GB937621A - Improvements in colour photography and in colour-forming phenylazo-pyrazolones therefor - Google Patents
Improvements in colour photography and in colour-forming phenylazo-pyrazolones thereforInfo
- Publication number
- GB937621A GB937621A GB33779/59A GB3377959A GB937621A GB 937621 A GB937621 A GB 937621A GB 33779/59 A GB33779/59 A GB 33779/59A GB 3377959 A GB3377959 A GB 3377959A GB 937621 A GB937621 A GB 937621A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pyrazolone
- atoms
- phenyl
- colour
- butyramido
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/333—Coloured coupling substances, e.g. for the correction of the coloured image
- G03C7/3335—Coloured coupling substances, e.g. for the correction of the coloured image containing an azo chromophore
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
- C07D231/52—Oxygen atom in position 3 and nitrogen atom in position 5, or vice versa
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
1-(21,41,61- Trichlorophenyl) - 3-{411-[a -(2111, 4111- di-tamylphenoxy)butyramido]anilino}- 5-pyrazolone is made by treating the corresponding 3-(411-aminoanilino)- 5-pyrazolone with acetonitrile and a -(2,4-di-t-amylphenoxy)-butyryl chloride. The 3-(411-aminoanilino)-5-pyrazolone is made by hydrogenating the corresponding nitro compound obtained on treating with caustic soda the compound formed by condensing the corresponding 3-amino-5-pyrazolone with acetonitrile and a -(p-nitrophenoxy) acetyl chloride. The 1-(21, 41,61-trichlorophenyl)- 3-amino- 5-pyrazolone is made by treating 2,4,6-trichlorophenylhydrazine with ethyl-b -ethoxy-b -iminopropionate in the presence of sodium ethoxide and acidifying the product with acetic acid. The corresponding 1-(phenyl) compounds may be made by similar methods. The final products are intermediates in the formation of colour couplers (see Groups IV(c) and XX). Specifications 598,174, 599,377, 617,247, 635,841, 702,255 and 711,488 are referred to.ALSO:The invention comprises colour couplers of formula <FORM:0937621/IV(a)/1> where R is a phenyl radical which may contain halogen atoms in the 2, 4 and 6 positions, R1 is H or an alkyl group of 1 to 4 C atoms, R11 is an alkyl or alkoxy group of 1 to 12 C atoms and X and Z are alkyl groups of 1 to 20 C atoms. Compounds in which either X or Z may be H are also described. The couplers are made by conventional processes of diazotization and coupling. R is specified as a phenyl or 2,4,6-tri-chloro-, -bromo-, -iodo- or -fluorophenyl radical. X and Z preferably have 1 to 15 C atoms and R11 preferably has 1 to 6 C atoms. The dyes are used in colour photography. They are yellow and form a magenta dye on development with a primary aromatic amine developer. Dyes prepared are 1-(21,41,61-trichlorophenyl) -3-(411-[a (2111,4111-di-t-amylphenoxy) -butyramido]anilino)-4-(4111-methoxy-, -ethoxy, -butoxy-, -dodecoxy- and sec-amyl and 21111-ethoxy-phenyl) azo-5-pyrazolones and 1-phenyl-3-(411-[a (2111,4111-di-t-amylphenoxy) butyramido]anilino)-4-(41111-methoxyphenyl) azo-5-pyrazolone. Specifications 598,174, 599,377, 617,247, 635,841, 702,255 and 711,488 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US765315A US2983608A (en) | 1958-10-06 | 1958-10-06 | Yellow-colored magenta-forming couplers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB937621A true GB937621A (en) | 1963-09-25 |
Family
ID=25073218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB33779/59A Expired GB937621A (en) | 1958-10-06 | 1959-10-06 | Improvements in colour photography and in colour-forming phenylazo-pyrazolones therefor |
Country Status (3)
Country | Link |
---|---|
US (1) | US2983608A (en) |
FR (1) | FR1238590A (en) |
GB (1) | GB937621A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0201033A2 (en) | 1985-04-30 | 1986-11-12 | Konica Corporation | A method for processing silver halide color photographic materials |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE619300A (en) * | 1959-04-06 | |||
BE622316A (en) * | 1961-09-11 | |||
US3311476A (en) * | 1962-12-26 | 1967-03-28 | Eastman Kodak Co | Two-equivalent couplers for color photography |
NL133047C (en) * | 1963-06-17 | |||
GB997500A (en) * | 1963-06-17 | 1965-07-07 | Ilford Ltd | Improvements in or relating to colour couplers and to their production and use in colour photography |
BE634670A (en) * | 1963-07-09 | |||
BE634665A (en) * | 1963-07-09 | |||
BE634669A (en) * | 1963-07-09 | 1964-01-09 | ||
US3622318A (en) * | 1970-03-20 | 1971-11-23 | Eastman Kodak Co | Photographic materials and processes |
DE2042922A1 (en) * | 1970-08-29 | 1972-03-02 | Agfa Gevaert AG, 5090 Leverkusen | Diffusion-resistant purple components for the production of photographic color images |
JPS566540B2 (en) * | 1973-03-31 | 1981-02-12 | ||
US4278598A (en) * | 1974-12-20 | 1981-07-14 | Eastman Kodak Company | Positive-working immobile intramolecular nucleophilic displacement compounds and photographic elements containing same |
US4013635A (en) * | 1975-02-26 | 1977-03-22 | Eastman Kodak Company | Cyan azo dye-providing compounds |
GB1571506A (en) * | 1976-02-23 | 1980-07-16 | Agfa Gevaert | 4-phenyl azo - 2 - pyrazolin - 5 - one colour coupler and their use in photography |
GB1585178A (en) * | 1976-09-10 | 1981-02-25 | Kodak Ltd | Photographic materials |
GB1568246A (en) * | 1976-11-15 | 1980-05-29 | Ciba Geigy Ag | Magentamasked colour couplers |
US4228070A (en) * | 1979-02-28 | 1980-10-14 | Eastman Kodak Company | Purification of photographic image-forming sulfonamido compounds employing immiscible solvents |
US4281143A (en) * | 1979-09-04 | 1981-07-28 | Eastman Kodak Company | Process for preparing 1-aryl-3-amino-5-pyrazolones |
JPS59116647A (en) | 1982-12-13 | 1984-07-05 | Konishiroku Photo Ind Co Ltd | Silver halide photosensitive material |
JPS59188641A (en) | 1983-04-11 | 1984-10-26 | Fuji Photo Film Co Ltd | Silver halide photographic emulsion |
JPS60143331A (en) | 1983-12-29 | 1985-07-29 | Fuji Photo Film Co Ltd | Silver halide photosensitive material |
CA1267557A (en) | 1985-05-16 | 1990-04-10 | Shigeharu Koboshi | Method for color-developing a silver halide photographic light-sensitive material |
AU588878B2 (en) | 1985-05-31 | 1989-09-28 | Konishiroku Photo Industry Co., Ltd. | Method for forming direct positive color image |
DE3530357A1 (en) * | 1985-08-24 | 1987-02-26 | Agfa Gevaert Ag | COLOR PHOTOGRAPHIC RECORDING MATERIAL |
AU591540B2 (en) | 1985-12-28 | 1989-12-07 | Konishiroku Photo Industry Co., Ltd. | Method of processing light-sensitive silver halide color photographic material |
US5354646A (en) * | 1986-03-26 | 1994-10-11 | Konishiroku Photo Industry Co., Ltd. | Method capable of rapidly processing a silver halide color photographic light-sensitive material |
JP2873486B2 (en) * | 1990-05-11 | 1999-03-24 | コニカ株式会社 | Silver halide color photographic materials |
JP2877579B2 (en) * | 1991-08-26 | 1999-03-31 | コニカ株式会社 | Silver halide color photographic materials |
US5385815A (en) | 1992-07-01 | 1995-01-31 | Eastman Kodak Company | Photographic elements containing loaded ultraviolet absorbing polymer latex |
EP0684511B1 (en) | 1994-05-20 | 2001-02-28 | Eastman Kodak Company | Low contrast film |
EP0686873B1 (en) | 1994-06-08 | 2000-04-19 | Eastman Kodak Company | Color photographic element containing new epoxy scavengers for residual magenta coupler |
EP0695968A3 (en) | 1994-08-01 | 1996-07-10 | Eastman Kodak Co | Viscosity reduction in a photographic melt |
EP0711804A3 (en) | 1994-11-14 | 1999-09-22 | Ciba SC Holding AG | Latent light stabilizers |
US5585228A (en) | 1994-11-30 | 1996-12-17 | Eastman Kodak Company | Benzotriazole based UV absorbing compounds and photographic elements containing them |
EP0762198B1 (en) | 1995-08-02 | 2000-10-04 | Eastman Kodak Company | Photographic elements comprising filter dyes |
US5723280A (en) | 1995-11-13 | 1998-03-03 | Eastman Kodak Company | Photographic element comprising a red sensitive silver halide emulsion layer |
US6183944B1 (en) | 1995-11-30 | 2001-02-06 | Eastman Kodak Company | Aggregated dyes for radiation-sensitive elements |
US5747236A (en) | 1996-01-26 | 1998-05-05 | Eastman Kodak Company | Silver halide light sensitive emulsion layer having enhanced photographic sensitivity |
DE69731568T2 (en) | 1996-01-26 | 2005-12-22 | Eastman Kodak Co. | Photosensitive silver halide emulsion layer with increased photographic speed |
US5747235A (en) | 1996-01-26 | 1998-05-05 | Eastman Kodak Company | Silver halide light sensitive emulsion layer having enhanced photographic sensitivity |
US20130052594A1 (en) | 2011-08-31 | 2013-02-28 | Diane M. Carroll-Yacoby | Motion picture films to provide archival images |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2584349A (en) * | 1944-11-10 | 1952-02-05 | Gen Aniline & Film Corp | Color forming development with an aromatic primary amino developer and alpha-[4-sulfophenylazo]-aceto-acet-2-4-dichloroanilide |
US2681338A (en) * | 1950-04-24 | 1954-06-15 | Ici Ltd | Azo coloring salts |
US2725291A (en) * | 1952-05-01 | 1955-11-29 | Eastman Kodak Co | Azo dye couplers having two coupling nuclei |
US2766231A (en) * | 1953-01-28 | 1956-10-09 | Ciba Ltd | Monoazo-dyestuffs |
-
1958
- 1958-10-06 US US765315A patent/US2983608A/en not_active Expired - Lifetime
-
1959
- 1959-10-06 FR FR806824A patent/FR1238590A/en not_active Expired
- 1959-10-06 GB GB33779/59A patent/GB937621A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0201033A2 (en) | 1985-04-30 | 1986-11-12 | Konica Corporation | A method for processing silver halide color photographic materials |
Also Published As
Publication number | Publication date |
---|---|
US2983608A (en) | 1961-05-09 |
FR1238590A (en) | 1960-08-12 |
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