GB883033A - Phenolic antioxidants - Google Patents
Phenolic antioxidantsInfo
- Publication number
- GB883033A GB883033A GB1048559A GB1048559A GB883033A GB 883033 A GB883033 A GB 883033A GB 1048559 A GB1048559 A GB 1048559A GB 1048559 A GB1048559 A GB 1048559A GB 883033 A GB883033 A GB 883033A
- Authority
- GB
- United Kingdom
- Prior art keywords
- groups
- hydrogen atoms
- alkyl groups
- compounds
- organic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002530 phenolic antioxidant Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000011368 organic material Substances 0.000 abstract 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 3
- 230000006866 deterioration Effects 0.000 abstract 3
- 229910001882 dioxygen Inorganic materials 0.000 abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 3
- 239000004519 grease Substances 0.000 abstract 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 abstract 2
- -1 polyethylene Polymers 0.000 abstract 2
- 230000006641 stabilisation Effects 0.000 abstract 2
- LNEGIZDEHYCVMR-UHFFFAOYSA-N 2,4-dimethyl-6-[1,5,5-tris(2-hydroxy-3,5-dimethylphenyl)pentyl]phenol Chemical compound CC1=CC(C)=C(O)C(C(CCCC(C=2C(=C(C)C=C(C)C=2)O)C=2C(=C(C)C=C(C)C=2)O)C=2C(=C(C)C=C(C)C=2)O)=C1 LNEGIZDEHYCVMR-UHFFFAOYSA-N 0.000 abstract 1
- WNIAXWJGMRGLTL-UHFFFAOYSA-N 2,6-dimethyl-4-[1,3,3-tris(4-hydroxy-3,5-dimethylphenyl)propyl]phenol Chemical compound CC1=C(O)C(C)=CC(C(CC(C=2C=C(C)C(O)=C(C)C=2)C=2C=C(C)C(O)=C(C)C=2)C=2C=C(C)C(O)=C(C)C=2)=C1 WNIAXWJGMRGLTL-UHFFFAOYSA-N 0.000 abstract 1
- FSPCDXLAFOGOQG-UHFFFAOYSA-N 2,6-dimethyl-4-[2,4,4-tris(4-hydroxy-3,5-dimethylphenyl)pentan-2-yl]phenol Chemical compound CC1=C(O)C(C)=CC(C(C)(CC(C)(C=2C=C(C)C(O)=C(C)C=2)C=2C=C(C)C(O)=C(C)C=2)C=2C=C(C)C(O)=C(C)C=2)=C1 FSPCDXLAFOGOQG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 1
- 125000005594 diketone group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229920005615 natural polymer Polymers 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- 229920001059 synthetic polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
- C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Lubricants (AREA)
Abstract
A composition comprises an organic material susceptible to oxidative deterioration in the presence of molecular oxygen, e.g. an oil, fat, wax or grease, and a minor proportion of a tetranuclear phenol of the formula <FORM:0883033/III/1> where the groups R1 and R2 are alkyl groups, the groups R3 are alkyl groups or hydrogen atoms and n is a number from 1 to 6. The Provisional Specification refers to compounds of the general formula where R1, R2 and R3 may represent hydrogen atoms.ALSO:A composition comprises an organic material susceptible to oxidative deterioration in the presence of molecular oxygen, e.g. a natural polymer such as rubber or a synthetic polymer such as a polyolefin, and a minor proportion of a tetranuclear phenol of the formula <FORM:0883033/IV (a)/1> where the groups R1 and R2 are alkyl groups, the groups R3 are alkyl groups or hydrogen atoms and n is a number from 1 to 6. An example describes the stabilization of linear polyethylene. The Provisional Specification refers to compounds of the general formula where R1, R2 and R3 may represent hydrogen atoms.ALSO:A composition comprises an organic material susceptible to oxidative deterioration in the presence of molecular oxygen and a minor proportion of a tetranuclear phenol of the formula <FORM:0883033/IV (b)/1> where the groups R1 and R2 are alkyl groups, the groups R3 are alkyl groups or hydrogen atoms and n is a number from 1 to 6. The organic material may be for example, a hydrocarbon, a polymer, a polymerisable composition, a plasticiser, or an oil, fat, wax or grease. An example describes the stabilisation of n-hexadecane. The invention also includes the compounds 1,1,5,5 - tetrakis - (2 - hydroxy - 3,5 - dimethylphenyl) pentane, 1,1,3,3-tetrakis (4- hydroxy - 3,5 - dimethylphenyl) propane and 2,2,4,4 - tetrakis - (4 - hydroxy - 3,5 - dimethyl - phenyl) pentane which may be prepared by reacting the phenol with the appropriate diketone or dialdehyde acetal. The Provisional Specification refers to compounds of the general formula where R1, R2 and R3 may represent hydrogen atoms.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1048559A GB883033A (en) | 1959-03-26 | 1959-03-26 | Phenolic antioxidants |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1048559A GB883033A (en) | 1959-03-26 | 1959-03-26 | Phenolic antioxidants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB883033A true GB883033A (en) | 1961-11-22 |
Family
ID=9968710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1048559A Expired GB883033A (en) | 1959-03-26 | 1959-03-26 | Phenolic antioxidants |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB883033A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4474999A (en) * | 1982-03-19 | 1984-10-02 | General Electric Company | Phenol compounds, process and polymers |
| EP0186893A3 (en) * | 1985-01-02 | 1988-04-20 | General Electric Company | Cross-linked polycarbonate resin additives |
| US5012016A (en) * | 1990-03-20 | 1991-04-30 | Shell Oil Company | Process for preparing tetraphenolic compounds |
-
1959
- 1959-03-26 GB GB1048559A patent/GB883033A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4474999A (en) * | 1982-03-19 | 1984-10-02 | General Electric Company | Phenol compounds, process and polymers |
| EP0186893A3 (en) * | 1985-01-02 | 1988-04-20 | General Electric Company | Cross-linked polycarbonate resin additives |
| US5012016A (en) * | 1990-03-20 | 1991-04-30 | Shell Oil Company | Process for preparing tetraphenolic compounds |
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