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GB972078A - - Google Patents

Info

Publication number
GB972078A
GB972078A GB10330/61A GB1033061A GB972078A GB 972078 A GB972078 A GB 972078A GB 10330/61 A GB10330/61 A GB 10330/61A GB 1033061 A GB1033061 A GB 1033061A GB 972078 A GB972078 A GB 972078A
Authority
GB
United Kingdom
Prior art keywords
fibres
fibre
compound
acrylic
chlorine atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10330/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Deutsche Gold und Silber Scheideanstalt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Gold und Silber Scheideanstalt filed Critical Deutsche Gold und Silber Scheideanstalt
Publication of GB972078A publication Critical patent/GB972078A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/10—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material
    • D06B1/14—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material with a roller
    • D06B1/145—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material with a roller the treating material being kept in the trough formed between two or more rollers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/285—Acrylic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/242—Applying crosslinking or accelerating agent onto compounding ingredients such as fillers, reinforcements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Fibre-reinforced polyacrylic or polymethacrylic acid esters are produced by a process comprising treating glass fibres or synthetic or natural fibres with a compound that contains a labile chlorine atom and, if desired, with another component of the accelerator system, especially copper naphthenate in an amount of 10-3,000 p.p.m. of the monomer, and then in a second stage treating the fibre with (A) a monomeric ester of acrylic or methacrylic acids which contains from 0.5 to 2.0% of an organic peroxide and which may contain up to 50% of a polymeric substance (B) and, if necessary, up to 80% of a further monomeric polymerizable compound (C) and finally curing the product. The compound containing a labile chlorine atom may be hydrochloric acid or a quaternary ammonium chloride such as phenyl ethyl dibutylamine hydrochloride and is preferably sprayed on to the fibres as a solution in water, methanol, acetone, methyl acetate or methyl methacrylate. At the same time organic sulphur compounds such as a -aminosulphones, a -oxysulphones or mercaptans may be applied. The polymeric substance (B) may be a polymer of an ester of acrylic or methacrylic acid which may be an unsaturated polyester resin. The compound (C) may be styrene, vinyl acetate, acrylonitrile, vinyl toluene, diallyphthalate, allyl methacrylate, ethylene glycol dimethacrylate, triallyl cyanurate or divinyl benzene. Up to 1.0% of a hydroperoxide may be present in addition to the peroxide. The organic sulphur compounds may be added with the resin instead of sprayed on to the fibre and is present up to 0.5%. Curing is carried out at room temperature. The fibres may be in the form of mats, fabrics, strands or fibres. Specification 768,843 is referred to.
GB10330/61A 1960-05-23 1961-03-21 Expired GB972078A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED32935A DE1284083B (en) 1960-05-23 1960-05-23 Process for the production of molded articles reinforced with glass fibers, synthetic or natural fibers

Publications (1)

Publication Number Publication Date
GB972078A true GB972078A (en) 1964-10-07

Family

ID=7041517

Family Applications (1)

Application Number Title Priority Date Filing Date
GB10330/61A Expired GB972078A (en) 1960-05-23 1961-03-21

Country Status (6)

Country Link
BE (1) BE601742A (en)
CH (1) CH423227A (en)
DE (1) DE1284083B (en)
FR (1) FR1289681A (en)
GB (1) GB972078A (en)
NL (2) NL262140A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19848028A1 (en) * 1998-10-17 2000-04-20 Roehm Gmbh Transparent acrylic polymer screen, for noise barrier, contains partially sized polymeric fibers
WO2010072990A1 (en) * 2008-12-23 2010-07-01 Advanced Composites Group Limited Curative fibre components
WO2014118101A1 (en) * 2013-01-29 2014-08-07 Akzo Nobel Chemicals International B.V. Process for preparing a fiber-reinforced composite material
US11208564B2 (en) 2014-01-22 2021-12-28 Arkema France Impregnation process for a functional fibrous substrate, a liquid monomer syrup for the impregnation process, its method of polymerization and structured article obtained thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3322566A (en) * 1963-01-14 1967-05-30 Air Logistics Corp Resin coating

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2899402A (en) * 1955-09-21 1959-08-11 Process for manufacturing fiber re-

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19848028A1 (en) * 1998-10-17 2000-04-20 Roehm Gmbh Transparent acrylic polymer screen, for noise barrier, contains partially sized polymeric fibers
DE19848028C2 (en) * 1998-10-17 2001-06-07 Roehm Gmbh Transparent plastic pane made of acrylic glass, process for its production and use
WO2010072990A1 (en) * 2008-12-23 2010-07-01 Advanced Composites Group Limited Curative fibre components
US9926418B2 (en) 2008-12-23 2018-03-27 Cytec Industrial Materials (Derby) Limited Curative fibre components
WO2014118101A1 (en) * 2013-01-29 2014-08-07 Akzo Nobel Chemicals International B.V. Process for preparing a fiber-reinforced composite material
US9873795B2 (en) 2013-01-29 2018-01-23 Akzo Nobel Chemicals International B.V. Process for preparing a fiber-reinforced composite material
US11208564B2 (en) 2014-01-22 2021-12-28 Arkema France Impregnation process for a functional fibrous substrate, a liquid monomer syrup for the impregnation process, its method of polymerization and structured article obtained thereof

Also Published As

Publication number Publication date
NL262140A (en)
DE1284083B (en) 1968-11-28
FR1289681A (en) 1962-04-06
CH423227A (en) 1966-10-31
NL121531C (en)
BE601742A (en)

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