GB803373A - Dehydrogenation catalyst and a process for its production - Google Patents
Dehydrogenation catalyst and a process for its productionInfo
- Publication number
- GB803373A GB803373A GB38041/56A GB3804156A GB803373A GB 803373 A GB803373 A GB 803373A GB 38041/56 A GB38041/56 A GB 38041/56A GB 3804156 A GB3804156 A GB 3804156A GB 803373 A GB803373 A GB 803373A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- copper
- alkali metal
- catalyst
- metal compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 10
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 12
- 229910052802 copper Inorganic materials 0.000 abstract 12
- 239000010949 copper Substances 0.000 abstract 12
- 229910052759 nickel Inorganic materials 0.000 abstract 11
- 150000001339 alkali metal compounds Chemical class 0.000 abstract 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 2
- 150000003112 potassium compounds Chemical class 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910001960 metal nitrate Inorganic materials 0.000 abstract 1
- 229910001463 metal phosphate Inorganic materials 0.000 abstract 1
- 229910052914 metal silicate Inorganic materials 0.000 abstract 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical class [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- -1 saturated aliphatic alcohols Chemical group 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Abstract
A catalyst, particularly suitable for the dehydrogenation of an alcohol to a carbonyl compound comprises: copper, nickel, and an alkaline-reacting alkali metal compound on a siliceous support; the alkali metal compound or compounds being present to the extent of from 1 to 30 per cent of the combined copper and nickel. The preferred support is kieselguhr and the preferred alkali metal compound is a potassium compound. Advantageously the support comprises 20 to 400 per cent of the combined weight of copper and nickel and the alkali metal compound advantageously comprises 3 to 20 per cent of the combined weight of copper and nickel. The copper and nickel are in the proportions of 2-1 to 1-2. The catalyst is prepared by precipitating the aqueous solution of a compound of copper and a compound of nickel by an alkaline-reacting alkali metal compound on to kieselguhr; washing the precipitate; impregnating with an alkali metal compound; drying and treating with hydrogen or hydrogen-containing gas. The catalyst may be activated by treatment, before reduction by hydrogen with an inert and/or an oxidizing gas for at least sixty minutes at 250 DEG to 600 DEG C. The catalyst may be regenerated by treatment with oxygen or oxygen - containing gas at temperatures below 300 DEG C.ALSO:Carbonyl compounds are prepared by the dehydrogenation of alcohols wherein is used as catalyst a composition comprising copper, nickel and one or more alkaline-reacting alkali metal compounds on a siliceous support, the alkali metal compound or compounds being present to the extent of from 1 to 30 per cent of the combined weight of copper and nickel. The preferred support is kieselguhr and the preferred alkali metal compound is a potassium compound. Advantageously the support comprises 20 to 400 per cent of the combined weight of copper and nickel and the alkali metal compound advantageously comprises 3 to 20 per cent of the combined weight of copper and nickel. The copper and nickel may be present in the proportions of 2-1 to 1-2. The preparation of the catalysts is described (see Group III). Alcohols, particularly secondary saturated aliphatic alcohols, may be converted into carbonyl compounds at a temperature in the range of 200 DEG to 300 DEG C., using a space velocity of 3 to 6 litres (liquid) of alcohol per litre of catalyst per hour. Spent catalyst may be regenerated by treatment with oxygen at temperatures below 300 DEG C. followed by reduction. Examples describe the conversion of isopropyl alcohol to acetone and sec.-butanol to methyl ethyl ketone by passing the alcohol or mixture thereof with hydrogen in the vapour phase over a catalyst obtained by adding a solution of copper and nickel nitrates to a solution of sodium carbonate containing kieselguhr, filtering, impregnating the solid residue with potassium carbonate and finally reducing with hydrogen at 300 DEG C. The potassium carbonate used may be replaced by an alkali metal hydroxide, silicate, phosphate, nitrate or borate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE803373X | 1956-01-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB803373A true GB803373A (en) | 1958-10-22 |
Family
ID=6721538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB38041/56A Expired GB803373A (en) | 1956-01-31 | 1956-12-13 | Dehydrogenation catalyst and a process for its production |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB803373A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4600529A (en) * | 1983-09-19 | 1986-07-15 | Gas Research Institute | Dehydrogenation of alcohols using alkali carbonate catalysts |
| CN109772344A (en) * | 2017-11-14 | 2019-05-21 | 中国石油化工股份有限公司 | A kind of copper-based catalysts, its manufacturing method and its application |
| CN114733530A (en) * | 2022-03-29 | 2022-07-12 | 西安交通大学 | A kind of hydrogenation catalyst of organic liquid hydrogen storage carrier and preparation method and application thereof |
-
1956
- 1956-12-13 GB GB38041/56A patent/GB803373A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4600529A (en) * | 1983-09-19 | 1986-07-15 | Gas Research Institute | Dehydrogenation of alcohols using alkali carbonate catalysts |
| CN109772344A (en) * | 2017-11-14 | 2019-05-21 | 中国石油化工股份有限公司 | A kind of copper-based catalysts, its manufacturing method and its application |
| CN114733530A (en) * | 2022-03-29 | 2022-07-12 | 西安交通大学 | A kind of hydrogenation catalyst of organic liquid hydrogen storage carrier and preparation method and application thereof |
| CN114733530B (en) * | 2022-03-29 | 2023-11-03 | 陕西氢易能源科技有限公司 | Hydrogenation catalyst of organic liquid hydrogen storage carrier, and preparation method and application thereof |
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