GB876588A - Carbamic acid esters and means for producing the same - Google Patents
Carbamic acid esters and means for producing the sameInfo
- Publication number
- GB876588A GB876588A GB1981360A GB1981360A GB876588A GB 876588 A GB876588 A GB 876588A GB 1981360 A GB1981360 A GB 1981360A GB 1981360 A GB1981360 A GB 1981360A GB 876588 A GB876588 A GB 876588A
- Authority
- GB
- United Kingdom
- Prior art keywords
- trichloromethyl
- pent
- acid esters
- carbamic acid
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229940112021 centrally acting muscle relaxants carbamic acid ester Drugs 0.000 title abstract 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 title abstract 2
- ZJYIVQQAVUHTJE-UHFFFAOYSA-N 1,1,1-trichlorobutan-2-one Chemical compound CCC(=O)C(Cl)(Cl)Cl ZJYIVQQAVUHTJE-UHFFFAOYSA-N 0.000 abstract 2
- KZVCZBYBJXVTHA-UHFFFAOYSA-N 3-(trichloromethyl)pent-1-yn-3-ol Chemical compound ClC(C(CC)(C#C)O)(Cl)Cl KZVCZBYBJXVTHA-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- AHSOPEZLLQKEHV-UHFFFAOYSA-N 1,1,1,16-tetrachlorohexadecane Chemical compound ClCCCCCCCCCCCCCCCC(Cl)(Cl)Cl AHSOPEZLLQKEHV-UHFFFAOYSA-N 0.000 abstract 1
- HSSCBKMQOAEQDK-UHFFFAOYSA-N 1,1,1-trichloro-2-methylpent-4-yn-2-ol Chemical compound ClC(C(C)(CC#C)O)(Cl)Cl HSSCBKMQOAEQDK-UHFFFAOYSA-N 0.000 abstract 1
- IUOCVKFNJMAETJ-UHFFFAOYSA-N 3-(trichloromethyl)pent-1-yn-1-ol Chemical compound ClC(Cl)(Cl)C(C#CO)CC IUOCVKFNJMAETJ-UHFFFAOYSA-N 0.000 abstract 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
- -1 alkali metal amide Chemical class 0.000 abstract 1
- 229910000102 alkali metal hydride Inorganic materials 0.000 abstract 1
- 150000008046 alkali metal hydrides Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- FZFAMSAMCHXGEF-UHFFFAOYSA-N chloro formate Chemical compound ClOC=O FZFAMSAMCHXGEF-UHFFFAOYSA-N 0.000 abstract 1
- 239000005554 hypnotics and sedatives Substances 0.000 abstract 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 abstract 1
- LROBJRRFCPYLIT-UHFFFAOYSA-M magnesium;ethyne;bromide Chemical compound [Mg+2].[Br-].[C-]#C LROBJRRFCPYLIT-UHFFFAOYSA-M 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises carbamic acid esters of 2-trichloromethyl-pent-4-yn-2-ol and 3-trichloromethyl-pent-4-yn-3-ol and the preparation thereof by reacting the appropriate trichloromethyl-pentynol with an alkali metal, an alkali metal amide, an alkali metal hydride or an alkaline-earth metal hydride and treating the resulting metal salt successively with phosgene, to provide the corresponding chloroformate, and ammonia. The products are sedatives and hypnotics. 3-Trichloromethyl-pent-4-yn-3-ol is prepared by reacting 1,1,1-trichlorobutan-2-one with ethynyl magnesium bromide. 1,1,1-Trichlorobutan-2-one is prepared by reacting ethyl magnesium bromide and trichlorocetyl chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1981360A GB876588A (en) | 1960-06-03 | 1960-06-03 | Carbamic acid esters and means for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1981360A GB876588A (en) | 1960-06-03 | 1960-06-03 | Carbamic acid esters and means for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB876588A true GB876588A (en) | 1961-09-06 |
Family
ID=10135661
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1981360A Expired GB876588A (en) | 1960-06-03 | 1960-06-03 | Carbamic acid esters and means for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB876588A (en) |
-
1960
- 1960-06-03 GB GB1981360A patent/GB876588A/en not_active Expired
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