GB916597A - Process of recovering and purifying benzene - Google Patents
Process of recovering and purifying benzeneInfo
- Publication number
- GB916597A GB916597A GB12817/59A GB1281759A GB916597A GB 916597 A GB916597 A GB 916597A GB 12817/59 A GB12817/59 A GB 12817/59A GB 1281759 A GB1281759 A GB 1281759A GB 916597 A GB916597 A GB 916597A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzene
- hydrogen
- gas
- recovering
- dealkylated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title abstract 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004523 catalytic cracking Methods 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 239000011280 coal tar Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/04—Benzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
- C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
- C07C4/18—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Benzene is purified and recovered from an impure stock by subjecting to catalytic cracking in the presence of hydrogen and a catalyst containing 10-15% chromium oxide supported on high purity, low sodium content, gamma alumina at above 1150 DEG F. and separating benzene from the gas formed. Sulphur compounds are destroyed, paraffinic impurities cracked to gas and homologues of benzene are dealkylated. Suitable stocks are coal tar light oil and petroleum catalytic reformates boiling above the gasoline range, e.g. 300-400 DEG F. Suitable conditions are a space velocity of 1-5 wt./wt./hr., preferably to give a residence time of about 12 seconds, a pressure of 100-1,000 p.s.i.g. and a hydrogen to hydrocarbon molar ratio of 1-10:1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US728620A US2951886A (en) | 1958-04-15 | 1958-04-15 | Recovery and purification of benzene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB916597A true GB916597A (en) | 1963-01-23 |
Family
ID=24927590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12817/59A Expired GB916597A (en) | 1958-04-15 | 1959-04-15 | Process of recovering and purifying benzene |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US2951886A (en) |
| BE (1) | BE577729A (en) |
| DE (1) | DE1270017B (en) |
| ES (1) | ES248649A1 (en) |
| FR (1) | FR1221539A (en) |
| GB (1) | GB916597A (en) |
| NL (1) | NL113125C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081259A (en) * | 1963-03-12 | Coke oven light oil purification | ||
| NL256487A (en) * | 1959-10-05 | |||
| US3207802A (en) * | 1960-12-14 | 1965-09-21 | Air Prod & Chem | Purification of coke-oven light oil |
| US3285986A (en) * | 1962-03-12 | 1966-11-15 | Phillips Petroleum Co | Separation process |
| US3213151A (en) * | 1962-07-27 | 1965-10-19 | Phillips Petroleum Co | Recovery of hydrogen from gaseous mixtures and improved hydrogenation process |
| US3284522A (en) * | 1964-04-20 | 1966-11-08 | Air Prod & Chem | Cyclohexane production |
| US4451687A (en) * | 1982-07-06 | 1984-05-29 | Air Products And Chemicals, Inc. | Catalyst for the hydrodealkylation of alkylaromatic compounds |
| US4436836A (en) | 1982-07-06 | 1984-03-13 | Air Products And Chemicals, Inc. | Catalyst for the hydrodealkylation of alkylaromatic compounds |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2734929A (en) * | 1956-02-14 | Dealkylation of hydrocarbons | ||
| US2402854A (en) * | 1940-06-13 | 1946-06-25 | Universal Oil Prod Co | Hydrocarbon conversion |
| GB667145A (en) * | 1949-10-26 | 1952-02-27 | Peter William Reynolds | Improvements in and relating to the production of alumina |
| US2705733A (en) * | 1950-05-20 | 1955-04-05 | Basf Ag | Purification of crude benzene |
| US2780661A (en) * | 1951-08-15 | 1957-02-05 | Exxon Research Engineering Co | Reforming followed by hydrodealkylation |
| US2773917A (en) * | 1952-09-16 | 1956-12-11 | Socony Mobil Oil Co | Demethylation over chromia or molybdena catalysts |
| US2774801A (en) * | 1952-09-16 | 1956-12-18 | Socony Mobil Oil Co Inc | Conversion of methylnaphthalenes |
-
0
- BE BE577729D patent/BE577729A/xx unknown
- NL NL113125D patent/NL113125C/xx active
-
1958
- 1958-04-15 US US728620A patent/US2951886A/en not_active Expired - Lifetime
-
1959
- 1959-04-13 DE DEP1270A patent/DE1270017B/en active Pending
- 1959-04-14 ES ES0248649A patent/ES248649A1/en not_active Expired
- 1959-04-15 GB GB12817/59A patent/GB916597A/en not_active Expired
- 1959-04-15 FR FR792137A patent/FR1221539A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2951886A (en) | 1960-09-06 |
| DE1270017B (en) | 1968-06-12 |
| FR1221539A (en) | 1960-06-02 |
| NL113125C (en) | |
| BE577729A (en) | |
| ES248649A1 (en) | 1959-09-16 |
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