GB835896A - New aryloxazolyl-ethylene derivatives and process for their manufacture - Google Patents
New aryloxazolyl-ethylene derivatives and process for their manufactureInfo
- Publication number
- GB835896A GB835896A GB1868556A GB1868556A GB835896A GB 835896 A GB835896 A GB 835896A GB 1868556 A GB1868556 A GB 1868556A GB 1868556 A GB1868556 A GB 1868556A GB 835896 A GB835896 A GB 835896A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aryloxazolyl
- ethylenes
- give
- ethylene derivatives
- new
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
The invention comprises new aryloxazolyl-ethylene derivatives of formula <FORM:0835896/IV (b)/1> in which R1 and R2 each represent an alkyl residue. They may be produced by heating two molecular proportions of an ortho-hydroxy-aminoaryl compound with one molecular proportion of thiomalic acid or an alkyl mono- or di-ester thereof. The reaction is advantageously carried out in the temperature range 100-200 DEG C. in an inert organic solvent such as monochlorbenzene, dichlorbenzenes, trichlorbenzenes, nitrobenzenes, toluene, xylenes or cumene. The compounds formed may be treated with agents capable of splitting off water to give di(aryloxazolyl)-ethylenes in accordance with the process described and claimed in Specification 835,897. In the examples details are given of the preparation of <FORM:0835896/IV (b)/2> <FORM:0835896/IV (b)/3> and <FORM:0835896/IV (b)/4> These compounds when heated with zinc chloride lose water to give the corresponding a ,b -di-[benzoxazolyl-(2)]-ethylenes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1868556A GB835896A (en) | 1956-06-15 | 1956-06-15 | New aryloxazolyl-ethylene derivatives and process for their manufacture |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1868556A GB835896A (en) | 1956-06-15 | 1956-06-15 | New aryloxazolyl-ethylene derivatives and process for their manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
GB835896A true GB835896A (en) | 1960-05-25 |
Family
ID=10116658
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1868556A Expired GB835896A (en) | 1956-06-15 | 1956-06-15 | New aryloxazolyl-ethylene derivatives and process for their manufacture |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB835896A (en) |
-
1956
- 1956-06-15 GB GB1868556A patent/GB835896A/en not_active Expired
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