GB900123A - Improvements in or relating to the production of alkyl-or aryl-halosilanes - Google Patents
Improvements in or relating to the production of alkyl-or aryl-halosilanesInfo
- Publication number
- GB900123A GB900123A GB285560A GB285560A GB900123A GB 900123 A GB900123 A GB 900123A GB 285560 A GB285560 A GB 285560A GB 285560 A GB285560 A GB 285560A GB 900123 A GB900123 A GB 900123A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicon
- alloy
- copper
- catalyst
- ferrosilicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052710 silicon Inorganic materials 0.000 abstract 9
- 239000010703 silicon Substances 0.000 abstract 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 7
- 229910045601 alloy Inorganic materials 0.000 abstract 6
- 239000000956 alloy Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 5
- 229910000519 Ferrosilicon Inorganic materials 0.000 abstract 4
- 239000000376 reactant Substances 0.000 abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 3
- 239000004411 aluminium Substances 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 229910052802 copper Inorganic materials 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- 239000011701 zinc Substances 0.000 abstract 3
- 229910052725 zinc Inorganic materials 0.000 abstract 3
- 229910018067 Cu3Si Inorganic materials 0.000 abstract 2
- 229910000676 Si alloy Inorganic materials 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 abstract 2
- WCCJDBZJUYKDBF-UHFFFAOYSA-N copper silicon Chemical compound [Si].[Cu] WCCJDBZJUYKDBF-UHFFFAOYSA-N 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001502 aryl halides Chemical class 0.000 abstract 1
- YGZSVWMBUCGDCV-UHFFFAOYSA-N chloro(methyl)silane Chemical class C[SiH2]Cl YGZSVWMBUCGDCV-UHFFFAOYSA-N 0.000 abstract 1
- NBWIIOQJUKRLKW-UHFFFAOYSA-N chloro(phenyl)silane Chemical class Cl[SiH2]C1=CC=CC=C1 NBWIIOQJUKRLKW-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- -1 impurities) Chemical compound 0.000 abstract 1
- ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 abstract 1
- 229940102396 methyl bromide Drugs 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 150000003376 silicon Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/16—Preparation thereof from silicon and halogenated hydrocarbons direct synthesis
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/10—Alloys based on copper with silicon as the next major constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
Alkyl or aryl halosilanes are prepared by reacting an alkyl or aryl halide with silicon in the presence of a catalyst comprising a copper-silicon alloy containing 5 to 25% by weight of silicon or ferrosilicon (including impurities), the catalyst alloy and silicon reactant having been sintered at temperatures up to 1250 DEG C. in a reducing or inert atmosphere or in a vacuum before reacting with the halide. An accelerator such as zinc or aluminium may be included in the alloy. The proportion of copper is preferably 1 to 50% by weight of the total silicon. A particularly preferred catalyst alloy is one which corresponds to the formula Cu3Si. The silicon reactant may also be in the form of ferrosilicon. The examples describe the preparation of mixtures of methylchlorosilanes and of phenylchlorosilanes; the Specification also mentions methyl bromide and isopropyl chloride as reactants.ALSO:A copper-silicon alloy used as catalyst in the preparation of organohalosilanes (see Group IV (a)) contains 5 to 25% by weight of silicon or ferrosilicon including the usual impurities, the remainder consisting of copper and optionally an accelerator, e.g. zinc or aluminium. A particularly preferred alloy corresponds to the formula Cu3Si(12.8% Si). The alloy is itself sintered with the silicon used for the preparation of the silane, at temperatures up to 1250 DEG C. in a reducing or inert atmosphere or in a vacuum. This silicon reactant may also be ferrosilicon. In the final mixture, the copper preferably comprises 1 to 50% by weight. The proportion of aluminium in the catalyst alloy should not exceed 10%; the zinc is referred to in proportions of around 1% to 7%.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEG26234A DE1158976B (en) | 1959-01-26 | 1959-01-26 | Process for the production of methylchlorosilane mixtures with an increased proportion of dimethyldichlorosilane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB900123A true GB900123A (en) | 1962-07-04 |
Family
ID=7122865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB285560A Expired GB900123A (en) | 1959-01-26 | 1960-01-26 | Improvements in or relating to the production of alkyl-or aryl-halosilanes |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1158976B (en) |
| FR (1) | FR1244879A (en) |
| GB (1) | GB900123A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3233731A4 (en) * | 2014-12-18 | 2018-10-17 | Dow Silicones Corporation | Method for producing aryl-functional silanes |
| CN112342422A (en) * | 2020-10-27 | 2021-02-09 | 湖北新蓝天新材料股份有限公司 | Copper-silicon alloy material and preparation method and application thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE5348C (en) * | PAPPERITZ & AVERKAMP, Maschinenfabrikanten, in Berlin, Blumenstrafse 37 | Innovations to grist mills | ||
| US2380995A (en) * | 1941-09-26 | 1945-08-07 | Gen Electric | Preparation of organosilicon halides |
| GB575673A (en) * | 1942-03-04 | 1946-02-28 | British Thomson Houston Co Ltd | Improvements in and relating to preparation of organosilicon halides |
| US2427605A (en) * | 1945-03-15 | 1947-09-16 | Gen Electric | Preparation of alkylhalogenosilanes |
| DE950124C (en) * | 1954-12-21 | 1956-10-04 | Buna Chem Werke Veb | Process for the production of dialkyldichlorosilanes from alkyl chlorides and an activated silicon-copper mixture |
-
1959
- 1959-01-26 DE DEG26234A patent/DE1158976B/en active Pending
-
1960
- 1960-01-12 FR FR815401A patent/FR1244879A/en not_active Expired
- 1960-01-26 GB GB285560A patent/GB900123A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3233731A4 (en) * | 2014-12-18 | 2018-10-17 | Dow Silicones Corporation | Method for producing aryl-functional silanes |
| CN112342422A (en) * | 2020-10-27 | 2021-02-09 | 湖北新蓝天新材料股份有限公司 | Copper-silicon alloy material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1158976B (en) | 1963-12-12 |
| FR1244879A (en) | 1960-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB645314A (en) | Improvements in and relating to the preparation of dialkyl-substituted dihalogenosilanes | |
| US5068386A (en) | Preparation of tertiary-hydrocarbylsilyl compounds | |
| Zeitler et al. | Tetrakistriphenylsiloxytitanium and Some Related Compounds1 | |
| GB900123A (en) | Improvements in or relating to the production of alkyl-or aryl-halosilanes | |
| GB692669A (en) | Improvements in or relating to organosilyl alcohols | |
| GB777086A (en) | Improvements in or relating to the production of phenylchlorosilanes | |
| GB817098A (en) | Process for the manufacture of organo-halogen-silanes | |
| Westermark | Preparation of some organic silicon hydrides | |
| GB626519A (en) | Improvements in and relating to the preparation of organohalogenosilanes | |
| GB1134843A (en) | Process for the preparation of hydrocarbylhalogenosilanes | |
| US6156918A (en) | Process for the preparation of silanes, with a tertiary hydrocarbon group in the a-position relative to the silicon atom | |
| GB987443A (en) | Process for the alkylation of halogenosilanes | |
| GB907462A (en) | Improvements in or relating to the manufacture of boron hydrides and boron hydrides containing organic substituent radicals | |
| GB1009605A (en) | Process for the manufacture of alkylchlorosilanes | |
| GB1364199A (en) | Silicon containing dioxolane derivatives | |
| US3631193A (en) | Tris(dimethylhydrogensiloxy) - 3 3 3-trifluoropropylsilane vinyltriacetoxysilane adducts | |
| GB928441A (en) | New complex compounds of transition metals | |
| GB915479A (en) | Preparation of organosilicon compounds | |
| GB671710A (en) | Improvements in or relating to chlorosilanes | |
| GB876708A (en) | Process for producing alkylhydrosilanes | |
| US3395167A (en) | Preparation of silalactones | |
| GB922026A (en) | Organosilicon compounds | |
| Unno et al. | Borderline of hydrogen bonding of silanols | |
| GB848249A (en) | Improvements relating to the preparation of alkyl halogenosilanes | |
| GB851868A (en) | Preparation of organohalogenosilanes |