GB913482A - Improvements in and relating to preparing pyrylium compounds - Google Patents
Improvements in and relating to preparing pyrylium compoundsInfo
- Publication number
- GB913482A GB913482A GB2942561A GB2942561A GB913482A GB 913482 A GB913482 A GB 913482A GB 2942561 A GB2942561 A GB 2942561A GB 2942561 A GB2942561 A GB 2942561A GB 913482 A GB913482 A GB 913482A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pyrylium
- hydroxy
- chloride
- giving
- relating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/78—Ring systems having three or more relevant rings
- C07D311/92—Naphthopyrans; Hydrogenated naphthopyrans
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Condensed pyrylium chlorides are prepared by reacting an aromatic o-hydroxyaldehyde with a ketone (containing an a -methylene group) in presence of POCl3 and a hydroxylic organic solvent. In examples, 2-hydroxy-1-naphthaldehyde is reacted with (1) 4-methoxy-acetophenone in ethanol giving 2-(4-methoxyphenyl) - naphtho - (11 : 21-5 : 6)-pyrylium-(1 : 2)-chloride; (2) levulinic acid in ethyleneglycol monomethyl ether giving 2-(2-hydroxy-5 : 6-benzostyryl) - 3 - (acetic acid - 2 - methoxyethyl ester) - naphtho - (11 : 21-5 : 6) - pyrylium-(1 : 2)-chloride, and (3) benzylacetone giving 2-(2-hydroxy - 5 : 6 - benzostyryl)-3-benzylnaphtho-(11 : 21-5 : 6) -pyrylium-(1 : 2)-chloride.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEW0028382 | 1960-08-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB913482A true GB913482A (en) | 1962-12-19 |
Family
ID=7598916
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2942561A Expired GB913482A (en) | 1960-08-16 | 1961-08-15 | Improvements in and relating to preparing pyrylium compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB913482A (en) |
-
1961
- 1961-08-15 GB GB2942561A patent/GB913482A/en not_active Expired
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