GB861833A - Process for the manufacture of ferrocene derivatives - Google Patents
Process for the manufacture of ferrocene derivativesInfo
- Publication number
- GB861833A GB861833A GB17359A GB17359A GB861833A GB 861833 A GB861833 A GB 861833A GB 17359 A GB17359 A GB 17359A GB 17359 A GB17359 A GB 17359A GB 861833 A GB861833 A GB 861833A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pivalyl
- halide
- manufacture
- ferrocene derivatives
- iron compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical class [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- -1 pivalyl halide Chemical class 0.000 abstract 3
- 150000002506 iron compounds Chemical class 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 abstract 1
- WGHHJNOAZJLVCU-UHFFFAOYSA-L 2,2-dimethylpropanoate iron(2+) Chemical compound C(C(C)(C)C)(=O)[O-].[Fe+2].C(C(C)(C)C)(=O)[O-] WGHHJNOAZJLVCU-UHFFFAOYSA-L 0.000 abstract 1
- JVSFQJZRHXAUGT-UHFFFAOYSA-N 2,2-dimethylpropanoyl chloride Chemical group CC(C)(C)C(Cl)=O JVSFQJZRHXAUGT-UHFFFAOYSA-N 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Mono- and di-pivalyl ferrocenes are made by heating ferrocene with a pivalyl halide, optionally in the presence of an iron compound other than anhydrous ferric chloride as a catalyst. A suitable pivalyl halide is pivalyl chloride. The iron compound should be soluble in organic solvents and may be iron pivalate. The reaction is preferably carried out between 70 DEG and 180 DEG C. using as solvent ethylene dichloride, di-n-butyl ether or excess of the pivalyl halide used as a reactant. Specification 819,108 is re-ferred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB17359A GB861833A (en) | 1959-01-02 | 1959-01-02 | Process for the manufacture of ferrocene derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB17359A GB861833A (en) | 1959-01-02 | 1959-01-02 | Process for the manufacture of ferrocene derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB861833A true GB861833A (en) | 1961-03-01 |
Family
ID=9699701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17359A Expired GB861833A (en) | 1959-01-02 | 1959-01-02 | Process for the manufacture of ferrocene derivatives |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB861833A (en) |
-
1959
- 1959-01-02 GB GB17359A patent/GB861833A/en not_active Expired
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