GB867139A - Improvements in the production of polyolefins - Google Patents
Improvements in the production of polyolefinsInfo
- Publication number
- GB867139A GB867139A GB617660A GB617660A GB867139A GB 867139 A GB867139 A GB 867139A GB 617660 A GB617660 A GB 617660A GB 617660 A GB617660 A GB 617660A GB 867139 A GB867139 A GB 867139A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amine
- polyolefins
- production
- collidine
- acetylacetone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Propylene is polymerized in the presence of a catalyst containing an amine and the reaction product of titanium trichloride and an aluminium trialkyl. The amine may be an alkylamine, or a tert, aromatic or heterocyclic base. The polymerization is preferably effected in an inert solvent or diluent such as pentane, hexane, cyclohexane, heptane or octane. The Specification contains a list of suitable amines of which triethylamine, n-butyl amine, N-dimethyl aniline, pyridine, and gamma collidine are preferred. The polypropylene may be purified by treatment with isopropanol containing 10% hydrogen chloride and 0,01% acetylacetone. Specification 828,791 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB617660A GB867139A (en) | 1960-02-22 | 1960-02-22 | Improvements in the production of polyolefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB617660A GB867139A (en) | 1960-02-22 | 1960-02-22 | Improvements in the production of polyolefins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB867139A true GB867139A (en) | 1961-05-03 |
Family
ID=9809799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB617660A Expired GB867139A (en) | 1960-02-22 | 1960-02-22 | Improvements in the production of polyolefins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB867139A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3281401A (en) * | 1963-07-17 | 1966-10-25 | Phillips Petroleum Co | Polymerization utilizing a tertiary amine adjuvant |
US4072809A (en) | 1974-01-18 | 1978-02-07 | Standard Oil Company (Indiana) | Catalyst and process for the polymerization of alpha-olefins |
US4156063A (en) | 1971-06-25 | 1979-05-22 | Montecanti Edison, S.p.A. | Process for the stereoregular polymerization of alpha olefins |
US4317898A (en) * | 1972-01-31 | 1982-03-02 | Standard Oil Company (Indiana) | Catalyst and process for the polymerization of olefins |
-
1960
- 1960-02-22 GB GB617660A patent/GB867139A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3281401A (en) * | 1963-07-17 | 1966-10-25 | Phillips Petroleum Co | Polymerization utilizing a tertiary amine adjuvant |
US4156063A (en) | 1971-06-25 | 1979-05-22 | Montecanti Edison, S.p.A. | Process for the stereoregular polymerization of alpha olefins |
US4317898A (en) * | 1972-01-31 | 1982-03-02 | Standard Oil Company (Indiana) | Catalyst and process for the polymerization of olefins |
US4072809A (en) | 1974-01-18 | 1978-02-07 | Standard Oil Company (Indiana) | Catalyst and process for the polymerization of alpha-olefins |
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