments processed in a conventional manner. The proportion of the hybridizing substance added is preferably about 25 to 75% based on the weight of the fibre-forming polymer. Specification 934,786 is referred to.
GB1614261A 1960-05-23 1961-05-04 Fibrillatable artificial fibre Expired GB982114A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US3116960A 1960-05-23 1960-05-23

Publications (1)

Publication Number Publication Date
GB982114A true GB982114A (en) 1965-02-03

Family

ID=21857978

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1614261A Expired GB982114A (en) 1960-05-23 1961-05-04 Fibrillatable artificial fibre

Country Status (4)

Country Link
DE (1) DE1469022A1 (en)
FI (1) FI41057B (en)
GB (1) GB982114A (en)
SE (1) SE304440B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3499822A (en) * 1965-02-23 1970-03-10 Rasmussen O B Extruded,expanded mat-like or web-like fibrillar sheet assembly and method for its production
EP0398825A1 (en) * 1989-05-18 1990-11-22 Aussedat-Rey, Societe Anonyme Process for making a plane, supple and hardly tearable substrate, and the same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3499822A (en) * 1965-02-23 1970-03-10 Rasmussen O B Extruded,expanded mat-like or web-like fibrillar sheet assembly and method for its production
EP0398825A1 (en) * 1989-05-18 1990-11-22 Aussedat-Rey, Societe Anonyme Process for making a plane, supple and hardly tearable substrate, and the same
FR2647128A1 (en) * 1989-05-18 1990-11-23 Aussedat Rey PROCESS FOR MANUFACTURING A PLANAR SUBSTRATE, FIBROUS, FLEXIBLE, DIFFICULTLY RELEASABLE AND SUBSTRATE OBTAINED
US5387319A (en) * 1989-05-18 1995-02-07 Societe Anonyme: Aussedat-Rey Process for manufacturing a flat, fibrous, supple substrate, difficult to tear and substrate obtained

Also Published As

Publication number Publication date
FI41057B (en) 1969-04-30
SE304440B (en) 1968-09-23
DE1469022A1 (en) 1969-03-20

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