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GB854095A - Method of electrodialyzing aqueous solutions - Google Patents

Method of electrodialyzing aqueous solutions

Info

Publication number
GB854095A
GB854095A GB4064258A GB4064258A GB854095A GB 854095 A GB854095 A GB 854095A GB 4064258 A GB4064258 A GB 4064258A GB 4064258 A GB4064258 A GB 4064258A GB 854095 A GB854095 A GB 854095A
Authority
GB
United Kingdom
Prior art keywords
chambers
concentrating
liquids
diluting
current
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4064258A
Inventor
Walter Juda
Wayne A Mcrae
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Veolia WTS Systems USA Inc
Original Assignee
Ionics Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ionics Inc filed Critical Ionics Inc
Priority to GB4064258A priority Critical patent/GB854095A/en
Publication of GB854095A publication Critical patent/GB854095A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44Ion-selective electrodialysis
    • B01D61/52Accessories; Auxiliary operation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4604Treatment of water, waste water, or sewage by electrochemical methods for desalination of seawater or brackish water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4611Fluid flow
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46115Electrolytic cell with membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • C02F2201/46125Electrical variables
    • C02F2201/4613Inversing polarity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Urology & Nephrology (AREA)
  • Analytical Chemistry (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

854,095. Electro-dialysis of aqueous liquids. IONICS Inc. Dec. 17, 1958, No. 40642/58. Class 41 In the electro-dialysis of liquids the liquid is passed through a series of diluting chambers alternating with concentrating chambers provided with cationic and anionic permselective membranes, the end chambers of each series only being provided with electrodes, the current is periodically reversed, and the flow of diluting and concentrating liquids interchanged, whereby the membranes are prevented from fouling and clogging particularly the anionic membrane. Brackish waters, sea water, and sugar solutions and similar liquids containing relatively minor amounts of electrolytes, are treated. A suitable apparatus comprises a dimineratiser unit 20 Fig. 2 comprising a stack of chambers bounded by anion permeable membranes A and cation membranes C, with electrode chambers E 1 E 2 at each end. The anode and cathode feeds (which may be tap water or a suitable electrolyte) concentrating and feed liquids and the effluents, are fed through valves Va...Vh to pumps P1...P4, tanks T1...T4, through switch valves V 1 ...V 16 connected to the stack of chambers. Each tank has two pairs of valves. As shown, chambers 1 are diluting, 2 are concentrating, chambers 3 and 4 contain anolyte and catholyte. On reversing the switches S1...S4, the concentrating and diluting chambers are interchanged, by reversing the flow of liquids, and similarly the anode chamber becomes the cathode. In examples using 150 diluting and concentrating chambers, the salinity of sea water was reduced from 35,000 ppm. to 500 ppm with an output of 1000 gals. per day. After 3 weeks the current had fallen from 30 amps to 15 amps; and output fell to 500 gals. per day when current and liquid flows were reversed the original rates were restored. In the treatment of sugar or molasses solution a little acid is added to adjust pH value to 3À5, and dilute salt solution is used as concentrating liquid. Reversal of current and liquid flow is effected at periods of 12 to 24 hours. Specifications 720,002, 772,862, 821,229 and U.S.A. Specification 2,848,403 are referred to.
GB4064258A 1958-12-17 1958-12-17 Method of electrodialyzing aqueous solutions Expired GB854095A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB4064258A GB854095A (en) 1958-12-17 1958-12-17 Method of electrodialyzing aqueous solutions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4064258A GB854095A (en) 1958-12-17 1958-12-17 Method of electrodialyzing aqueous solutions

Publications (1)

Publication Number Publication Date
GB854095A true GB854095A (en) 1960-11-16

Family

ID=10415907

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4064258A Expired GB854095A (en) 1958-12-17 1958-12-17 Method of electrodialyzing aqueous solutions

Country Status (1)

Country Link
GB (1) GB854095A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988007406A1 (en) * 1987-04-03 1988-10-06 Gradient Pty. Ltd. Improvements relating to separation of charged molecules
EP1044717A2 (en) * 1994-05-20 2000-10-18 US Filter/ Ionpure, Inc Polarity reversal and double reversal electrodeionization apparatus and method
WO2016133396A1 (en) * 2015-02-20 2016-08-25 Redstack B.V. Method for fouling reduction in membrane based fluid-flow processes, and device capable of performing such method
CN110436586A (en) * 2019-08-09 2019-11-12 南开大学 A kind of process units and method of high purity water

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988007406A1 (en) * 1987-04-03 1988-10-06 Gradient Pty. Ltd. Improvements relating to separation of charged molecules
AU601040B2 (en) * 1987-04-03 1990-08-30 Life Therapeutics Limited Improvements relating to separation of charged molecules
US5039386A (en) * 1987-04-03 1991-08-13 Gradient Pty. Electrophoretic method for preparative separation of charged molecules in liquids
EP1044717A2 (en) * 1994-05-20 2000-10-18 US Filter/ Ionpure, Inc Polarity reversal and double reversal electrodeionization apparatus and method
EP1044717A3 (en) * 1994-05-20 2001-03-07 US Filter/ Ionpure, Inc Polarity reversal and double reversal electrodeionization apparatus and method
WO2016133396A1 (en) * 2015-02-20 2016-08-25 Redstack B.V. Method for fouling reduction in membrane based fluid-flow processes, and device capable of performing such method
NL2014329B1 (en) * 2015-02-20 2016-10-13 Redstack Bv Method for fouling reduction in membrane based fluid-flow processes, and device capable of performing such method.
CN110436586A (en) * 2019-08-09 2019-11-12 南开大学 A kind of process units and method of high purity water

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