GB786926A - Improvements in unsaturated polyesters - Google Patents
Improvements in unsaturated polyestersInfo
- Publication number
- GB786926A GB786926A GB33983/55A GB3398355A GB786926A GB 786926 A GB786926 A GB 786926A GB 33983/55 A GB33983/55 A GB 33983/55A GB 3398355 A GB3398355 A GB 3398355A GB 786926 A GB786926 A GB 786926A
- Authority
- GB
- United Kingdom
- Prior art keywords
- heating
- anhydride
- polyester
- mixture
- glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
An unsaturated polyester is the reaction product of (1) a glycol (e.g. ethylene-, diethylene-or propylene-glycol); (2) maleic acid or anhydride; and (3) hexahydrophthalic acid or anhydride; the maleic and hexahydrophthalic acids being present in the molar ratio of 0.6:0.4 to 0.4:0.6. The polyester may be copolymerized with an ethylenically unsaturated monomer, e.g. styrene or vinyl toluene (o-, m-, or p- or a mixture thereof. In an example, a polyester is made by heating a mixture of 1:2-propylene glycol and hexahydrophthalic acid to 100 DEG C., adding maleic anhydride and continuing the heating at 170-200 DEG C., to produce a resin of acid number 10-60. Later hydroquinone, styrene and methyl ketone peroxide were added, the mixture poured into a mould and the resin cured by heating to 70-110 DEG C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US786926XA | 1955-01-12 | 1955-01-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB786926A true GB786926A (en) | 1957-11-27 |
Family
ID=22145645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB33983/55A Expired GB786926A (en) | 1955-01-12 | 1955-11-28 | Improvements in unsaturated polyesters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB786926A (en) |
-
1955
- 1955-11-28 GB GB33983/55A patent/GB786926A/en not_active Expired
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