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GB808336A - Sulfactive hydrogenation catalyst - Google Patents

Sulfactive hydrogenation catalyst

Info

Publication number
GB808336A
GB808336A GB2325957A GB2325957A GB808336A GB 808336 A GB808336 A GB 808336A GB 2325957 A GB2325957 A GB 2325957A GB 2325957 A GB2325957 A GB 2325957A GB 808336 A GB808336 A GB 808336A
Authority
GB
United Kingdom
Prior art keywords
oxide
molybdenum
hydrogenation
hydrogen
sulphide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2325957A
Inventor
Ralph Burgess Mason
Edward Wheelock Stee Nicholson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB2325957A priority Critical patent/GB808336A/en
Publication of GB808336A publication Critical patent/GB808336A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)

Abstract

Hydrogenation catalysts are prepared by at least partially reducing a higher oxide of chromium, molybdenum, tungsten, cobalt or nickel with hydrogen to a lower oxide and sulphiding the reduced oxide. The preferred starting oxide is molybdenum trioxide which may be supported on charcoal and prepared for example by heating charcoal, impregnated with an ammonium molybdate solution, to 200-350 DEG F.; this may be reduced at 300-1000 DEG F. and 200-3000 p.s.i.g. The reduced oxide can then be sulphided with gaseous hydrogen sulphide or a solution of hydrogen sulphide in an inert liquid such as varsol or virgin naphtha or with carbon disulphide. The molybdenum sulphide catalyst produced is particularly useful in the hydrogenation of aldehydes to alcohols (see Group IV (b)), and in an example the molybdenum oxide used for this purpose is compounded with oxides of zinc and magnesium.ALSO:Alcohols are produced from aldehydes formed by the carbonylation of olefines by liquid phase hydrogenation in the presence of a molybdenum sulphide catalyst supported on charcoal prepared by reducing with hydrogen preformed pellets of activated charcoal supporting a minor proportion of molybdenum trioxide to convert at least part of the oxide to an oxide in which the metal is at a lower valence state and sulphiding the hydrogenated product (see Group III). Conditions for the hydrogenation may be 2500-4500 p.s.i.g. and 400-600 DEG F. with a liquid feed rate of 0.25-2 v./v./hr. and a hydrogen feed rate of 5000-20,000 cu. ft. per barrel using a catalyst containing 1-10 per cent molybdenum sulphide based on the carrier. Up to 8-10 per cent of water may also be added to the hydrogenation zone. The reduction of C8 aldehydes is exemplified. The alcohols produced are of low sulphur content and suitable for the preparation of plasticizing agents.
GB2325957A 1957-07-23 1957-07-23 Sulfactive hydrogenation catalyst Expired GB808336A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2325957A GB808336A (en) 1957-07-23 1957-07-23 Sulfactive hydrogenation catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2325957A GB808336A (en) 1957-07-23 1957-07-23 Sulfactive hydrogenation catalyst

Publications (1)

Publication Number Publication Date
GB808336A true GB808336A (en) 1959-02-04

Family

ID=10192751

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2325957A Expired GB808336A (en) 1957-07-23 1957-07-23 Sulfactive hydrogenation catalyst

Country Status (1)

Country Link
GB (1) GB808336A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4528089A (en) * 1982-07-20 1985-07-09 Exxon Research And Engineering Co. Hydrogenation processes using carbon-containing molybdenum and tungsten sulfide catalysts
EP1219584A2 (en) * 2000-12-14 2002-07-03 Oxeno Olefinchemie GmbH Process for the hydrogenation of hydroformylation mixtures
CN112742427A (en) * 2019-10-29 2021-05-04 中国石油化工股份有限公司 Startup method of hydrogenation catalyst
CN112978798A (en) * 2021-02-02 2021-06-18 昆明理工大学 Method and device for preparing molybdenum oxide nano material with adjustable phase, shape and size

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4528089A (en) * 1982-07-20 1985-07-09 Exxon Research And Engineering Co. Hydrogenation processes using carbon-containing molybdenum and tungsten sulfide catalysts
EP1219584A2 (en) * 2000-12-14 2002-07-03 Oxeno Olefinchemie GmbH Process for the hydrogenation of hydroformylation mixtures
EP1219584A3 (en) * 2000-12-14 2003-10-29 Oxeno Olefinchemie GmbH Process for the hydrogenation of hydroformylation mixtures
US6680414B2 (en) 2000-12-14 2004-01-20 Oxeno Olefinchemie Gmbh Process for the hydrogenation of hydroformylation mixtures
CN112742427A (en) * 2019-10-29 2021-05-04 中国石油化工股份有限公司 Startup method of hydrogenation catalyst
CN112978798A (en) * 2021-02-02 2021-06-18 昆明理工大学 Method and device for preparing molybdenum oxide nano material with adjustable phase, shape and size

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