GB968058A - Sulphite esters - Google Patents
Sulphite estersInfo
- Publication number
- GB968058A GB968058A GB2302862A GB2302862A GB968058A GB 968058 A GB968058 A GB 968058A GB 2302862 A GB2302862 A GB 2302862A GB 2302862 A GB2302862 A GB 2302862A GB 968058 A GB968058 A GB 968058A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alcohol
- sulphite
- phenol
- acyclic
- alkynyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- -1 sulphite diesters Chemical class 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- WCTKUENARPWTAY-UHFFFAOYSA-N ac1l9mss Chemical compound OS(Cl)=O WCTKUENARPWTAY-UHFFFAOYSA-N 0.000 abstract 2
- 125000002015 acyclic group Chemical group 0.000 abstract 2
- 239000000443 aerosol Substances 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 2
- 150000005690 diesters Chemical class 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000007921 spray Substances 0.000 abstract 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- 241000238876 Acari Species 0.000 abstract 1
- 241000256113 Culicidae Species 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004966 cyanoalkyl group Chemical group 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000003350 kerosene Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- AIPQCSOFOOIEBX-UHFFFAOYSA-N prop-2-ynyl tridecyl sulfite Chemical compound S(=O)(OCC#C)OCCCCCCCCCCCCC AIPQCSOFOOIEBX-UHFFFAOYSA-N 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052903 pyrophyllite Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- OSRVIALWBHNFOC-UHFFFAOYSA-N tridecyl hydrogen sulfite Chemical compound CCCCCCCCCCCCCOS(O)=O OSRVIALWBHNFOC-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C301/00—Esters of sulfurous acid
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C301/00—Esters of sulfurous acid
- C07C301/02—Esters of sulfurous acid having sulfite groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
- C12N1/06—Lysis of microorganisms
- C12N1/063—Lysis of microorganisms of yeast
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Genetics & Genomics (AREA)
- Medicinal Chemistry (AREA)
- Agronomy & Crop Science (AREA)
- Biomedical Technology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- Virology (AREA)
- Tropical Medicine & Parasitology (AREA)
- Microbiology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises mixed sulphite diesters of an acyclic alkynyl alcohol and a saturated aliphatic alcohol or phenol, particularly diesters of the formula: <FORM:0968058/C1/1> wherein R is an alkyl, aralkyl, cyanoalkyl, haloalkyl, carbalkoxyalkyl aryl, alkaryl or haloaryl radical and R1 is an acyclic-alkynyl radical. The esters are prepared from the chlorosulphinate of the alcohol or phenol, by treatment in a solvent, e.g. benzene, xylene or solvent naphtha, with the alkynyl alcohol in the presence of an HCl acceptor, e.g. pyridine, dimethylaniline or trimethylamine, at between -10 DEG and 50 DEG C. The chlorosulphinate is prepared by treatment of alcohol or phenol with thionyl chloride at between -5 DEG and 30 DEG C. These compounds may be used as insecticides. (see Division A5).ALSO:Insecticidal compositions contain as the active ingredients mixed sulphite esters of an acyclic alkynyl alcohol and a saturated aliphatic alcohol or phenol, particularly diesters of the general formula <FORM:0968058/A5-A6/1> wherein R is an alkyl, cyanoalkyl haloalkyl, carbalkoxy alkyl, aryl, aralkyl, alkaryl or haloaryl radical and R1 is an acyclic-alkynyl radical (see Division C2). The chemicals may be applied as dusts mixed with powdered solid carriers, for example mica, talc, pyrophyllite and clays; as liquids or sprays when dissolved in a solvent, for example acetone, benzene or kerosene, or as aerosol sprays when dissolved directly in an aerosol carrier. They are preferably used as aqueous emulsions containing an anionic, non-ionic or cationic surface active dispersing agent or as aqueous suspensions containing solid powder carriers and dispersing agents. Examples describe the use of proparyl tridecyl sulphite in the control of mosquito larvae and propargyl tridecyl sulphite and 2-(3-butynyl) hexadecyl sulphite in the control of mites.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13174261A | 1961-08-16 | 1961-08-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB968058A true GB968058A (en) | 1964-08-26 |
Family
ID=22450820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2302862A Expired GB968058A (en) | 1961-08-16 | 1962-06-15 | Sulphite esters |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE619991A (en) |
| CH (1) | CH406729A (en) |
| DE (1) | DE1493276C3 (en) |
| GB (1) | GB968058A (en) |
| LU (1) | LU42045A1 (en) |
| NL (1) | NL120231C (en) |
-
1962
- 1962-05-22 DE DE19621493276 patent/DE1493276C3/en not_active Expired
- 1962-06-15 GB GB2302862A patent/GB968058A/en not_active Expired
- 1962-07-10 BE BE619991A patent/BE619991A/en unknown
- 1962-07-12 CH CH838762A patent/CH406729A/en unknown
- 1962-07-12 LU LU42045D patent/LU42045A1/xx unknown
- 1962-07-24 NL NL281346A patent/NL120231C/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| NL281346A (en) | 1964-12-10 |
| LU42045A1 (en) | 1962-09-12 |
| DE1493276C3 (en) | 1974-01-17 |
| CH406729A (en) | 1966-01-31 |
| NL120231C (en) | 1965-08-16 |
| DE1493276B2 (en) | 1973-05-30 |
| DE1493276A1 (en) | 1969-02-20 |
| BE619991A (en) | 1962-11-05 |
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