GB932489A - Process of dyeing fibres - Google Patents
Process of dyeing fibresInfo
- Publication number
- GB932489A GB932489A GB28933/61A GB2893361A GB932489A GB 932489 A GB932489 A GB 932489A GB 28933/61 A GB28933/61 A GB 28933/61A GB 2893361 A GB2893361 A GB 2893361A GB 932489 A GB932489 A GB 932489A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dithio
- oxamide
- solution
- metal
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004043 dyeing Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OAEGRYMCJYIXQT-UHFFFAOYSA-N dithiooxamide Chemical compound NC(=S)C(N)=S OAEGRYMCJYIXQT-UHFFFAOYSA-N 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- -1 pyridylalkyl Chemical group 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 229910021645 metal ion Inorganic materials 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 125000004181 carboxyalkyl group Chemical group 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- QOPUBSBYMCLLKW-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]-4-hydroxybutanoic acid Chemical class OCCC(C(O)=O)N(CC(O)=O)CCN(CC(O)=O)CC(O)=O QOPUBSBYMCLLKW-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- RBUWXXZEECELIO-UHFFFAOYSA-N N',N'-bis(3-methoxypropyl)ethanedithioamide Chemical compound N(C(=S)C(=S)N)(CCCOC)CCCOC RBUWXXZEECELIO-UHFFFAOYSA-N 0.000 abstract 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004103 aminoalkyl group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 150000003841 chloride salts Chemical class 0.000 abstract 1
- 125000000068 chlorophenyl group Chemical group 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 210000003746 feather Anatomy 0.000 abstract 1
- 210000004209 hair Anatomy 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 125000003884 phenylalkyl group Chemical group 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 125000004076 pyridyl group Chemical group 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 239000012047 saturated solution Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/008—Preparing dyes in situ
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
Organic fibres or filaments, e.g. of polyamides, acrylic polymers, polyesters, cellulose acetate (including triacetate), natural and regenerated cellulose, silk and especially keratinous materials including human and animal hair, furs, feathers and wool, are dyed by treatment in the absence of nitrous acid or any salt thereof with an aqueous solution containing metal ions of one or more of the metals Co, Ni, Cu, Zn, Pd, Ag and Cd and with a dithio-oxamide. The metals are preferably in the form of sulphates or chlorides. The specified dithio-oxamides are of the formula <FORM:0932489/IV(a)/1> where R is hydrogen, alkyl, carboxyalkyl, aminoalkyl, sulphoalkyl, acetoalkyl, hydroxyalkyl, phenylalkyl, pyridylalkyl, phenylpyridyl, chlorophenyl, allyl, benzyl, furfuryl or pyridyl or are alkali metal or alkaline earth metal or ammonium salts of the carboxyalkyl and sulphoalkyl dithio-oxamides among which are, for example, dithio-oxamide, N,N1-dimethyl-dithio-oxamide, N,N1-bis(3-methoxypropyl) dithio-oxamide and N,N1-bis(2-sulphoethyl) dithio-oxamide dicalcium salt. The metal ions and the dithio-oxamide may be applied simultaneously or in either sequence; when applied from the same solution a complexing agent may be included, e.g. thiourea or alkali metal salts of hydroxyethyl-ethylene diaminetetraacetic acid. The concentration of both the metal salt and the dithio-oxamide solution may be from 0,00002 M up to a saturated solution, preferably 0,002 M, which solutions may also contain water-imiscible solvents, e.g. acetone and ethanol. In the preferred method of dyeing keratinous fibres the fibres are first soaked in a metal ion solution at 20 DEG -95 DEG C. at a pH of 4-10 and then soaked in a dithio-oxamide solution. Examples are given. Specification 521,648 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50323A US3075821A (en) | 1960-08-18 | 1960-08-18 | Process of dyeing keratinous fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB932489A true GB932489A (en) | 1963-07-31 |
Family
ID=21964588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28933/61A Expired GB932489A (en) | 1960-08-18 | 1961-08-10 | Process of dyeing fibres |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3075821A (en) |
| GB (1) | GB932489A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3215605A (en) * | 1962-04-25 | 1965-11-02 | Revlon | Method for coloring hair and other keratinaceous fibers with metal salts |
| CH425713A (en) * | 1964-07-07 | 1967-06-15 | Sandoz Ag | Process for dyeing polyamide fibers with water-soluble, non-metallizable dyes |
| US3973574A (en) * | 1965-11-25 | 1976-08-10 | Fumio Umezawa | Waving and straightening hair by producing metal chelates in the keratin of the hair |
| US3622380A (en) * | 1969-02-18 | 1971-11-23 | Universal Oil Prod Co | Coloring solution and use thereof |
| US3838966A (en) * | 1970-05-25 | 1974-10-01 | Mennen Co | Permanent but removable hair-coloring system |
| JPS5710085B2 (en) * | 1973-05-04 | 1982-02-24 | ||
| US4173453A (en) * | 1976-04-09 | 1979-11-06 | CDC Research Inc. | Topical hair coloring formulation in the form of suspension, lotion and cream |
| US4583986A (en) * | 1981-07-20 | 1986-04-22 | Combe Incorporated | Catalyzed bismuth dye system for human hair |
| DE3566915D1 (en) * | 1984-11-09 | 1989-01-26 | Ciba Geigy Ag | Process for improving the light fastness of dyed leathers |
| DE102006020049A1 (en) * | 2006-04-26 | 2007-10-31 | Henkel Kgaa | Product for dyeing and/or lightening keratin fibers, especially human hair, comprises an oxalic acid compound |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2505085A (en) * | 1947-09-25 | 1950-04-25 | Polaroid Corp | Light-polarizing, molecularly oriented, transparent, high polymeric plastic containing dichroic dithiooxamide stain |
-
1960
- 1960-08-18 US US50323A patent/US3075821A/en not_active Expired - Lifetime
-
1961
- 1961-08-10 GB GB28933/61A patent/GB932489A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3075821A (en) | 1963-01-29 |
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