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GB917253A - Herbicidal compounds and compositions and process for preparing same - Google Patents

Herbicidal compounds and compositions and process for preparing same

Info

Publication number
GB917253A
GB917253A GB30116/61A GB3011661A GB917253A GB 917253 A GB917253 A GB 917253A GB 30116/61 A GB30116/61 A GB 30116/61A GB 3011661 A GB3011661 A GB 3011661A GB 917253 A GB917253 A GB 917253A
Authority
GB
United Kingdom
Prior art keywords
propyl
dinitro
aniline
allyl
butyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30116/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eli Lilly and Co
Original Assignee
Eli Lilly and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eli Lilly and Co filed Critical Eli Lilly and Co
Publication of GB917253A publication Critical patent/GB917253A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/06Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
    • C07D295/073Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18Nitro compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/06Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention comprises substituted dinitro anilines of the general formula:- <FORM:0917253/IV (b)/1> wherein R is ethyl, n-propyl, n-butyl, or allyl; R1, R2, and R3 are methyl, ethyl, n-propyl, n-butyl, or allyl; or R and R1, or R2 and R3 may form with the nitrogen atom a piperidino or pyrrolidino radical; and R4 is halogen (fluorine, chlorine, or bromine), halo-alkyl, or alkyl of 1-4 carbon atoms. Specified compounds of the above formula include N,N-di-n - propyl-4-trifluoromethyl-2.6-dinitro-aniline, N.N-di-n-propyl-2.6-dinitro-p-toluidine, N.N-diallyl-2.6-dinitro-aniline, 2.6-dinitro-1-piperidinobenzene, and 2.6 - dinitro-1-pyrrolidinobenzene. These compounds may be obtained by reacting 2.6-dinitrochlorobenzene or a substituted 2.6 - dinitrochlorobenzene with a secondary amine in an inert solvent such as benzene or ethanol. They may be used as herbicides.ALSO:Herbicidal compositions comprise as active ingredients substituted dinitro anilines of the general formula <FORM:0917253/VI/1> <FORM:0917253/VI/2> wherein R is ethyl, n-propyl, n-butyl or allyl; R1, R2 and R3 are methyl, ethyl, n-propyl, n-butyl, or allyl; or R and R1, or R2 and R3 may form with the nitrogen atom a piperidino or pyrrolidino radical; and R4 is halogen (fluorine, chlorine, or bromine), halo-alkyl, or alkyl of 1-4 carbon atoms. These compounds may be used as selective herbicides for killing germinating grasses in the presence of established grasses and most broad-leaf plants. They may be applied in the form of sprays, or as granules, or upon carriers such as vermiculite or peat. Preferred compounds of the above formul are those with two n-propyl groups attached to the amino nitrogen e.g. N.N-di-n-propyl - 2.6 - dinitro - aniline, and N.N - di - n-propyl - 4 - trifluoromethyl - 2.6 - dinitro - aniline.
GB30116/61A 1960-08-31 1961-08-21 Herbicidal compounds and compositions and process for preparing same Expired GB917253A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US5306660A 1960-08-31 1960-08-31

Publications (1)

Publication Number Publication Date
GB917253A true GB917253A (en) 1963-01-30

Family

ID=21981713

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30116/61A Expired GB917253A (en) 1960-08-31 1961-08-21 Herbicidal compounds and compositions and process for preparing same

Country Status (5)

Country Link
CY (1) CY315A (en)
DE (1) DE1300727B (en)
GB (1) GB917253A (en)
NL (1) NL268751A (en)
OA (1) OA01731A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3227734A (en) * 1964-11-13 1966-01-04 Shell Oil Co Herbicidal 4-methylsulfonyl-2,6-dinitro-n,n-substituted anilines
DE2013510A1 (en) * 1969-04-01 1970-10-08 United States Borax & Chemical Corp., Los Angeles, Calif. (V.St.A.) New herbicides
FR2085214A1 (en) * 1970-02-10 1971-12-24 Baut Jacques
WO2023222836A1 (en) 2022-05-20 2023-11-23 Syngenta Crop Protection Ag Herbicidal compositions
WO2024023035A1 (en) 2022-07-25 2024-02-01 Syngenta Crop Protection Ag Herbicidal compositions

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3227734A (en) * 1964-11-13 1966-01-04 Shell Oil Co Herbicidal 4-methylsulfonyl-2,6-dinitro-n,n-substituted anilines
DE2013510A1 (en) * 1969-04-01 1970-10-08 United States Borax & Chemical Corp., Los Angeles, Calif. (V.St.A.) New herbicides
FR2085214A1 (en) * 1970-02-10 1971-12-24 Baut Jacques
WO2023222836A1 (en) 2022-05-20 2023-11-23 Syngenta Crop Protection Ag Herbicidal compositions
WO2024023035A1 (en) 2022-07-25 2024-02-01 Syngenta Crop Protection Ag Herbicidal compositions

Also Published As

Publication number Publication date
DE1300727B (en) 1969-08-07
OA01731A (en) 1969-12-15
CY315A (en) 1965-08-31
NL268751A (en)

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