GB795173A - Process for the production of new ester compounds - Google Patents
Process for the production of new ester compoundsInfo
- Publication number
- GB795173A GB795173A GB27034/55A GB2703455A GB795173A GB 795173 A GB795173 A GB 795173A GB 27034/55 A GB27034/55 A GB 27034/55A GB 2703455 A GB2703455 A GB 2703455A GB 795173 A GB795173 A GB 795173A
- Authority
- GB
- United Kingdom
- Prior art keywords
- malonic
- neopentyl
- sodium
- give
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 ester compounds Chemical class 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 5
- 229910052708 sodium Inorganic materials 0.000 abstract 5
- 239000011734 sodium Substances 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- XJYNAHTZBUSMKO-UHFFFAOYSA-N 2-(2,2-dimethylpropyl)propanedioic acid Chemical compound CC(C)(C)CC(C(O)=O)C(O)=O XJYNAHTZBUSMKO-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001339 alkali metal compounds Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000104 sodium hydride Inorganic materials 0.000 abstract 1
- 239000012312 sodium hydride Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Esters of the formula R-CH2-CXZ-(CO)n-OR1 are prepared by condensing R-CH2-CH2X with R3O-(CO)n-OR1 in the presence of an alkali metal or a strongly basic alkali metal compound to give a compound in which Z is an alkali metal, and if desired, acidifying this to give Z=H, or condensing with an alkyl or alkenyl halide to give Z=alkyl or alkenyl; X is CN or COOR2, R is tertiary alkyl (preferably C4-C7) and R1-R3 are alkyl, preferably identical radicals (C1-C4) to avoid the production of a mixture of compounds. Suitable condensing agents are sodium, sodamide, sodium hydride and sodium alcoholate. When one of the reactants is a dialkyl carbonate the sodium alcoholate may be formed in situ by addition of metallic sodium. Examples show the preparation of the di-ethyl esters of the following acids: neopentyl-malonic, neopentyloxalacetic, methyl-neopentyl-malonic, ethylneopentyl - malonic, allyl - neopentyl - malonic, 2 - bromallyl - neopentyl - malonic, carbethoxymethyl - neopentyl - malonic, neopenylcyanoacetic (and sodium derivative), neopentylcyano - oxalacetic, b ,b - dimethylbutyl - malonic and b - methyl - b - ethylbutyl - allyl - malonic. The dimethyl ester of neopentyl-malonic acid is also prepared. The compounds (n=2) split off CO on heating to give the compounds (n=1).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE795173X | 1954-09-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB795173A true GB795173A (en) | 1958-05-21 |
Family
ID=20339756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB27034/55A Expired GB795173A (en) | 1954-09-23 | 1955-09-22 | Process for the production of new ester compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB795173A (en) |
-
1955
- 1955-09-22 GB GB27034/55A patent/GB795173A/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES448454A1 (en) | Method of preparing malonic acid dialkyl esters | |
| GB795173A (en) | Process for the production of new ester compounds | |
| GB1388834A (en) | Cyclic acetal derivatives and their use as herbicides | |
| ES311043A1 (en) | A procedure for preparing cinamic acid derivatives. (Machine-translation by Google Translate, not legally binding) | |
| GB1342810A (en) | Process for the preparation of cyclic ketones | |
| GB1071818A (en) | Novel indane derivatives and processes for their preparation | |
| GB1107036A (en) | Esters of dibenzocycloheptenyl-carboxylic acids | |
| GB847779A (en) | 2-(4-biphenylyl)-í¸-hexenoic acid esters thereof | |
| GB820503A (en) | Improvements in or relating to the production of n-substituted 2-hydroxymethyl pyrrolidines | |
| GB837949A (en) | Reserpic acid diesters and salts thereof and process for their manufacture | |
| GB1079100A (en) | Process for preparing cyclene-carboxylates | |
| ES345183A1 (en) | Glycyrrhetinic acid derivatives | |
| GB837841A (en) | Reserpic acid diesters and salts thereof and process for their manufacture | |
| GB839313A (en) | Reserpic acid diesters and salts thereof and process for their manufacture | |
| GB923170A (en) | ||
| GB656864A (en) | Preparation of amino alcohol esters of disubstituted malonic acids | |
| GB637400A (en) | Nitroolefine derivatives of malonic esters and process for preparing same | |
| GB585833A (en) | Alkamine esters of pyrrole-2, 4-dicarboxylic acids | |
| GB1274543A (en) | Aziridino-mitosenes | |
| GB585834A (en) | Alkamine esters of pyrrole substituted acrylic acids | |
| GB837947A (en) | Reserpic acid esters and salts thereof and process for their manufacture | |
| GR14490B (en) | METHOD OF PREPARATION OF PEPPERS. | |
| GB913353A (en) | Steroids | |
| GB516542A (en) | Manufacture of cyclopentanopolyhydrophenanthrene derivatives | |
| GB738445A (en) | Steroid alkali-metal enolates |