[go: up one dir, main page]

GB805527A - Improvements in or relating to coating compositions - Google Patents

Improvements in or relating to coating compositions

Info

Publication number
GB805527A
GB805527A GB6469/57A GB646957A GB805527A GB 805527 A GB805527 A GB 805527A GB 6469/57 A GB6469/57 A GB 6469/57A GB 646957 A GB646957 A GB 646957A GB 805527 A GB805527 A GB 805527A
Authority
GB
United Kingdom
Prior art keywords
ester
coating
orthozirconate
orthotitanate
beta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6469/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB805527A publication Critical patent/GB805527A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Wrappers (AREA)

Abstract

A composition comprising an oily liquid polymer of butadiene-1,3 and an orthotitanate ester or an orthozirconate ester is used for coating the interior of metal containers, e.g. of tin-plated steel, sheet steel, terne-plate and aluminium-clad steel, for food packaging. The coating may be applied by roller-coating, spraying, dipping and flow-coating. The polymer may be a homo-polymer of butadiene or a copolymer of butadiene and styrene in which the butadiene is in preponderance; it is preferably an oily liquid having a molecular weight of 700-20,000. It may also be modified by a minor proportion, e.g. up to 2 per cent by weight of maleic anhydride or citraconic anhydride. The ester used may be (1) an orthotitanate or orthozirconate ester of an aliphatic monohydric alcohol preferably of 6 to 20 carbon atoms such as 2-ethyl-hexyl alcohol; (2) an orthotitanate or orthozirconate ester of a 2,3-diorgano-substituted 1,3-diol such as 2-ethylhexane diol-1,3; these chelated derivatives are described in U.S.A. Specification 2,643,262 and may be formed in situ in the composition by introducing the titanium or zirconium derivative as the tetrabutyl ester and adding the diol; (3) an orthotitanate or orthozirconate ester of an enolixable beta-ketoacid ester, such as the C1-C6 alkyl and cyclohexyl alcohol esters of acetoacetic, beta-oxo-valeric, beta-oxo-caproic, beta-oxo-caprylic, or beta-oxo-cyclo-hexanepropionic acid; these chelates may also be similarly formed in situ; (4) an orthotitanate or orthozirconate partial ester of an aliphatic monohydric alcohol and partial acylate of a fatty oil acid, such as polymeric isopropoxytitanium oleate. These partial anhydrides-partial esters are described in U.S.A. Specifications 2,621,193, 2,621,195 and 2,666,772. The coating composition is dissolved in a volatile inert organic mutual solvent for the polymer and ester. Hydrocarbons or hydrocarbon mixtures boiling within the range of 80-220 DEG C. are preferred, such as mineral spirits. "Varnish Makers' and Painters'" naphtha and petroleum naphthas. Other conventional solvents can also be added. The solvent or diluent should be free of water. An aliphatic monohydric alcohol may also be added to provide the liquid product with viscosity stability and resistance to gelation. The alcohol may be added in an amount of 30-400 per cent by weight based on the orthotitanate or orthozirconate ester; it may be unsaturated and contain up to 20 carbon atoms, a large number being specified. There may also be added metal driers such as iron, cobalt or manganese salts of 2-ethylhexoic acid, liquid siloxane polymers to alter the surface characteristics of the coating, 1-5 per cent by weight based on the polymer of a flexibilizer such as tri-2-ethylhexyl phosphate, compatible resins and plasticizers and conventional pigments, extenders, fillers, lakes and dyes. The liquid coating composition may contain 10-70 per cent by weight of non-volatile matter and is applied to give a coating of 2-10 mg. per square inch for use as an interior coating of containers for the packaging of wetpack food products. After the solvent has evaporated the coating is cured by baking at 200-420 DEG F. for 60-5 minutes.ALSO:A composition comprising an oily liquid polymer of butadiene-1,3 and an orthotitanate ester or an orthozirconate ester is used for coating the interior of metal containers for food packaging. The polymer may be a homopolymer of butadiene or a copolymer of butadiene and styrene in which the butadiene is in preponderance, it is preferably an oily liquid having a molecular weight of 700-20,000. It may also be modified by a minor proportion, e.g. up to 2 per cent by weight of maleic anhydride or citraconic anhydride. The ester used may be (1) an orthotitanate or orthozirconate ester of an aliphatic monohydric alcohol, preferably of 6 to 20 carbon atoms such as 2-ethylhexyl alcohol; (2) an orthotitanate or orthozirconate ester of a 2,3-diorgano-substituted 1,3-diol such as 2-ethylhexane diol-1,3. These chelated derivatives are described in U.S.A. Specification 2,643,262 and may be formed in situ in the composition by introducing the titanium or zirconium derivative as the tetrabutyl ester and adding the diol; (3) an orthotitanate or orthozirconate ester of an enolizable beta-ketoacid ester, such as the C1-C6 alkyl and cyclohexyl alcohol esters of acetoacetic, beta-oxo - valeric, beta - oxo - caproic, beta - oxo-caprylic, or beta - oxo - cyclo - hexanepropionic acid. These chelates may also be similarly formed in situ. (4) an orthotitanate or orthozirconate partial ester of an aliphatic monohydric alcohol and partial acylate of a fatty oil acid, such as polymeric isopropoxytitanium oleate. These partial anhydrides-partial esters are described in U.S.A. Specifications 2,621,193, 2,621,195 and 2,666,772. The coating composition is dissolved in a volatile inert organic mutual solvent for the polymer and ester. Hydrocarbons or hydrocarbon mixtures boiling within the range of 80-220 DEG C. are preferred, such as mineral spirits. "Varnish Makers' and Painters'" naphtha and petroleum naphthas. Other conventional solvents can also be added. The solvent or diluent should be free of water. An aliphatic monohydric alcohol may also be added to provide the liquid product with viscosity stability and resistance to gelation. The alcohol may be added in an amount of 30-400 per cent by weight based on the orthotitanate or orthozirconate ester; it may be unsaturated and contain up to 20 carbon atoms, a large number being specified. There may also be added metal driers such as iron, cobalt or manganese, salts of 2-ethylhexoic acid, liquid siloxane polymers to alter the surface characteristics of the coating, 1-5 per cent by weight based on the polymer of a flexibilizer such as tri-2-ethylhexyl phosphate, compatible resins and plasticizers and conventional pigments, extenders, fillers, lakes and dyes. The liquid coating composition may contain 10-70 per cent by weight of non-volatile matter and is applied to give a coating of 2-10 mg. per square inch for use as an interior coating of containers for the packaging of wet-pack food products. After the solvent has evaporated the coating is cured by baking at 200-420 DEG F. for 60-5 minutes.
GB6469/57A 1956-03-15 1957-02-26 Improvements in or relating to coating compositions Expired GB805527A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US805527XA 1956-03-15 1956-03-15

Publications (1)

Publication Number Publication Date
GB805527A true GB805527A (en) 1958-12-10

Family

ID=22158121

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6469/57A Expired GB805527A (en) 1956-03-15 1957-02-26 Improvements in or relating to coating compositions

Country Status (4)

Country Link
BE (1) BE555696A (en)
DE (1) DE1055158B (en)
FR (1) FR1172702A (en)
GB (1) GB805527A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1232681B (en) * 1960-06-21 1967-01-19 Du Pont Method of lining metal containers for food

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1232681B (en) * 1960-06-21 1967-01-19 Du Pont Method of lining metal containers for food

Also Published As

Publication number Publication date
BE555696A (en)
DE1055158B (en) 1959-04-16
FR1172702A (en) 1959-02-13

Similar Documents

Publication Publication Date Title
US2048799A (en) Silicon esters of modified polyhydroxy alcohols
US2358475A (en) Modified drying oil
US3331886A (en) Thermosettable coating comprising (1) an organic polycarboxylic polymeric material and (2) a resinous polyepoxide-alkanol amine adduct
US2733222A (en) Alkyl titanates
US3474060A (en) Aqueous stove lacquers comprising a basic pigment and a salt of an alkyd resin with a tertiary alkylamine
US2072770A (en) Coating composition and drier
US2876207A (en) Stabilized liquid coating composition containing butadiene 1-3 and method of preparing same
US2495458A (en) Interpolymer produced from polyhydric alcohol, polybasic acid, and interpolymer of vinylaromatic compound with drying oil or acid
US2888417A (en) Liquid polydiene coating modified with oil modified alkyd resin
GB805527A (en) Improvements in or relating to coating compositions
US2888422A (en) Film forming aqueous colloidal dispersions containing tris (hydroxymethyl) nitromethane and method for preparing same
DE1292285B (en) Coating and painting materials
US2544391A (en) Coating composition
US3859235A (en) Modified alkyd resin compositions for paints and varnishes comprising oxalic acid
US2135976A (en) Composition of matter and method of
US3320195A (en) Coating compositions containing a tetrasubstituted guanidine
US2580876A (en) Copolymer of styrene and rosin and esters thereof with the alcoholysis product of a drying oil and a polyhydric alcohol containing free hydroxyl groups
US2873202A (en) Water repellent and mar resistant coating composition containing a waxy dialkyl ether
US2863786A (en) Odor-free liquid conjugated diene polymers
US2863784A (en) Hydroxylated conjugated diolefin polymers in drying oil compositions and a method ofpreparing the same
US2877197A (en) Liquid coating composition comprising a polythiol polymer, a metallic drier, an amine, and a solvent therefor
US2907669A (en) Treatment of hydrocarbon drying oils with epoxidized triglyceride oils
US4100119A (en) Greater water resistance and shorter drying time in water soluble enamel paints
US3574566A (en) Nitrogen- and phosphorus-containing composition suitable for application to metal surfaces
US2901450A (en) Film-forming and drying compositions