GB875393A - Process for the production of hydrocyanic acid - Google Patents
Process for the production of hydrocyanic acidInfo
- Publication number
- GB875393A GB875393A GB23152/58A GB2315258A GB875393A GB 875393 A GB875393 A GB 875393A GB 23152/58 A GB23152/58 A GB 23152/58A GB 2315258 A GB2315258 A GB 2315258A GB 875393 A GB875393 A GB 875393A
- Authority
- GB
- United Kingdom
- Prior art keywords
- platinum
- catalyst
- total
- nickel
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0229—Preparation in gaseous phase from hydrocarbons and ammonia in the absence of oxygen, e.g. HMA-process
- C01C3/0233—Preparation in gaseous phase from hydrocarbons and ammonia in the absence of oxygen, e.g. HMA-process making use of fluidised beds, e.g. the Shawinigan-process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
Hydrogen cyanide is produced by the interaction of a hydrocarbon, e.g. methane, and ammonia in the presence of a catalyst comprising (a) up to 5% by weight of the total catalyst of one or more of the platinum metals platinum, palladium, iridium, and rhodium, (b) one or more of the elements copper, nickel, aluminium, and silicon in a total amount of up to 100% atom based on the total platinum metal content, and (c) an oxygen, nitrogen, and/or carbon compound of magnesium, calcium, strontium, barium, boron, aluminium, or silicon. The catalyst may be in the form of fine or coarse granules or small rods, and may be employed in a fluidized bed or in a bed moving countercurrently to the interacting gases. According to the example, a catalyst prepared by precipitating alumina from a solution of aluminium sulphate containing platinum and nickel sulphate, the total metal content being 5% and the atomic ratio of platinum to nickel being 4 to 1, was employed at 1150 DEG C. and a throughput of 1 mol. of ammonia and 1 mol. of methane per hour.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE875393X | 1957-07-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB875393A true GB875393A (en) | 1961-08-16 |
Family
ID=6817268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23152/58A Expired GB875393A (en) | 1957-07-20 | 1958-07-18 | Process for the production of hydrocyanic acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB875393A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3723535A1 (en) * | 1987-07-16 | 1989-01-26 | Degussa | METHOD FOR PRODUCING CYAN HYDROGEN |
EP0803470A1 (en) * | 1996-04-27 | 1997-10-29 | Degussa Aktiengesellschaft | Process for the preparation of catalytically active coatings for the synthesis of hydrogen cyanide |
-
1958
- 1958-07-18 GB GB23152/58A patent/GB875393A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3723535A1 (en) * | 1987-07-16 | 1989-01-26 | Degussa | METHOD FOR PRODUCING CYAN HYDROGEN |
US4961914A (en) * | 1987-07-16 | 1990-10-09 | Degussa Aktiengesellschaft | Method of preparing hydrogen cyanide |
EP0803470A1 (en) * | 1996-04-27 | 1997-10-29 | Degussa Aktiengesellschaft | Process for the preparation of catalytically active coatings for the synthesis of hydrogen cyanide |
US5928984A (en) * | 1996-04-27 | 1999-07-27 | Degussa Aktiengesellschaft | Process for preparing catalytically active coatings for the synthesis of hydrogen cyanide |
US6048512A (en) * | 1996-04-27 | 2000-04-11 | Degussa Aktiengesellschaft | Process for preparing catalytically active coatings for the synthesis of hydrogen cyanide |
AU720260B2 (en) * | 1996-04-27 | 2000-05-25 | Degussa A.G. | Process for preparing catalytically active coatings for the synthesis of hydrogen cyanide |
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