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GB902437A - Improvements in or relating to the catalytic hydrogenation of gas oils - Google Patents

Improvements in or relating to the catalytic hydrogenation of gas oils

Info

Publication number
GB902437A
GB902437A GB2753858A GB2753858A GB902437A GB 902437 A GB902437 A GB 902437A GB 2753858 A GB2753858 A GB 2753858A GB 2753858 A GB2753858 A GB 2753858A GB 902437 A GB902437 A GB 902437A
Authority
GB
United Kingdom
Prior art keywords
catalyst
fraction
pour point
hydrogen
point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2753858A
Inventor
Ghislain Marc De Mente Thierry
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Labofina SA
Original Assignee
Labofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL242628D priority Critical patent/NL242628A/xx
Application filed by Labofina SA filed Critical Labofina SA
Priority to GB2753858A priority patent/GB902437A/en
Priority to FR803637A priority patent/FR1361851A/en
Priority to DE1959L0034054 priority patent/DE1236701B/en
Publication of GB902437A publication Critical patent/GB902437A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A process for the reduction of the pour point of a petroleum gas oil distillate by catalytic hydrogenation comprises hydrogenating the distillate (which has a pour point higher than 0 DEG F. and a viscosity lower than 10 centistokes at 100 DEG F.) in the presence of a catalyst comprising oxides of metals of Group VI and VIII supported on a mixed silica-alumina base (the silica content of the catalyst being less than 40% of the total weight of the catalyst) at a temperature from 400 DEG to 450 DEG C. (but below the temperature at which substantial cracking of the distillate occurs) and at a pressure from 5 to 100 kg./cm2 (but above the equilibrium pressure at which the amount of hydrogen evolved in the reaction is equal to the amount of hydrogen consumed), with a hydrogen recycling rate of at most 15 mols. of hydrogen per average mol. of charge and a charge delivery rate of 0,5 to 10 v./v./hr. The catalyst preferably comprises oxides of cobalt and molybdenum supported on silica-alumina. The product of the process comprises mainly a fraction whose initial boiling point is identical with that of the starting material but which has, with respect to the latter, a lower pour point as well as a reduced sulphur content and a higher Diesel Index. The total reaction product may be separated by distillation into various fractions, for example (1) a gas oil fraction the cut point of which is set so that the fraction conforms to gas oil specifications, particularly as regards the flash point and pour point, and (2) a petrol fraction which can either be used as such or preferably as a charge to a reforming process. Specification 749,850 is referred to.
GB2753858A 1958-08-27 1958-08-27 Improvements in or relating to the catalytic hydrogenation of gas oils Expired GB902437A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
NL242628D NL242628A (en) 1958-08-27
GB2753858A GB902437A (en) 1958-08-27 1958-08-27 Improvements in or relating to the catalytic hydrogenation of gas oils
FR803637A FR1361851A (en) 1958-08-27 1959-08-25 Process for improving diesel
DE1959L0034054 DE1236701B (en) 1958-08-27 1959-08-25 Process for lowering the pour point of gas oils

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2753858A GB902437A (en) 1958-08-27 1958-08-27 Improvements in or relating to the catalytic hydrogenation of gas oils

Publications (1)

Publication Number Publication Date
GB902437A true GB902437A (en) 1962-08-01

Family

ID=10261207

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2753858A Expired GB902437A (en) 1958-08-27 1958-08-27 Improvements in or relating to the catalytic hydrogenation of gas oils

Country Status (4)

Country Link
DE (1) DE1236701B (en)
FR (1) FR1361851A (en)
GB (1) GB902437A (en)
NL (1) NL242628A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1234901B (en) * 1962-12-03 1967-02-23 California Research Corp Process for the production of gasoline and medium distillates
EP0044965A1 (en) * 1980-07-28 1982-02-03 Union Oil Company Of California Catalyst and process for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
JPS59193137A (en) * 1983-03-31 1984-11-01 Res Assoc Residual Oil Process<Rarop> Composition containing zeolite and hydrocracking catalyst using it
JPS59196745A (en) * 1983-03-31 1984-11-08 Res Assoc Residual Oil Process<Rarop> Iron-containing zeolite composition
US4790927A (en) 1981-05-26 1988-12-13 Union Oil Company Of California Process for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
US4877762A (en) 1981-05-26 1989-10-31 Union Oil Company Of California Catalyst for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
CN113654941A (en) * 2021-09-01 2021-11-16 西南石油大学 Multifunctional teaching experiment system and method for measuring pressure in petroleum field

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE12392C (en) * F. O. R'JPPERT in Chemnitz, Schillerplatz 9 Adjustable seat with self-adjusting backrest and footplate
US2689821A (en) * 1950-10-17 1954-09-21 Union Oil Co Hydrocarbon conversion process
US2760907A (en) * 1953-09-01 1956-08-28 Union Oil Co Hydrocarbon conversion process and catalyst
FR1108294A (en) * 1953-09-18 1956-01-11 Basf Ag Process for the refining, by catalytic hydrogenation under pressure, of mineral oils and tars, as well as their distillation, cracking and hydrogenation products
BE537215A (en) * 1954-04-14
NL198189A (en) * 1954-06-21
GB785158A (en) * 1954-12-21 1957-10-23 Exxon Research Engineering Co Methods of preparing hydrofining catalysts and processes for using same
GB793812A (en) * 1955-08-17 1958-04-23 British Petroleum Co Improvements relating to the catalytic desulphurisation of hydrocarbons

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1234901B (en) * 1962-12-03 1967-02-23 California Research Corp Process for the production of gasoline and medium distillates
EP0044965A1 (en) * 1980-07-28 1982-02-03 Union Oil Company Of California Catalyst and process for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
US4790927A (en) 1981-05-26 1988-12-13 Union Oil Company Of California Process for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
US4877762A (en) 1981-05-26 1989-10-31 Union Oil Company Of California Catalyst for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
JPS59193137A (en) * 1983-03-31 1984-11-01 Res Assoc Residual Oil Process<Rarop> Composition containing zeolite and hydrocracking catalyst using it
JPS59196745A (en) * 1983-03-31 1984-11-08 Res Assoc Residual Oil Process<Rarop> Iron-containing zeolite composition
JPH0555189B2 (en) * 1983-03-31 1993-08-16 Jushitsuyu Taisaku Gijutsu
JPH0555188B2 (en) * 1983-03-31 1993-08-16 Jushitsuyu Taisaku Gijutsu
CN113654941A (en) * 2021-09-01 2021-11-16 西南石油大学 Multifunctional teaching experiment system and method for measuring pressure in petroleum field
CN113654941B (en) * 2021-09-01 2024-04-05 西南石油大学 Multifunctional teaching experiment system and method for measuring pressure in petroleum field

Also Published As

Publication number Publication date
NL242628A (en)
FR1361851A (en) 1964-05-29
DE1236701B (en) 1967-03-16

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