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GB786926A - Improvements in unsaturated polyesters - Google Patents

Improvements in unsaturated polyesters

Info

Publication number
GB786926A
GB786926A GB33983/55A GB3398355A GB786926A GB 786926 A GB786926 A GB 786926A GB 33983/55 A GB33983/55 A GB 33983/55A GB 3398355 A GB3398355 A GB 3398355A GB 786926 A GB786926 A GB 786926A
Authority
GB
United Kingdom
Prior art keywords
heating
anhydride
polyester
mixture
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33983/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uniroyal Inc
Original Assignee
United States Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Rubber Co filed Critical United States Rubber Co
Publication of GB786926A publication Critical patent/GB786926A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/553Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

An unsaturated polyester is the reaction product of (1) a glycol (e.g. ethylene-, diethylene-or propylene-glycol); (2) maleic acid or anhydride; and (3) hexahydrophthalic acid or anhydride; the maleic and hexahydrophthalic acids being present in the molar ratio of 0.6:0.4 to 0.4:0.6. The polyester may be copolymerized with an ethylenically unsaturated monomer, e.g. styrene or vinyl toluene (o-, m-, or p- or a mixture thereof. In an example, a polyester is made by heating a mixture of 1:2-propylene glycol and hexahydrophthalic acid to 100 DEG C., adding maleic anhydride and continuing the heating at 170-200 DEG C., to produce a resin of acid number 10-60. Later hydroquinone, styrene and methyl ketone peroxide were added, the mixture poured into a mould and the resin cured by heating to 70-110 DEG C.
GB33983/55A 1955-01-12 1955-11-28 Improvements in unsaturated polyesters Expired GB786926A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US786926XA 1955-01-12 1955-01-12

Publications (1)

Publication Number Publication Date
GB786926A true GB786926A (en) 1957-11-27

Family

ID=22145645

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33983/55A Expired GB786926A (en) 1955-01-12 1955-11-28 Improvements in unsaturated polyesters

Country Status (1)

Country Link
GB (1) GB786926A (en)

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