GB839483A - Improvements in or relating to the coating of organic polymer substrates - Google Patents
Improvements in or relating to the coating of organic polymer substratesInfo
- Publication number
- GB839483A GB839483A GB1617157A GB1617157A GB839483A GB 839483 A GB839483 A GB 839483A GB 1617157 A GB1617157 A GB 1617157A GB 1617157 A GB1617157 A GB 1617157A GB 839483 A GB839483 A GB 839483A
- Authority
- GB
- United Kingdom
- Prior art keywords
- coating
- substrate
- irradiated
- room temperature
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title abstract 19
- 239000011248 coating agent Substances 0.000 title abstract 16
- 239000000758 substrate Substances 0.000 title abstract 13
- 229920000620 organic polymer Polymers 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- 230000000694 effects Effects 0.000 abstract 6
- 239000004744 fabric Substances 0.000 abstract 6
- 239000000463 material Substances 0.000 abstract 5
- -1 polyethylene Polymers 0.000 abstract 5
- 230000005855 radiation Effects 0.000 abstract 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 4
- 239000004698 Polyethylene Substances 0.000 abstract 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 4
- 229920000573 polyethylene Polymers 0.000 abstract 4
- 239000004627 regenerated cellulose Substances 0.000 abstract 4
- 239000000126 substance Substances 0.000 abstract 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 4
- 239000004677 Nylon Substances 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 238000004040 coloring Methods 0.000 abstract 3
- 230000002209 hydrophobic effect Effects 0.000 abstract 3
- 230000001678 irradiating effect Effects 0.000 abstract 3
- 229920001778 nylon Polymers 0.000 abstract 3
- 239000011368 organic material Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 239000002245 particle Substances 0.000 abstract 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 235000021314 Palmitic acid Nutrition 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 230000005660 hydrophilic surface Effects 0.000 abstract 2
- 230000014759 maintenance of location Effects 0.000 abstract 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract 2
- 229920005615 natural polymer Polymers 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000005033 polyvinylidene chloride Substances 0.000 abstract 2
- 150000003333 secondary alcohols Chemical class 0.000 abstract 2
- 229920001059 synthetic polymer Polymers 0.000 abstract 2
- 150000003573 thiols Chemical class 0.000 abstract 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 abstract 2
- 238000004078 waterproofing Methods 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000001680 brushing effect Effects 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 239000003925 fat Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 102000004169 proteins and genes Human genes 0.000 abstract 1
- 108090000623 proteins and genes Proteins 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/14—Surface shaping of articles, e.g. embossing; Apparatus therefor by plasma treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/068—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using ionising radiations (gamma, X, electrons)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/16—Surface shaping of articles, e.g. embossing; Apparatus therefor by wave energy or particle radiation, e.g. infrared heating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
- C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2201/00—Polymeric substrate or laminate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0866—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using particle radiation
- B29C2035/0872—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using particle radiation using ion-radiation, e.g. alpha-rays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0866—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using particle radiation
- B29C2035/0877—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using particle radiation using electron radiation, e.g. beta-rays
Landscapes
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Polymeric substrates are coated with a chemically dissimilar organic substance which becomes bonded to the substrate, by irradiating the substrate in the substantial absence of oxygen with charged particle radiation of energy between 15 and 50,000 electron volts for a minimum exposure of 0.01 watt-sec. per cm.2 and thereafter, while the effect of the irradiation is still active, contacting the substrate with the dissimilar organic material to form the coating. The dissimilar material may be a polymer, a monomer or a non-polymerizable compound, preferably chain transfer agents containing active hydrogen or halogen, e.g. chloroform, carbon tetrachloride, triphenylmethane, thiols, secondary alcohols and maleic anhydride; fats and proteins may also be used. The substrate may be of a natural or synthetic polymer. The irradiation is preferably carried out at room temperature or below and the effect may be preserved by low temperature or inert atmosphere for a considerable period before the coating step is effected. The substrate may be earthed. The coating may be applied by dipping, spraying, brushing or printing. In examples: (1) one side of an uncoated regenerated cellulose film is irradiated with 25 KeV electrons and three minutes later the film is immersed in monomeric vinylidene chloride in the dark for twenty hours at room temperature under nitrogen. The irradiated side acquires a coating of polyvinylidene chloride which is not extractable with dioxane; (2) a film of polyethylene is irradiated in a vacuum at - 78 DEG C. with 30 KeV electrons and then immersed in acrylic acid for 18 hours at room temperature, rinsed and dried. A coating of grafted acrylic acid is formed on the irradiated side which shows improved retention of printing ink. The coating of polyethylene with glycerol or polyethylene glycol to form a hydrophilic surface, or of nylon fabric with palmitic acid to form a hydrophobic coating are referred to. The invention may be used to fine sizes, finishing agents, antistatic coatings and colouring materials to fibrous organic polymers and fabrics and ship agents and waterproofing layers to regenerated cellulose film.ALSO:Fibrous natural or synthetic organic materials are chemically bonded to substances such as sizes, finishing agents, antistatic coatings and colouring materials by irradiating the fibrous material in the substantial absence of oxygen with charged particle radiation of energy between 15 and 50,000 electron volts for a minimum exposure of 0.01 watt-sec. per cm.2 and thereafter, while the effect of the radiation is still active, contacting the substrate with the substance to be bonded thereto. The irradiation is preferably carried out at room temperature or below and the effect may be preserved by low temperature or an inert atmosphere for a considerable period before the coating step is effected. The formation of a hydrophobic coating on nylon fabric by contacting the irradiated fabric with palmitic acid is referred to.ALSO:Polymeric substrates are coated with a chemically dissimilar organic substance which becomes bonded to the substrate, by irradiating the substrate in the substantial absence of oxygen with charged particle radiation of energy between 15 and 50,000 electron volts for a minimum exposure of 0.01 watt-sec. per cm2, and thereafter, while the effect of the radiation is still active, contacting the substrate with a dissimilar organic material to form the coating. The dissimilar material may be a polymer, a monomer or a non-polymerizable compound, preferably chain transfer agents containing active hydrogen or halogen, e.g. chloroform, carbon tetrachloride, triphenylmethane, thiols, secondary alcohols and maleic anhydride. The substrate may be of a natural or synthetic polymer. The irradiation is preferably carried out at room temperature or below and the effect may be preserved by low temperature or inert atmosphere for a considerable period before the coating step is effected. In examples: (1) one side of an uncoated regenerated cellulose film is irradiated with 25 Ke V electrons and three minutes later the film is immersed in monomeric vinylidene chloride in the dark for twenty hours at room temperature under nitrogen. The irradiated side acquires a coating of polyvinylidene chloride which is not extractable with dioxane; (2) a film of polyethylene is irradiated in a vacuum at - 78 DEG C. with 30 Ke V electrons and then immersed in acrylic acid for 18 hours at room temperature, rinsed and dried. A coating of grafted acrylic acid is formed on the irradiated side which shows improved retention of printing ink. The coating of polyethylene with glycerol or polyethylene glycol to form a hydrophilic surface, or of nylon fabric to form a hydrophobic coating are referred to. The invention may be used to fix sizes, finishing agents, antistatic coatings and colouring materials to fibrous organic polymers and fabrics and ship agents and waterproofing layers to regenerated cellulose film.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58937256A | 1956-06-05 | 1956-06-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB839483A true GB839483A (en) | 1960-06-29 |
Family
ID=24357736
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1617157A Expired GB839483A (en) | 1956-06-05 | 1957-05-21 | Improvements in or relating to the coating of organic polymer substrates |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE558061A (en) |
| DE (1) | DE1446785A1 (en) |
| FR (1) | FR1182284A (en) |
| GB (1) | GB839483A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2220870A (en) * | 1988-07-22 | 1990-01-24 | Taylowe Ltd | A coated substrate |
| US5382703A (en) * | 1992-11-06 | 1995-01-17 | Kimberly-Clark Corporation | Electron beam-graftable compound and product from its use |
| US6632854B1 (en) * | 1999-03-19 | 2003-10-14 | Atofina Research, S.A. | Production of polypropylene having improved properties |
| CN114984768A (en) * | 2022-06-27 | 2022-09-02 | 上海翊科聚合物科技有限公司 | Surface modification method of hollow fiber membrane for artificial membrane lung |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2597352B2 (en) * | 1985-06-20 | 1997-04-02 | インターナショナル・ビジネス・マシーンズ・コーポレーション | Method for improving adhesion between metal and organic substrate |
| DE102009036947B4 (en) | 2009-08-11 | 2018-05-03 | Leibniz-Institut für Oberflächenmodifizierung e.V. | Direct modification of polymer membranes with low molecular weight compounds and polymer membranes thus obtained and their use |
-
0
- BE BE558061D patent/BE558061A/xx unknown
-
1957
- 1957-05-14 DE DE19571446785 patent/DE1446785A1/en active Pending
- 1957-05-20 FR FR1182284D patent/FR1182284A/en not_active Expired
- 1957-05-21 GB GB1617157A patent/GB839483A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2220870A (en) * | 1988-07-22 | 1990-01-24 | Taylowe Ltd | A coated substrate |
| US5382703A (en) * | 1992-11-06 | 1995-01-17 | Kimberly-Clark Corporation | Electron beam-graftable compound and product from its use |
| US6632854B1 (en) * | 1999-03-19 | 2003-10-14 | Atofina Research, S.A. | Production of polypropylene having improved properties |
| CN114984768A (en) * | 2022-06-27 | 2022-09-02 | 上海翊科聚合物科技有限公司 | Surface modification method of hollow fiber membrane for artificial membrane lung |
Also Published As
| Publication number | Publication date |
|---|---|
| BE558061A (en) | |
| DE1446785A1 (en) | 1969-10-09 |
| FR1182284A (en) | 1959-06-24 |
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