GB932539A - Preparation of diethylaluminium hydride - Google Patents
Preparation of diethylaluminium hydrideInfo
- Publication number
- GB932539A GB932539A GB40664/59A GB4066459A GB932539A GB 932539 A GB932539 A GB 932539A GB 40664/59 A GB40664/59 A GB 40664/59A GB 4066459 A GB4066459 A GB 4066459A GB 932539 A GB932539 A GB 932539A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- preparation
- proportion
- hydrogen
- diethylaluminium hydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910000838 Al alloy Inorganic materials 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 239000010955 niobium Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/065—Aluminium compounds with C-aluminium linkage compounds with an Al-H linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Diethylaluminium hydride is prepared by reacting triethylaluminium with hydrogen and an aluminium alloy at elevated temperature and superatmospheric pressure, said alloy comprising a major proportion of aluminium and a minor proportion of one or more of the metals titanium, vanadium, zirconium and niobium. It is preferred that the proportion of aluminium should be at least 98% by weight. The reaction is carried out at a temperature between 80 and 200 DEG C. at a pressure between 60 and 350 atmospheres. An excess of hydrogen is used.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78320958A | 1958-12-29 | 1958-12-29 | |
| US58222A US3104252A (en) | 1958-12-29 | 1960-09-26 | Preparation of organoaluminum compounds in the presence of a catalytic amount of ti, zr, nb, v, sc, u, or hf |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB932539A true GB932539A (en) | 1963-07-31 |
Family
ID=26737371
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB40664/59A Expired GB932539A (en) | 1958-12-29 | 1959-11-30 | Preparation of diethylaluminium hydride |
| GB18796/61A Expired GB939824A (en) | 1958-12-29 | 1961-05-24 | Improvements in or relating to the preparation of organoaluminium compounds |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB18796/61A Expired GB939824A (en) | 1958-12-29 | 1961-05-24 | Improvements in or relating to the preparation of organoaluminium compounds |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3104252A (en) |
| BE (2) | BE594988A (en) |
| DE (2) | DE1181217B (en) |
| FR (1) | FR1243144A (en) |
| GB (2) | GB932539A (en) |
| NL (3) | NL265774A (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3387948A (en) * | 1962-03-30 | 1968-06-11 | Hercules Inc | Preparation of alkaline earth metal aluminum hydrides |
| US3387949A (en) * | 1962-03-30 | 1968-06-11 | Hercules Inc | Preparation of metal hydrides |
| US3373179A (en) * | 1962-09-14 | 1968-03-12 | Continental Oil Co | Method for the manufacture of dialkyl aluminum hydride compounds |
| NL301775A (en) * | 1962-12-28 | 1900-01-01 | ||
| US3388142A (en) * | 1963-07-12 | 1968-06-11 | Continental Oil Co | Method for producing dialkylaluminum hydride compounds |
| NL127426C (en) * | 1963-08-30 | |||
| US3394158A (en) * | 1963-10-02 | 1968-07-23 | Snam Spa | Complex aluminium hydrides partly substituted with alcoxylic groups |
| US3382269A (en) * | 1964-12-30 | 1968-05-07 | Continental Oil Co | Activation of aluminum in preparation of aluminum alkyls |
| US3428664A (en) * | 1965-01-27 | 1969-02-18 | Continental Oil Co | Distillative purification of aluminum alkyl |
| US3429695A (en) * | 1965-10-12 | 1969-02-25 | Ishikawajima Harima Heavy Ind | High strength aluminum alloy and its production method |
| US3505375A (en) * | 1966-11-01 | 1970-04-07 | Ethyl Corp | Process for producing alkyl aluminum compounds |
| US3470223A (en) * | 1967-02-02 | 1969-09-30 | Continental Oil Co | Solids purging from an aluminum alkyl stream |
| US3619181A (en) * | 1968-10-29 | 1971-11-09 | Aluminum Co Of America | Aluminum scandium alloy |
| FR2187928A2 (en) * | 1972-06-09 | 1974-01-18 | Ethyl Corp | Alkylaluminium cpds - from ternary or quaternary alloys contg aluminium,silicon,titanium and iron |
| US3853542A (en) * | 1973-01-08 | 1974-12-10 | Aluminum Co Of America | Process for promoting reactivity of aluminum |
| US3853931A (en) * | 1973-01-15 | 1974-12-10 | Aluminum Co Of America | Production of hydrocarbyl aluminum hydrides |
| US4529580A (en) * | 1982-12-15 | 1985-07-16 | Ethyl Corporation | Alkali metal aluminum hydride production |
| US4528176A (en) * | 1982-12-15 | 1985-07-09 | Ethyl Corporation | Sodium aluminum hydride production |
| US4512966A (en) * | 1983-12-02 | 1985-04-23 | Ethyl Corporation | Hydride production at moderate pressure |
| FR2607522B1 (en) * | 1986-12-02 | 1992-04-30 | Cegedur | PROCESS FOR INCREASING THE TEMPERATURE OF RECRYSTALLIZATION OF ALUMINUM AND ITS ALLOYS |
| US4882039A (en) * | 1986-12-04 | 1989-11-21 | Mobil Oil Corporation | Catalytic cracking of hydrocarbons with oxygen promoted alkali metal zeolite cracking catalyst |
| US5597529A (en) * | 1994-05-25 | 1997-01-28 | Ashurst Technology Corporation (Ireland Limited) | Aluminum-scandium alloys |
| CN102584879B (en) * | 2012-01-19 | 2014-05-07 | 营口市向阳催化剂有限责任公司 | Preparation method of aluminium triethyl |
| CN106467584B (en) * | 2015-08-21 | 2019-08-20 | 中国石油化工股份有限公司 | A kind of catalytic component, preparation method and application for vinyl polymerization |
| US11471984B2 (en) | 2018-06-28 | 2022-10-18 | Scandium International Mining Corporation | Control of recrystallization in cold-rolled AlMn(Mg)ScZr sheets for brazing applications |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2900402A (en) * | 1955-03-17 | 1959-08-18 | Monsanto Chemicals | Preparation of aluminum alkyls |
| NL109047C (en) * | 1955-04-01 | |||
| US2787626A (en) * | 1955-06-07 | 1957-04-02 | Ethyl Corp | Manufacture of triethylaluminum |
| US2931722A (en) * | 1956-11-21 | 1960-04-05 | Nat Lead Co | Aluminum-titanium master alloys |
| US2922714A (en) * | 1957-04-03 | 1960-01-26 | Union Carbide Corp | Columbium-tantalum-aluminum alloy |
| BE577477A (en) * | 1958-04-10 | |||
| AT215426B (en) * | 1958-04-10 | 1961-06-12 | Petrochemicals Ltd | Process for the production of aluminum compounds |
| BE593357A (en) * | 1959-04-16 | 1900-01-01 |
-
0
- BE BE614668D patent/BE614668A/xx unknown
- NL NL120205D patent/NL120205C/xx active
- NL NL246223D patent/NL246223A/xx unknown
- NL NL265774D patent/NL265774A/xx unknown
- BE BE594988D patent/BE594988A/xx unknown
-
1959
- 1959-11-30 GB GB40664/59A patent/GB932539A/en not_active Expired
- 1959-12-11 FR FR812849A patent/FR1243144A/en not_active Expired
-
1960
- 1960-09-26 US US58222A patent/US3104252A/en not_active Expired - Lifetime
-
1961
- 1961-05-24 GB GB18796/61A patent/GB939824A/en not_active Expired
- 1961-07-29 DE DEC32444A patent/DE1181217B/en active Pending
- 1961-07-29 DE DEC24749A patent/DE1185187B/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| GB939824A (en) | 1963-10-16 |
| NL265774A (en) | |
| FR1243144A (en) | 1960-10-07 |
| DE1181217B (en) | 1964-11-12 |
| NL246223A (en) | |
| BE614668A (en) | |
| US3104252A (en) | 1963-09-17 |
| NL120205C (en) | |
| BE594988A (en) | |
| DE1185187B (en) | 1965-01-14 |
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