GB759956A - Improvements in or relating to gelatinous explosive compositions - Google Patents
Improvements in or relating to gelatinous explosive compositionsInfo
- Publication number
- GB759956A GB759956A GB12057/54A GB1205754A GB759956A GB 759956 A GB759956 A GB 759956A GB 12057/54 A GB12057/54 A GB 12057/54A GB 1205754 A GB1205754 A GB 1205754A GB 759956 A GB759956 A GB 759956A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- hydrogenated terphenyl
- nitrocellulose
- amount
- nitric ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002360 explosive Substances 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 3
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 abstract 6
- 239000000020 Nitrocellulose Substances 0.000 abstract 4
- -1 chalk Chemical class 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 4
- 229920001220 nitrocellulos Polymers 0.000 abstract 4
- 239000000499 gel Substances 0.000 abstract 3
- 239000004615 ingredient Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000006 Nitroglycerin Substances 0.000 abstract 2
- 229920002472 Starch Polymers 0.000 abstract 2
- 238000005422 blasting Methods 0.000 abstract 2
- UQXKXGWGFRWILX-UHFFFAOYSA-N ethylene glycol dinitrate Chemical compound O=N(=O)OCCON(=O)=O UQXKXGWGFRWILX-UHFFFAOYSA-N 0.000 abstract 2
- 229960003711 glyceryl trinitrate Drugs 0.000 abstract 2
- 235000010344 sodium nitrate Nutrition 0.000 abstract 2
- 239000008107 starch Substances 0.000 abstract 2
- 235000019698 starch Nutrition 0.000 abstract 2
- DYSXLQBUUOPLBB-UHFFFAOYSA-N 2,3-dinitrotoluene Chemical compound CC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O DYSXLQBUUOPLBB-UHFFFAOYSA-N 0.000 abstract 1
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 abstract 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 abstract 1
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 abstract 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 abstract 1
- PLAZTCDQAHEYBI-UHFFFAOYSA-N 2-nitrotoluene Chemical compound CC1=CC=CC=C1[N+]([O-])=O PLAZTCDQAHEYBI-UHFFFAOYSA-N 0.000 abstract 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 1
- 229940090898 Desensitizer Drugs 0.000 abstract 1
- 108010010803 Gelatin Proteins 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229920001131 Pulp (paper) Polymers 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- SKKBQEZMHMDRLE-UHFFFAOYSA-N [1-(2,3-dinitrooxypropoxy)-3-nitrooxypropan-2-yl] nitrate Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)COCC(O[N+]([O-])=O)CO[N+]([O-])=O SKKBQEZMHMDRLE-UHFFFAOYSA-N 0.000 abstract 1
- 229940069428 antacid Drugs 0.000 abstract 1
- 239000003159 antacid agent Substances 0.000 abstract 1
- 230000001458 anti-acid effect Effects 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003575 carbonaceous material Substances 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000008273 gelatin Substances 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 235000011852 gelatine desserts Nutrition 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 235000012054 meals Nutrition 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical class [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 abstract 1
- 235000010333 potassium nitrate Nutrition 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical class [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000015 trinitrotoluene Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/28—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate
- C06B31/32—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate with a nitrated organic compound
- C06B31/56—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate with a nitrated organic compound the compound being nitrocellulose present as less than 10% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/001—Fillers, gelling and thickening agents (e.g. fibres), absorbents for nitroglycerine
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/28—Compositions containing a nitrated organic compound the compound being nitrocellulose present as less than 10% by weight of the total composition
- C06B25/30—Compositions containing a nitrated organic compound the compound being nitrocellulose present as less than 10% by weight of the total composition with nitroglycerine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
759,956. Gelatinous blasting explosives. HERCULES POWDER CO. April 26,1954 [Oct. 26, 1953], No. 12057/54. Drawings to Specification. Class 9(2) Gelatinous blasting explosives comprise an explosive oil containing a liquid explosive nitric ester, an amount of hydrogenated terphenyl not substantially in excess of the amount miscible with the explosive oil, and an amount of nitrocellulose sufficient to form a gel with the explosive oil and hydrogenated terphenyl. The hydrogenated terphenyl may be added as desensitizing plasticizer to gelatin dynamites or semigelatin dynamites comprising 50-80 per cent oxidizing salts, e.g. ammonium, sodium, or potassium nitrates, or sodium chlorate or perchlorate, 1-12 per cent carbonaceous substances, e.g. meals, pulps or starch, and 0.3-1 per cent antacid, e.g. chalk, as so-called dope ingredients. The dope ingredients in semigelatins may total 5-85 per cent. Sulphur may be included as additional fuel. The nitric ester in amount 10-40 per cent may be any nitrated polyhydric alcohol, e.g. nitroglycerin. tetranitrodiglycerin, ethylene glycol dinitrate, or mixtures 5-30 per cent aromatic nitrocompound may be added as desensitizer to the nitric ester, e.g. mono-, di-. or tri-nitrotoluene, or nitro-phenol, - naphthalene, -benzene, or -xylene. The amounts of hydrogenated terphenyl and nitrocellulose may be 0.1-5 per cent and 0.2-2 per cent respectively. In examples semigelatin dynamites are disclosed containing: nitroglycerin/ethylene glycol dinitrate 20/80. 70/30, and 30/70, dinitrotoluene/orthonitrotoluene 66/34, ammonium and sodium nitrates, in admixture with hydrogenated terphenyl, nitrocellulose, starch, wood pulp, and chalk. The compositions are preparedby forming' an initial gel of the nitric ester, aromatic nitrocompound, and hydrogenated terphenyl with nitrocellulose and mixing the gel with the remaining dope ingredients. The ammonium nitrate is coated with 80/ 20 rosin/paraffin, of size Œ10 per cent held on 40 mesh screen, and at least 25 per cent pass 100 mesh, and of density 1.06 g./cc.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US759956XA | 1953-10-26 | 1953-10-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB759956A true GB759956A (en) | 1956-10-24 |
Family
ID=22129252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12057/54A Expired GB759956A (en) | 1953-10-26 | 1954-04-26 | Improvements in or relating to gelatinous explosive compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB759956A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106316727A (en) * | 2016-08-30 | 2017-01-11 | 许畅 | Porous and granular ANFO (ammonium nitrate fuel oil) and preparation method thereof |
-
1954
- 1954-04-26 GB GB12057/54A patent/GB759956A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106316727A (en) * | 2016-08-30 | 2017-01-11 | 许畅 | Porous and granular ANFO (ammonium nitrate fuel oil) and preparation method thereof |
| CN106316727B (en) * | 2016-08-30 | 2018-10-02 | 许畅 | A kind of porous particulated ammonium oil explosive and preparation method thereof |
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