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GB845897A - Improvements in or relating to the production of coated articles - Google Patents

Improvements in or relating to the production of coated articles

Info

Publication number
GB845897A
GB845897A GB751457A GB751457A GB845897A GB 845897 A GB845897 A GB 845897A GB 751457 A GB751457 A GB 751457A GB 751457 A GB751457 A GB 751457A GB 845897 A GB845897 A GB 845897A
Authority
GB
United Kingdom
Prior art keywords
nylon
rays
irradiated
methylene blue
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB751457A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB845897A publication Critical patent/GB845897A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/18—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to irradiated or oxidised macromolecules
    • C08F291/185—The monomer(s) not being present during the irradiation or the oxidation of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/313—Unsaturated compounds containing phosphorus atoms, e.g. vinylphosphonium compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)
  • Paints Or Removers (AREA)

Abstract

A shaped structure comprising an organic polymeric material is modified by subjecting it to ionizing electromagnetic radiation, particularly X-rays or g -rays, the structure, after having been irradiated, being contacted with one or more unsaturated organic compounds which are capable of homopolymerization, the temperature of the structure during irradiation and up until the time of contacting with the unsaturated compound being maintained below room temperature, preferably below 0 DEG C. The polymeric material may be polyethylene, polystyrene, polybutadiene, rubber, polyisobutylene, a butadiene-styrene copolymer, polyvinyl chloride, polyvinylidene chloride, polychloroprene, poly-tetrafluoroethylene, polyvinyl fluoride, polyvinyl acetate, polymethyl methacrylate, polyethylene terephthalate, polyvinyl alcohol, cellulose, regenerated cellulose, polytetrahydrofuran, polyformaldehyde, a dioxolane polymer, a phenolurea- or triazine-formaldehyde polymer, a polyamide, a polyimide, polyacrylonitrile, cotton, wool or silk. The unsaturated compound may be styrene, acrylic acid or a derivative thereof, itaconic acid, vinyl chloride, vinylidene chloride, vinyl acetate, a vinyl ketone or ether, divinyl ether, acrylonitrile, methacrylonitrile, 1:3-butadiene, isoprene, chloroprene, 2:3-dimethyl-1:3- butadiene, phenyl acetylene, ethylene, propylene, an allyl ester, a halogen-, sulphur-, nitrogen- or phosphorus-containing vinyl compound or a vinyl silane. Non-polymerizing compounds may be reacted simultaneously, e.g. methylene blue may be attached to irradiated nylon by reacting nylon with potassium acrylate in a solution in which methylene blue has been dissolved. An example describes the X-ray irradiation at low temperature of nylon, wool and silk fabrics followed by treatment with sodium styrene sulphonate, the resulting fabric having improved antistatic properties. Specifications 820,120, 834,557, 838,412, and 845,898 are referred to.ALSO:A shaped structure comprising an organic polymeric material is modified by subjecting it to ionizing electromagnetic radiation, particularly X-rays or Y-rays, the structure, after having been irradiated, being contacted with one or more unsaturated organic compounds which are capable of homopolymerization, the temperature of the structure during irradiation and up until the time of contacting with the unsaturated compound being maintained below room temperature, preferably below 0 DEG C. (see Group IV(a)) for lists of suitable polymers and monomers). Non-polymerizing compounds may be reacted simultaneously, e.g. methylene blue may be attached to irradiated nylon by reacting nylon with potassium acrylate in a solution in which methylene blue has been dissolved. An example describes the X-ray irradiation at low temperature of nylon, wool and silk fabrics followed by treatment with sodium styrene sulphonate, the resulting fabric having improved antistatic properties. Specifications 820,120, 834,557, 838,412, and 845,898 are referred to.
GB751457A 1956-03-08 1957-03-06 Improvements in or relating to the production of coated articles Expired GB845897A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57038856A 1956-03-08 1956-03-08

Publications (1)

Publication Number Publication Date
GB845897A true GB845897A (en) 1960-08-24

Family

ID=24279453

Family Applications (2)

Application Number Title Priority Date Filing Date
GB751457A Expired GB845897A (en) 1956-03-08 1957-03-06 Improvements in or relating to the production of coated articles
GB1160259A Expired GB845898A (en) 1956-03-08 1957-03-06 Improvements in or relating to the production of coated articles

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1160259A Expired GB845898A (en) 1956-03-08 1957-03-06 Improvements in or relating to the production of coated articles

Country Status (5)

Country Link
CH (1) CH380373A (en)
DE (1) DE1494238A1 (en)
FR (1) FR1169204A (en)
GB (2) GB845897A (en)
NL (1) NL215212A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1005984B (en) * 1954-12-13 1957-04-11 Taylorix Organisation Stiegler Use of a colored sheet in plug-in devices for loose accounting forms on typewriters and accounting machines
US3274091A (en) * 1962-09-18 1966-09-20 Du Pont Method of producing non-fogging films
US3274090A (en) * 1962-09-18 1966-09-20 Du Pont Method of producing non-fogging films
US3275540A (en) * 1963-10-01 1966-09-27 Du Pont Surface treatment of shaped organic polymeric structures
US3291712A (en) * 1963-10-01 1966-12-13 Du Pont Surface treatment of shaped organic polymeric structures
US3478886A (en) * 1967-03-31 1969-11-18 Atomic Energy Commission Graft-copolymer column support material for liquid-liquid partition chromatography
CN105821667A (en) * 2016-03-22 2016-08-03 李晨露 Paint for improving anti-electromagnetic radiation performance of textile and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB960192A (en) * 1961-04-20 1964-06-10 Atomic Energy Commission Vapor phase coating of textile fibers using ionizing radiation and resultant products
US4225403A (en) * 1979-02-21 1980-09-30 Mobil Oil Corporation Process for improving films of poly(p-methylstyrene) and copolymers thereof by high energy radiation treatments
DE3643574A1 (en) * 1986-12-19 1988-06-30 Hartmut Ernst Artur Brueschke POLYMER WITH BETAIN STRUCTURE, SOLUTION DIFFUSION MEMBRANE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1005984B (en) * 1954-12-13 1957-04-11 Taylorix Organisation Stiegler Use of a colored sheet in plug-in devices for loose accounting forms on typewriters and accounting machines
US3274091A (en) * 1962-09-18 1966-09-20 Du Pont Method of producing non-fogging films
US3274090A (en) * 1962-09-18 1966-09-20 Du Pont Method of producing non-fogging films
US3275540A (en) * 1963-10-01 1966-09-27 Du Pont Surface treatment of shaped organic polymeric structures
US3291712A (en) * 1963-10-01 1966-12-13 Du Pont Surface treatment of shaped organic polymeric structures
US3478886A (en) * 1967-03-31 1969-11-18 Atomic Energy Commission Graft-copolymer column support material for liquid-liquid partition chromatography
CN105821667A (en) * 2016-03-22 2016-08-03 李晨露 Paint for improving anti-electromagnetic radiation performance of textile and preparation method thereof

Also Published As

Publication number Publication date
NL215212A (en)
FR1169204A (en) 1958-12-24
CH380373A (en) 1964-07-31
GB845898A (en) 1960-08-24
DE1494238A1 (en) 1969-02-13

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