GB908205A - Regenerated cellulose film and process for producing same - Google Patents
Regenerated cellulose film and process for producing sameInfo
- Publication number
- GB908205A GB908205A GB10633/61A GB1063361A GB908205A GB 908205 A GB908205 A GB 908205A GB 10633/61 A GB10633/61 A GB 10633/61A GB 1063361 A GB1063361 A GB 1063361A GB 908205 A GB908205 A GB 908205A
- Authority
- GB
- United Kingdom
- Prior art keywords
- soluble
- water
- polyamine
- film
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004627 regenerated cellulose Substances 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 5
- 229920000768 polyamine Polymers 0.000 abstract 5
- 238000004873 anchoring Methods 0.000 abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 239000007795 chemical reaction product Substances 0.000 abstract 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 abstract 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- -1 alkylene diol Chemical class 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229920001187 thermosetting polymer Polymers 0.000 abstract 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 abstract 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 abstract 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 1
- 229940035437 1,3-propanediol Drugs 0.000 abstract 1
- 229920002101 Chitin Polymers 0.000 abstract 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 1
- 239000001856 Ethyl cellulose Substances 0.000 abstract 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 235000013871 bee wax Nutrition 0.000 abstract 1
- 239000012166 beeswax Substances 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 235000013869 carnauba wax Nutrition 0.000 abstract 1
- 239000004203 carnauba wax Substances 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 229920001249 ethyl cellulose Polymers 0.000 abstract 1
- 235000019325 ethyl cellulose Nutrition 0.000 abstract 1
- 238000001879 gelation Methods 0.000 abstract 1
- 239000012943 hotmelt Substances 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 239000012170 montan wax Substances 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical class CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 abstract 1
- 238000007761 roller coating Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 abstract 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000001993 wax Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/06—Cellulose hydrate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A non-fibrous regenerated cellulose film has a uniform small content as anchoring agent of an initially water-soluble, thermosetting polyamido-polyamine-epichlorohydrin reaction product in thermoset form. The anchoring agent is conveniently made by reacting a water-soluble polyalkylene-polyamine with a water-soluble dicarboxylic acid to form a water-soluble cationic polyamido-polyamine, and reacting this with epichlorohydrin, the latter reaction being stopped short of gelation so that completion of the cross-linking reaction and conversion of the reaction product to insoluble gel form can take place after application of the anchoring agent to the film, when the film is heated and dried. A proportion of the polyalkylene polyamine can be replaced with a water-soluble alkylene diol, e.g. glycol, 1,3-propane-diol, diethylene-glycol, and tetraethylene glycol. Specified dicarboxylic acids include succinic, adipic, pimelic, and azelaic. Polyalkylene-polyamines mentioned include diethylenetriamine, tetraethylene pentamine, the propylenediamines, 3,31-iminobispropylamine, and, in general, any water-soluble polyamine having a functionality of at least two for carboxylic acids and a third functionality for epichlorohydrin as cross-linking agent. The film may be impregnated with an aqueous solution of the reaction product as anchoring agent and dried at 150 DEG -250 DEG F. to thermostat the agent at least to an insoluble gel state. The aqueous solution may also contain a plasticizer, suitably a polyhydric alcohol, e.g. glycerol, and desirably has a pH of at least 6, suitably 6-11. A hydrophobic organic topcoat may be applied to at least one side of the treated film, and specified topcoats include nitrocellulose, cellulose acetate, methyl cellulose, ethyl cellulose, polyethylene, deacetylated chitin, vinyl chloride-vinylidene chloride copolymer, rubber, chlorinated rubber, rubber hydrochloride, butyl methacrylate, moisture-resistant lacquers, waxes, e.g. montan wax, beeswax, and carnauba wax, and printer's ink. Topcoats may be applied from hot melt, organic solution or aqueous emulsion by roller-coating, spraying, or impregnation. Specification 865,727 and U.S.A. Specification 2,573,956 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1884460A | 1960-03-31 | 1960-03-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB908205A true GB908205A (en) | 1962-10-17 |
Family
ID=21790053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB10633/61A Expired GB908205A (en) | 1960-03-31 | 1961-03-23 | Regenerated cellulose film and process for producing same |
Country Status (2)
| Country | Link |
|---|---|
| BE (1) | BE601947A (en) |
| GB (1) | GB908205A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2162204A1 (en) * | 1971-12-15 | 1973-06-20 | Kalle Ag | METHOD FOR PRODUCING A SYNTHETIC RESIN COATED SAUSAGE CASE FROM REGENERATED CELLULOSE |
| US4397337A (en) | 1981-03-07 | 1983-08-09 | Hoechst Aktiengesellschaft | Tubular casing suitable for foodstuffs and process for its manufacture |
| US4401135A (en) | 1980-04-05 | 1983-08-30 | Hoechst Aktiengesellschaft | Tubular casing with glued seam and process for its manufacture |
| US4410011A (en) | 1980-10-25 | 1983-10-18 | Hoechst Aktiengesellschaft | Tubular casing with glued seam and its manufacture and use for curved or ring-shaped sausages |
| US4503115A (en) * | 1981-12-04 | 1985-03-05 | Hoechst Aktiengesellschaft | Plate-shaped molded article and process for its preparation and use |
| US4528225A (en) * | 1982-07-30 | 1985-07-09 | Hoechst Aktiengesellschaft | Easily peelable sausage casing having a glued seam, process for its manufacture, and its use |
| US4562101A (en) * | 1982-05-03 | 1985-12-31 | Hoechst Aktiengesellschaft | Shirred sausage casing and process for its production |
-
1961
- 1961-03-23 GB GB10633/61A patent/GB908205A/en not_active Expired
- 1961-03-29 BE BE601947A patent/BE601947A/en unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2162204A1 (en) * | 1971-12-15 | 1973-06-20 | Kalle Ag | METHOD FOR PRODUCING A SYNTHETIC RESIN COATED SAUSAGE CASE FROM REGENERATED CELLULOSE |
| US4401135A (en) | 1980-04-05 | 1983-08-30 | Hoechst Aktiengesellschaft | Tubular casing with glued seam and process for its manufacture |
| US4410011A (en) | 1980-10-25 | 1983-10-18 | Hoechst Aktiengesellschaft | Tubular casing with glued seam and its manufacture and use for curved or ring-shaped sausages |
| US4397337A (en) | 1981-03-07 | 1983-08-09 | Hoechst Aktiengesellschaft | Tubular casing suitable for foodstuffs and process for its manufacture |
| US4503115A (en) * | 1981-12-04 | 1985-03-05 | Hoechst Aktiengesellschaft | Plate-shaped molded article and process for its preparation and use |
| US4562101A (en) * | 1982-05-03 | 1985-12-31 | Hoechst Aktiengesellschaft | Shirred sausage casing and process for its production |
| US4528225A (en) * | 1982-07-30 | 1985-07-09 | Hoechst Aktiengesellschaft | Easily peelable sausage casing having a glued seam, process for its manufacture, and its use |
Also Published As
| Publication number | Publication date |
|---|---|
| BE601947A (en) | 1961-09-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB908205A (en) | Regenerated cellulose film and process for producing same | |
| DE839159T1 (en) | GEL COMPOSITION BASED ON POLYSACHARIDES | |
| GB909494A (en) | Emulsions containing synthetic resins | |
| DE69132818D1 (en) | Process for the surface treatment of absorbent resins | |
| DE69024495D1 (en) | CYCLODEXTRINE POLYMER BEADS | |
| US2887116A (en) | Treatment of keratinous material | |
| US1942146A (en) | Impregnated and superficially smoothed article | |
| GB1090505A (en) | Improvements in method for producing coated papers | |
| US2402331A (en) | Treatment of wood | |
| US4023974A (en) | Unburnt lead refill for writing and drawing pencils | |
| US2575443A (en) | Process for the manufacture of moistureproof sheet material | |
| KR960037785A (en) | Latex dispersions containing hydroxyl and carboxyl functionalities and their use for the preparation of coatings | |
| US2691604A (en) | Hardening of polyvinyl alcohol coatings on paper | |
| US2573957A (en) | Process for treating nonfibrous cellulose film and resulting product | |
| US2764507A (en) | Treatment of films with methylolcarbamyl polyazaalkane resins | |
| US2542353A (en) | Method of making retractile articles | |
| US3078181A (en) | Process for the manufacture of coated paper | |
| GB985276A (en) | A process for preparing dispersing agents and dispersing agent prepared thereby | |
| US3316120A (en) | Process for preparing topcoated plasticized non-fibrous regenerated cellulose film and the resultant product | |
| US1979936A (en) | Method of coating and the product resulting therefrom | |
| GB786764A (en) | Improvements in or relating to the production of moisture-proof sheet wrapping materials having a normally solid polyethylene plastic coating | |
| GB839204A (en) | Improvements in or relating to thermoplastic synthetic substances | |
| GB957280A (en) | Laundry bag | |
| JPH0467486B2 (en) | ||
| JPS60210940A (en) | Production of regenerated cellulose film coated with coloredresin |