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GB799823A - Production of high molecular weight polyethylenes - Google Patents

Production of high molecular weight polyethylenes

Info

Publication number
GB799823A
GB799823A GB1562/55A GB156255A GB799823A GB 799823 A GB799823 A GB 799823A GB 1562/55 A GB1562/55 A GB 1562/55A GB 156255 A GB156255 A GB 156255A GB 799823 A GB799823 A GB 799823A
Authority
GB
United Kingdom
Prior art keywords
aluminium
diethyl
diethyl aluminium
compounds
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1562/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB799823A publication Critical patent/GB799823A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J13/00—Discharge tubes with liquid-pool cathodes, e.g. metal-vapour rectifying tubes
    • H01J13/02—Details
    • H01J13/04—Main electrodes; Auxiliary anodes
    • H01J13/06—Cathodes
    • H01J13/10—Containers for the liquid pool; Arrangements or mounting thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00—Treatment of filament-forming or like material
    • D01D1/06—Feeding liquid to the spinning head
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2893/00—Discharge tubes and lamps
    • H01J2893/0072—Disassembly or repair of discharge tubes
    • H01J2893/0073—Discharge tubes with liquid poolcathodes; constructional details
    • H01J2893/0074—Cathodic cups; Screens; Reflectors; Filters; Windows; Protection against mercury deposition; Returning condensed electrode material to the cathodic cup; Liquid electrode level control
    • H01J2893/0075—Cathodic cups
    • H01J2893/0078—Mounting cathodic cups in the discharge tube

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The novel aluminium compounds of formula R2AlX, wherein R is hydrogen or a hydrocarbon radical and X is <FORM:0799823/IV (b)/1> are used as catalyst components in the polymerization of ethylene (see Group IV (a)). In Example 7 piperidyl diethyl aluminium is prepared by adding 1 mol. of dry piperidine at room temperature to 1 mol. of triethyl aluminium and then heating to 120-140 DEG C. In Example 8, dimethyl-amino diethyl aluminium is prepared from dimethyl amine and diethyl aluminium hydride, and in Example 9 ethylmercapto diethyl aluminium is obtained from ethyl mercaptan and triethyl aluminium. Other compounds specified are phenoxy-, b -naphthoxy-, methylcyclohexylamino-, dicyclohexylamino- and N-methyl anilino-diethyl aluminium compounds, diethyl aluminiumcaprolactamide, -acetate and benzoate, and diisobutyl aluminium benzoate. Specification 713,081 is referred to.ALSO:Catalysts used in the polymerization of ethylene are formed by mixing an aluminium compound R2AlX, wherein R is hydrogen or a hydrocarbon radical and X is hydrogen, halogen or an alkoxy, aryloxy, sec.-amine, mono-N-substituted amide, mercaptan, thiophenol, carboxylic acid, or a sulphonic acid group, and a compound of a metal of the A sub-groups of groups IV to VI. In examples, the aluminium compounds used are diethyl aluminium hydride, chloride, sesquichloride and phenolate, triphenyl aluminium, piperidyl diethyl aluminium, methoxy dimethyl aluminium, and diethylamino- and ethyl-mercapto-diethyl aluminium. Other compounds listed include phenoxy- and naphthoxy-diethyl aluminium, dimethylamino - diethyl aluminium (methylcyclohexylamino), diethyl aluminium, (dicyclohexylamino) - diethyl aluminium, (N-methylanilino)-diethyl aluminium, diethyl aluminium caprolactamide, diethyl aluminium acetate, and diethyl- and diisobutyl-aluminium benzoate. The Group IV (a), V (a) and VI (a) metallic compounds specified are the halides, oxyhalides, complex halides, oxides, hydroxides, alkoxides, acetates, benzoates and acetyl acetonates, e.g. titanium, zirconium and tungsten tetrachlorides and chromous chloride. Specification 713,081, [Group IV (a)], is referred to.ALSO:High molecular weight polyethylene is produced using a catalyst formed by mixing a compound of formula R2AlX, wherein R is hydrogen or a hydrocarbon radical and X is hydrogen, halogen or an alkoxy, aryloxy, sec.-amine, mono-N-substituted amide, mercaptan, thiophenol, carboxylic acid, or a sulphonic acid group, and a compound of a metal of the A subgroups of Groups IV to VI. In the examples the aluminium compounds used are diethyl aluminium hydride, chloride, sesquichloride and phenolate, triphenyl aluminium, piperidyl diethyl aluminium, methoxy dimethyl aluminium, and diethylamino and ethylmercapto diethyl aluminium, but other compounds listed include phenoxy- and naphthoxy-diethyl aluminium, dimethylamino diethylaluminium (methylcyclohexylamino) - diethyl aluminium, (dicyclohexylamino) - diethyl aluminium, (N - methyl anilino) - diethylaluminium, diethyl aluminium caprolactamide, diethyl aluminium acetate and diethyl- and diisobutyl-aluminium benzoate. The Group IV to VI metallic compounds disclosed are the halides (chlorides or bromides), oxy-halides (oxychloride), complex halides (complex fluorides), oxides, hydroxides and organic compounds such as alkoxides, acetates, benzoates and acetyl acetonates, and the examples use titanium, zirconium and tungsten tetrachlorides and chromous chloride. The ethylene, which may be introduced intermittently during the polymerization, may be pure or produced by cracking ethane, propane or petroleum, or in the Fischer-Tropsch synthesis. Polymerization may be carried out in solution in solvents such as pentane, hexane, cyclohexane, tetrahydronaphthalene, decahydronaphthalene, paraffins, benzene, xylene, o-dichlorbenzene, chlorinated naphthalenes, dibutyl ether, dioxane, tetrahydrofurane and mixtures. Catalyst formation and polymerization is preferably conducted in an inert atmosphere, e.g. nitrogen. On completion of polymerization the catalyst may be destroyed with methanol and the product washed with methanol and dilute nitric acid. The polyethylenes produced are linear, of crystalline structure and have improved physical properties. They may be stretched while cold and may be formed into films, sheets and filaments. Specification 713,081 is referred to.
GB1562/55A 1954-01-19 1955-01-18 Production of high molecular weight polyethylenes Expired GB799823A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEZ3941A DE1012460B (en) 1953-11-17 1954-01-19 Process for the production of high molecular weight polyethylenes
DEZ4603A DE1046319B (en) 1954-01-19 1954-12-11 Process for the production of high molecular weight polyethylenes
DEZ4604A DE1016023B (en) 1954-01-19 1954-12-13 Process for the production of high molecular weight polyethylenes

Publications (1)

Publication Number Publication Date
GB799823A true GB799823A (en) 1958-08-13

Family

ID=43499864

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1562/55A Expired GB799823A (en) 1954-01-19 1955-01-18 Production of high molecular weight polyethylenes

Country Status (7)

Country Link
BE (1) BE534792A (en)
CH (1) CH363485A (en)
DE (3) DE1012460B (en)
FR (1) FR1123617A (en)
GB (1) GB799823A (en)
LU (1) LU33306A1 (en)
NL (1) NL94705C (en)

Cited By (11)

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US3082234A (en) * 1960-11-03 1963-03-19 United States Borax Chem Preparation of thioaryloxides and alkyl aluminum thioaryloxides
US3245976A (en) * 1961-07-17 1966-04-12 Snam Societa Per Azioni Process for preparing 1, 4-cis-butadiene high polymers
US3281443A (en) * 1961-02-24 1966-10-25 Continental Oil Co Preparation and use of dialkoxyaluminum hydride reducing agents
US3311604A (en) * 1961-02-04 1967-03-28 Snam Spa Process for polymerizing isoprene with a catalyst consisting of titanium tetrachloride and an aluminum hydride
US4055634A (en) * 1974-02-22 1977-10-25 Hoffmann-La Roche, Inc. Antiperspirants
US4129702A (en) * 1973-08-19 1978-12-12 Imperial Chemical Industries Limited Polymerizing unsaturated halides with carbamate type metallic catalyst
US6462153B1 (en) * 1996-04-03 2002-10-08 Occidental Chemical Corporation Method of polymerizing vinyl chloride monomer
WO2006043985A1 (en) 2004-06-16 2006-04-27 Dow Global Technologies Inc. Method for identifying ziegler-natta cocatalyst
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
CN106916239A (en) * 2017-03-22 2017-07-04 山东东方宏业化工有限公司 A kind of preparation method of the polybutene 1 of Narrow Molecular Weight Distribution

Families Citing this family (152)

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US2899418A (en) * 1959-08-11 Polymerization of olefins by mechanical activation process
US3085084A (en) * 1954-08-16 1963-04-09 Du Pont Polymerization catalyst and process
DE1209747B (en) * 1954-10-30 1966-01-27 Bergwerksgesellschaft Hibernia Process for the preparation of polymers of aliphatic olefin hydrocarbons
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US3094514A (en) * 1958-02-13 1963-06-18 Goodrich Gulf Chem Inc Polymerization process for aliphatic, conjugated dienes
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Also Published As

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CH363485A (en) 1962-07-31
DE1016023B (en) 1957-09-19
BE534792A (en) 1955-01-31
FR1123617A (en) 1956-09-25
DE1046319B (en) 1958-12-11
DE1012460B (en) 1957-07-18
LU33306A1 (en) 1955-03-11
NL94705C (en) 1960-07-15

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