GB955945A - Saturated n-hydroxylactams - Google Patents
Saturated n-hydroxylactamsInfo
- Publication number
- GB955945A GB955945A GB69662A GB69662A GB955945A GB 955945 A GB955945 A GB 955945A GB 69662 A GB69662 A GB 69662A GB 69662 A GB69662 A GB 69662A GB 955945 A GB955945 A GB 955945A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxylactams
- saturated
- carbon atoms
- hydroxamic acids
- hydroxamic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/74—Oxygen atoms
- C07D211/76—Oxygen atoms attached in position 2 or 6
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
Abstract
The invention comprises saturated N-hydroxylactams of the formula: <FORM:0955945/C2/1> wherein Z is a linear aliphatic chain of 4 or 5 carbon atoms which may be substituted by allyl groups. They may be prepared by reacting a cyclic saturated ketone, the ring of which contains 5 or 6 carbon atoms, dissolved in a polar organic solvent, with a hydroxamic acid and an alkali metal hydroxide and acidifying the reaction mixture. Specified hydroxamic acids are nitro-, benzenesulpho- and b -naphthalenesulpho-hydroxamic acids. The N-hydroxylactams may be converted into the corresponding saturated lactams by catalytic hydrogenation in alcoholic solution using, for example, a palladium or charcoal catalyst.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT46261 | 1961-01-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB955945A true GB955945A (en) | 1964-04-22 |
Family
ID=11098736
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB69662A Expired GB955945A (en) | 1961-01-11 | 1962-01-08 | Saturated n-hydroxylactams |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB955945A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4473696A (en) * | 1982-10-07 | 1984-09-25 | Ici Americas Inc. | Synthesis of 2-substituted-5-methyl-pyridines |
US4658031A (en) * | 1982-10-07 | 1987-04-14 | Ici Americas Inc. | Synthesis of 2-substituted-5-methyl-pyridines and intermediates therefor |
US4687854A (en) * | 1982-10-07 | 1987-08-18 | Ici Americas Inc. | Bispiperidone precursor of 2-substituted-5-methyl-pyridines |
WO1993008803A1 (en) * | 1991-10-31 | 1993-05-13 | Board Of Governors Of Wayne State University | Cyclic hydroxamic acids |
-
1962
- 1962-01-08 GB GB69662A patent/GB955945A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4473696A (en) * | 1982-10-07 | 1984-09-25 | Ici Americas Inc. | Synthesis of 2-substituted-5-methyl-pyridines |
US4658031A (en) * | 1982-10-07 | 1987-04-14 | Ici Americas Inc. | Synthesis of 2-substituted-5-methyl-pyridines and intermediates therefor |
US4687854A (en) * | 1982-10-07 | 1987-08-18 | Ici Americas Inc. | Bispiperidone precursor of 2-substituted-5-methyl-pyridines |
WO1993008803A1 (en) * | 1991-10-31 | 1993-05-13 | Board Of Governors Of Wayne State University | Cyclic hydroxamic acids |
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