GB801674A - Preparation of alkyl aluminium compounds - Google Patents
Preparation of alkyl aluminium compoundsInfo
- Publication number
- GB801674A GB801674A GB17051/56A GB1705156A GB801674A GB 801674 A GB801674 A GB 801674A GB 17051/56 A GB17051/56 A GB 17051/56A GB 1705156 A GB1705156 A GB 1705156A GB 801674 A GB801674 A GB 801674A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dimethyl
- aluminium
- butene
- hexene
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005234 alkyl aluminium group Chemical group 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- 239000004411 aluminium Substances 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- KQRPZENSXZIOQO-UHFFFAOYSA-N 2,2-dimethyl-3-methylidenepentane Chemical compound CCC(=C)C(C)(C)C KQRPZENSXZIOQO-UHFFFAOYSA-N 0.000 abstract 1
- OWWIWYDDISJUMY-UHFFFAOYSA-N 2,3-dimethylbut-1-ene Chemical compound CC(C)C(C)=C OWWIWYDDISJUMY-UHFFFAOYSA-N 0.000 abstract 1
- LVLXQRZPKUFJJQ-UHFFFAOYSA-N 2,3-dimethylhex-1-ene Chemical compound CCCC(C)C(C)=C LVLXQRZPKUFJJQ-UHFFFAOYSA-N 0.000 abstract 1
- LIMAEKMEXJTSNI-UHFFFAOYSA-N 2,3-dimethylpent-1-ene Chemical compound CCC(C)C(C)=C LIMAEKMEXJTSNI-UHFFFAOYSA-N 0.000 abstract 1
- GIBPFTYFAOOKOV-UHFFFAOYSA-N 2,4-dimethyl-3-methylidenepentane Chemical compound CC(C)C(=C)C(C)C GIBPFTYFAOOKOV-UHFFFAOYSA-N 0.000 abstract 1
- PKVDGQHNRICJLA-UHFFFAOYSA-N 2,4-dimethylhex-1-ene Chemical compound CCC(C)CC(C)=C PKVDGQHNRICJLA-UHFFFAOYSA-N 0.000 abstract 1
- LXQPBCHJNIOMQU-UHFFFAOYSA-N 2,4-dimethylpent-1-ene Chemical compound CC(C)CC(C)=C LXQPBCHJNIOMQU-UHFFFAOYSA-N 0.000 abstract 1
- ISZWTVCVSJVEOL-UHFFFAOYSA-N 2,5-dimethylhex-1-ene Chemical compound CC(C)CCC(C)=C ISZWTVCVSJVEOL-UHFFFAOYSA-N 0.000 abstract 1
- ADHCYQWFCLQBFG-UHFFFAOYSA-N 2-methyl-3-methylidenepentane Chemical compound CCC(=C)C(C)C ADHCYQWFCLQBFG-UHFFFAOYSA-N 0.000 abstract 1
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 abstract 1
- IRUDSQHLKGNCGF-UHFFFAOYSA-N 2-methylhex-1-ene Chemical compound CCCCC(C)=C IRUDSQHLKGNCGF-UHFFFAOYSA-N 0.000 abstract 1
- PKXHXOTZMFCXSH-UHFFFAOYSA-N 3,3-dimethylbut-1-ene Chemical compound CC(C)(C)C=C PKXHXOTZMFCXSH-UHFFFAOYSA-N 0.000 abstract 1
- XTVRLCUJHGUXCP-UHFFFAOYSA-N 3-methyleneheptane Chemical compound CCCCC(=C)CC XTVRLCUJHGUXCP-UHFFFAOYSA-N 0.000 abstract 1
- TWCRBBJSQAZZQB-UHFFFAOYSA-N 3-methylidenehexane Chemical compound CCCC(=C)CC TWCRBBJSQAZZQB-UHFFFAOYSA-N 0.000 abstract 1
- RYKZRKKEYSRDNF-UHFFFAOYSA-N 3-methylidenepentane Chemical compound CCC(=C)CC RYKZRKKEYSRDNF-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 229910000091 aluminium hydride Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N diisobutylaluminium hydride Substances CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003701 inert diluent Substances 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 125000002370 organoaluminium group Chemical group 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A mixture of aluminium, an alpha-olefine, hydrogen and a trialkyl aluminium compound or a dialkyl aluminium hydride as catalyst is heated to at least 140 DEG C. to start the reaction, the temperature of the mixture being controlled below 250 DEG C. and during the greater part of the reaction between 140 DEG and 200 DEG C., then cooled to below 120 DEG C. and isolating the required aluminium alkyl. The organo-aluminium catalyst may be a mixture of by-products from a previous run. The aluminium may be a commercial powder preferably of particle diameter below about 50 microns. Specified alpha-olefines are those of formula CH2=CR1(R2), where R1 and R2 are alkyl groups, and include isobutylene, 2 - methyl - 1 - butene, 2,3 - dimethyl - 1 - butene, 2 - ethyl - 1 - butene, 2-ethyl - 3 - methyl - 1 - butene, 2 - methyl - 1-pentene, 2,3 - dimethyl - 1 - pentene, 2,4 - dimethyl - 1 - pentene, 2 - ethyl - 1 - pentene, 2-methyl - 1 - hexene, 2,3 - dimethyl - 1 - hexene, 2,4 - dimethyl - 1 - hexene, 2,5 - dimethyl - 1-hexene, 2 - ethyl - 1 - hexene, 2,3,3 - dimethyl-1 - butene, 2 - ethyl - 3,3 - dimethyl - 1 - butene and 2 - isopropyl - 3 - methyl - 1 - butene. The olefine and hydrogen should be anhydrous and free from acetylenic compounds, oxygen, acidic compounds, ammonia and organic compounds containing active hydrogen atoms. Inert diluents such as saturated paraffinic, cycloparaffinic and aromatic hydrocarbons may be used as reaction media. Example 1 describes the preparation of tri-isobutyl aluminium from aluminium powder, isobutylene and hydrogen in the presence of diisobutyl aluminium hydride.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US801674XA | 1956-06-15 | 1956-06-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB801674A true GB801674A (en) | 1958-09-17 |
Family
ID=22155684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17051/56A Expired GB801674A (en) | 1956-06-15 | 1956-06-01 | Preparation of alkyl aluminium compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB801674A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1125925B (en) * | 1959-02-24 | 1962-03-22 | Ethyl Corp | Process for the preparation of aluminum trialkyls and alkyl aluminum hydrides |
-
1956
- 1956-06-01 GB GB17051/56A patent/GB801674A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1125925B (en) * | 1959-02-24 | 1962-03-22 | Ethyl Corp | Process for the preparation of aluminum trialkyls and alkyl aluminum hydrides |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2848504A (en) | Alkyl hexafluorocyclobutanes and process for preparing them | |
| GB913358A (en) | Process for the preparation of hydrocarbon compounds of aluminium | |
| GB767400A (en) | Process for the manufacture of trialkylaluminium compounds | |
| GB801674A (en) | Preparation of alkyl aluminium compounds | |
| GB453854A (en) | Process for the manufacture of polymerisation products from olefines | |
| US2345573A (en) | Process for preparing beta-norborneol and its ether | |
| Jones et al. | Pyrazolines. VII. The Stereochemistry of the Thermal Decomposition of 5-Phenyl-1-pyrazolines1 | |
| US2546997A (en) | Perfluoro carbon compounds | |
| US3052698A (en) | Ester production | |
| GB772109A (en) | Unsaturated polyfluorinated organic compounds | |
| US2886599A (en) | Process for the production of boron alkyls | |
| GB999254A (en) | A novel unsaturated alcohol and a process for the preparation thereof | |
| US2955129A (en) | Preparation of tert.-alkyliso-thiocyanates | |
| Birchall et al. | 418. Polyfluoroarenes. Part III. A new synthesis of hexafluorobenzene | |
| US3264359A (en) | Dihalocarbene process | |
| GB936369A (en) | Preparation of dialkoxyvinylboranes | |
| GB1084742A (en) | Improvements in or relating to the manufacture of 2,3-dichloro-1,3-butadiene | |
| GB883375A (en) | A process of preparing primary alcohols | |
| GB1032621A (en) | Carbene reaction products | |
| GB942366A (en) | Process for preparation of high molecular weight alkyl aluminum compounds | |
| GB890221A (en) | Improvements in and relating to the production of organo-aluminium halide compositions | |
| US3478122A (en) | Novel process for the preparation of olefinic compounds and derivatives thereof | |
| GB890307A (en) | Improvements in or relating to the preparation of alcohols | |
| GB863179A (en) | Process and apparatus for the continuous production of sulphuric acid esters | |
| GB803558A (en) | Process for purifying hydrocarbons, especially olefines |