GB787850A - Method for the preparation of acid halides of carbon-to-phosphorus bonded acids of phosphorus - Google Patents
Method for the preparation of acid halides of carbon-to-phosphorus bonded acids of phosphorusInfo
- Publication number
- GB787850A GB787850A GB203055A GB203055A GB787850A GB 787850 A GB787850 A GB 787850A GB 203055 A GB203055 A GB 203055A GB 203055 A GB203055 A GB 203055A GB 787850 A GB787850 A GB 787850A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphorus
- carbon
- preparation
- acid halides
- bromide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 3
- 150000004820 halides Chemical class 0.000 title abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 title 2
- 239000011574 phosphorus Substances 0.000 title 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- -1 cycloaliphatic Chemical group 0.000 abstract 1
- CLUOCCWZZAGLPM-UHFFFAOYSA-N diphenyl-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(=S)(S)C1=CC=CC=C1 CLUOCCWZZAGLPM-UHFFFAOYSA-N 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N hydrogen bromide Substances Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 abstract 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/34—Halides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
The invention comprises a method of preparing thiophosphinic halides of the structure: <FORM:0787850/IV (b)/1> in which R and R1 are organic radicles, by the action of anhydrous hydrogen halide on a diorgano-dithiophosphinic acid. In examples, hydrogen chloride or bromide is reacted with diphenyldithiophosphinic acid, the corresponding di(chlorophenyl)- and, ditolyl-derivatives to give the diaryl thio phosphinic chloride or bromide. The starting materials may be obtained by the method of Specification 787,083. A table of radicles which may be represented by R and R1 includes aliphatic, cycloaliphatic, aryl, and many substituted hydrocarbon groups.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB203055A GB787850A (en) | 1955-01-24 | 1955-01-24 | Method for the preparation of acid halides of carbon-to-phosphorus bonded acids of phosphorus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB203055A GB787850A (en) | 1955-01-24 | 1955-01-24 | Method for the preparation of acid halides of carbon-to-phosphorus bonded acids of phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB787850A true GB787850A (en) | 1957-12-18 |
Family
ID=22146201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB203055A Expired GB787850A (en) | 1955-01-24 | 1955-01-24 | Method for the preparation of acid halides of carbon-to-phosphorus bonded acids of phosphorus |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB787850A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4481151A (en) * | 1981-09-09 | 1984-11-06 | Hoechst Aktiengesellschaft | Process for the preparation of dialkylphosphinic acid halides |
-
1955
- 1955-01-24 GB GB203055A patent/GB787850A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4481151A (en) * | 1981-09-09 | 1984-11-06 | Hoechst Aktiengesellschaft | Process for the preparation of dialkylphosphinic acid halides |
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