GB843170A - Polymerisation process - Google Patents
Polymerisation processInfo
- Publication number
- GB843170A GB843170A GB9933/59A GB993359A GB843170A GB 843170 A GB843170 A GB 843170A GB 9933/59 A GB9933/59 A GB 9933/59A GB 993359 A GB993359 A GB 993359A GB 843170 A GB843170 A GB 843170A
- Authority
- GB
- United Kingdom
- Prior art keywords
- antimony
- trialkyl
- polymerization
- silver salt
- effected
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Vinyl chloride is polymerised by means of a catalyst comprising a silver salt (e.g. AgNO3) and an antimony trialkyl (e.g. tri-n-propyl). The polymerization may be effected in bulk, or a inert organic or aqueous media; in the example, methanol is present. Preferred features are:-(a) the catalyst mixture is 0,5-3% wt. of monomer; (b) the silver salt is 25-50% wt. of the antimony trialkyl; (c) polymerization is effected at below room temperature and at atmospheric pressure.ALSO:A vinyl chloride polymerization catalyst comprises a silver salt and an antimony trialkyl, optionally in inert organic or aqueous media; the example specifies silver nitrate and antimony tri-n-propyl, methanol being present.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE566533A BE566533A (en) | 1958-04-05 | 1958-04-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB843170A true GB843170A (en) | 1960-08-04 |
Family
ID=3881976
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9933/59A Expired GB843170A (en) | 1958-04-05 | 1959-03-23 | Polymerisation process |
Country Status (4)
Country | Link |
---|---|
BE (2) | BE566536A (en) |
DE (1) | DE1126138B (en) |
FR (1) | FR1230632A (en) |
GB (1) | GB843170A (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE554743A (en) * | 1954-09-01 | |||
BE545968A (en) * | 1956-03-10 |
-
1958
- 1958-04-05 BE BE566536A patent/BE566536A/fr unknown
- 1958-04-05 BE BE566533A patent/BE566533A/fr unknown
-
1959
- 1959-03-17 DE DES62183A patent/DE1126138B/en active Pending
- 1959-03-23 GB GB9933/59A patent/GB843170A/en not_active Expired
- 1959-04-03 FR FR791184A patent/FR1230632A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1230632A (en) | 1960-09-19 |
DE1126138B (en) | 1962-03-22 |
BE566536A (en) | 1958-10-06 |
BE566533A (en) | 1958-10-06 |
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