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GB968389A - Polypropylene fibres - Google Patents

Polypropylene fibres

Info

Publication number
GB968389A
GB968389A GB43529/60A GB4352960A GB968389A GB 968389 A GB968389 A GB 968389A GB 43529/60 A GB43529/60 A GB 43529/60A GB 4352960 A GB4352960 A GB 4352960A GB 968389 A GB968389 A GB 968389A
Authority
GB
United Kingdom
Prior art keywords
methyl
methacrylate
vinyl
carbon atoms
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB43529/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US860648A external-priority patent/US3156743A/en
Priority claimed from US6596A external-priority patent/US3090769A/en
Priority claimed from US6597A external-priority patent/US3315014A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB968389A publication Critical patent/GB968389A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C08L39/08—Homopolymers or copolymers of vinyl-pyridine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Coloring (AREA)

Abstract

Compositions suitable for spinning fibres comprise polypropylene and a polymeric modifier which is either a homopolymer of a monomer of formula: <FORM:0968389/C3/1> where R is hydrogen or methyl, R1 is an alkyl, alkoxyalkyl, cycloalkyl, aralkyl or aryl radical containing 1 to 12 carbon atoms, or a copolymer of such a monomer with (1) a different monomer of the same formula, (2) a vinyl pyridine monomer of formula: <FORM:0968389/C3/2> where R2 is hydrogen or methyl, R3 is an alkyl group containing 1 to 4 carbon atoms and n is 0 or an integer from 1 to 4, or (3) an N-substituted acrylamide monomer of formula: <FORM:0968389/C3/3> where R4 is hydrogen or an alkyl group containing 1 to 4 carbon atoms, R5 is hydrogen or an alkyl, cycloalkyl, aralkyl or aryl group containing 1 to 18 carbon atoms, and R6 is an alkyl, cycloalkyl, aralkyl or aryl group containing 1 to 18 carbon atoms, said modifier being present in an amount sufficient to impart dye affinity, light and gas fastness and resistance to oxidation and weathering to fibres of such compositions. The modifiers may also comprise units derived from other monomers containing one or more ethylenically unsaturated groups, e.g. butadiene, isoprene, vinyl acetate, methyl vinyl ketone, 2-chlorethyl vinyl ether, styrene, a -methylstyrene, acrylic and methacrylic acids, esters and nitriles, methylenemalonitrile, maleic, fumaric and itaconic esters, vinylidene cyanide, vinyl chloride, vinylidene chloride, N-vinyl succinimide, N-vinylphthalimide, and N-vinyl pyrrolidone. Many suitable monomers of the above specified formulae and modifiers derived therefrom are listed, and examples describe compositions comprising polypropylene and (1) polymethyl methacrylate; (2) poly n-butyl methacrylate, polyethyl methacrylate, polyethyl acrylate, polyisobutyl methacrylate, poly 2-ethylhexyl acrylate, polylauryl methacrylate or poly 2-methoxyethyl acrylate; (3) n-butyl/isobutyl methacrylate, methyl acrylate/ethyl methacrylate, methyl/n-butyl methacrylate, methyl methacrylate/ethyl acrylate or methyl/cyclohexyl methacrylate copolymers; (4) methyl methacrylate/3-isopropenyl pyridine or 2-methyl-3-vinyl pyridine/3-vinyl pyridine/n-butyl methacrylate copolymers; (5) ethyl acrylate/2-methyl-6-vinyl pyridine or ethyl acrylate/2-vinyl pyridine copolymers; (6) methyl methacrylate/2-methyl-5-vinyl pyridine copolymer; (7) ethyl acrylate/N-t.butyl acrylamide copolymer; (8) N,N-dimethyl acrylamide/N-iso-propyl acrylamide/methyl methacrylate copolymer; (9) methyl methacrylate/N,N-dimethyl acrylamide copolymer; (10) methyl methacrylate/ethyl fumarate copolymer; (11) methyl methacrylate/vinyl acetate copolymer; (12) methyl methacrylate/styrene copolymer; (13) ethyl acrylate/acrylonitrile copolymer; (14) ethyl acrylate/vinylidene chloride or methyl acrylate/vinyl chloride copolymers and (15) ethyl acrylate/2-chlorethyl vinyl ether or methyl acrylate/ vinyl chloride copolymers. The compositions may be melt spun into fibres which may be made into blankets, seat covers and marine hawsers, and may be dyed.ALSO:Polypropylene composition fibres are dyed with dispersed, premetallised, acid and direct dyes, said compositions comprising polypropylene and a polymeric modifier comprising either a homopolymer of a monomer of formula: <FORM:0968389/D1-D2/1> where R is hydrogen or methyl, R1 is an alkyl, alkoxyalkyl, cycloalkyl, aralkyl or aryl radical containing 1 to 12 carbon atoms, or a copolymer of such a monomer with (1) a different monomer of the same formula, (2) a vinyl pyridine monomer of formula: <FORM:0968389/D1-D2/2> where R2 is hydrogen or methyl, R3 is an alkyl group containing 1 to 4 carbon atoms and n is O or an integer from 1 to 4 or (3) an N-substituted acrylamide of formula: <FORM:0968389/D1-D2/3> where R4 is hydrogen or an alkyl group containing 1 to 4 carbon atoms, R5 is hydrogen or an alkyl, cycloalkyl, aralkyl or aryl group containing 1 to 18 carbon atoms, and R6 is an alkyl, cycloalkyl, aralkyl or aryl group containing 1 to 18 carbon atoms, said modifier being present in an amount sufficient to impart dye affinity, light and gas fastness and resistance to oxidation and weathering to said fibres. Examples describe the dyeing with dyes of the specified types of knit tubes of yarns of compositions comprising polypropylene.
GB43529/60A 1959-12-21 1960-12-19 Polypropylene fibres Expired GB968389A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US860648A US3156743A (en) 1959-12-21 1959-12-21 Dyeable polypropylene fibers containing acrylate and methacrylate units in polymeric form
US659560A 1960-02-04 1960-02-04
US659860A 1960-02-04 1960-02-04
US6596A US3090769A (en) 1960-02-04 1960-02-04 Dyeable polypropylene fibers containing polyvinyl acetal resins
US6597A US3315014A (en) 1960-02-04 1960-02-04 Dyeable polypropylene fibers containing polymers of vinyl pyridines

Publications (1)

Publication Number Publication Date
GB968389A true GB968389A (en) 1964-09-02

Family

ID=27533179

Family Applications (4)

Application Number Title Priority Date Filing Date
GB42984/60A Expired GB931920A (en) 1959-12-21 1960-12-14 Polypropylene fibres
GB43529/60A Expired GB968389A (en) 1959-12-21 1960-12-19 Polypropylene fibres
GB3068/61A Expired GB968692A (en) 1959-12-21 1961-01-26 Polypropylene compositions
GB4161/61A Expired GB975701A (en) 1959-12-21 1961-02-03 Polypropylene compositions

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB42984/60A Expired GB931920A (en) 1959-12-21 1960-12-14 Polypropylene fibres

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB3068/61A Expired GB968692A (en) 1959-12-21 1961-01-26 Polypropylene compositions
GB4161/61A Expired GB975701A (en) 1959-12-21 1961-02-03 Polypropylene compositions

Country Status (5)

Country Link
BE (1) BE596575A (en)
DE (6) DE1469069A1 (en)
FR (1) FR1274733A (en)
GB (4) GB931920A (en)
NL (1) NL259310A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL127158C (en) * 1962-04-23
CA1096532A (en) * 1974-07-01 1981-02-24 Rohm And Haas Company Process for improving the processability of polyolefins and improved polyolefin compositions
FR2939234A1 (en) * 2008-12-03 2010-06-04 Nexans RETICULABLE COMPOSITION FOR MEDIUM AND HIGH VOLTAGE POWER CABLE
CN110698777A (en) * 2019-10-12 2020-01-17 安徽强茗塑业科技有限公司 Modified polypropylene composite material and preparation process thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT206643B (en) * 1956-09-27 1959-12-10 Montedison Spa Polypropylene dyeable polymer product and process for its manufacture
DE1251903B (en) * 1956-12-12 1967-10-12 MONTECATINI Societa Gene rale per 1 Industna Mmeraria e Chimica Mailand (Italien) Process for improving the colorability of threads, films or tapes made of polyolefins
NL254499A (en) * 1959-08-03

Also Published As

Publication number Publication date
FR1274733A (en) 1961-10-27
NL259310A (en)
DE1259500B (en) 1968-01-25
DE1254287B (en) 1967-11-16
GB968692A (en) 1964-09-02
DE1669397A1 (en) 1970-12-03
GB931920A (en) 1963-07-24
DE1267376B (en) 1968-05-02
BE596575A (en) 1961-02-15
DE1469069A1 (en) 1969-03-20
DE1254286B (en) 1967-11-16
GB975701A (en) 1964-11-18

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