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GB867139A - Improvements in the production of polyolefins - Google Patents

Improvements in the production of polyolefins

Info

Publication number
GB867139A
GB867139A GB617660A GB617660A GB867139A GB 867139 A GB867139 A GB 867139A GB 617660 A GB617660 A GB 617660A GB 617660 A GB617660 A GB 617660A GB 867139 A GB867139 A GB 867139A
Authority
GB
United Kingdom
Prior art keywords
amine
polyolefins
production
collidine
acetylacetone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB617660A
Inventor
Donald Francis Hoeg
Samuel Liebman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co filed Critical WR Grace and Co
Priority to GB617660A priority Critical patent/GB867139A/en
Publication of GB867139A publication Critical patent/GB867139A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Propylene is polymerized in the presence of a catalyst containing an amine and the reaction product of titanium trichloride and an aluminium trialkyl. The amine may be an alkylamine, or a tert, aromatic or heterocyclic base. The polymerization is preferably effected in an inert solvent or diluent such as pentane, hexane, cyclohexane, heptane or octane. The Specification contains a list of suitable amines of which triethylamine, n-butyl amine, N-dimethyl aniline, pyridine, and gamma collidine are preferred. The polypropylene may be purified by treatment with isopropanol containing 10% hydrogen chloride and 0,01% acetylacetone. Specification 828,791 is referred to.
GB617660A 1960-02-22 1960-02-22 Improvements in the production of polyolefins Expired GB867139A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB617660A GB867139A (en) 1960-02-22 1960-02-22 Improvements in the production of polyolefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB617660A GB867139A (en) 1960-02-22 1960-02-22 Improvements in the production of polyolefins

Publications (1)

Publication Number Publication Date
GB867139A true GB867139A (en) 1961-05-03

Family

ID=9809799

Family Applications (1)

Application Number Title Priority Date Filing Date
GB617660A Expired GB867139A (en) 1960-02-22 1960-02-22 Improvements in the production of polyolefins

Country Status (1)

Country Link
GB (1) GB867139A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281401A (en) * 1963-07-17 1966-10-25 Phillips Petroleum Co Polymerization utilizing a tertiary amine adjuvant
US4072809A (en) 1974-01-18 1978-02-07 Standard Oil Company (Indiana) Catalyst and process for the polymerization of alpha-olefins
US4156063A (en) 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
US4317898A (en) * 1972-01-31 1982-03-02 Standard Oil Company (Indiana) Catalyst and process for the polymerization of olefins

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281401A (en) * 1963-07-17 1966-10-25 Phillips Petroleum Co Polymerization utilizing a tertiary amine adjuvant
US4156063A (en) 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
US4317898A (en) * 1972-01-31 1982-03-02 Standard Oil Company (Indiana) Catalyst and process for the polymerization of olefins
US4072809A (en) 1974-01-18 1978-02-07 Standard Oil Company (Indiana) Catalyst and process for the polymerization of alpha-olefins

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