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GB732573A - Treatment of textile materials for improving crease and shrink resistance - Google Patents

Treatment of textile materials for improving crease and shrink resistance

Info

Publication number
GB732573A
GB732573A GB30258/52A GB3025852A GB732573A GB 732573 A GB732573 A GB 732573A GB 30258/52 A GB30258/52 A GB 30258/52A GB 3025852 A GB3025852 A GB 3025852A GB 732573 A GB732573 A GB 732573A
Authority
GB
United Kingdom
Prior art keywords
compound
glycidyl ether
polymer
per molecule
polyhydric alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30258/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB732573A publication Critical patent/GB732573A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/625—Hydroxyacids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/08—Oxirane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A polyepoxy compound or compounds having an average number of epoxy groups per molecule greater than 1.0 and consisting of a glycidyl ether of a polyhydric alcohol or a polymer of a 2-alkenyl glycidyl ether, or a mixture of a glycidyl ether of a polyhydric alcohol and a polymer of a 2-alkenyl glycidyl ether, is dispersed in a textile material, which is then subjected to an elevated temperature in the presence of a hardening agent to harden the compound. The polyepoxy compound may be saturated or unsaturated, aliphatic or cycloaliphatic, and may be substituted with non-interfering substituents such as hydroxyl groups. There may be an average of more than 1.5 epoxy groups per molecule. The compound may be a polymer of allyl glycidyl ether having a molecular weight between 300 and 1,000 and an average number of epoxy groups per molecule of up to 6.0, or a condensation product of one or more polyhydric alcohols with dichlor-, epichlor-, dibromo- or epibromohydrin. The polyhydric alcohol may have from 2 to 10 carbon atoms and from 2 to 6 hydroxyl groups, ethylene glycol and glycerol being specified. The hardening agent may be p-toluenesulphonic acid, phosphoric, boric, perchloric or persulphuric acid, a p-cresole or urea-boron-trifluoride complex, triethylamine, ethylene diamine, or mono- or poly-carboxylic acids or their anhydrides containing from 2 to 12 carbon atoms such as citric, acetic or phthalic acid or anhydride. The amount of compound taken up by the material may vary from 3 to 50 per cent by weight of the material, which may be yarn or woven, knitted or netted fabrics of cotton, linen, silk, jute, rayon, wool or mixtures thereof. The compound may be applied as aqueous or organic solution or dispersion. A solution in an aqueous lower aliphatic alcohol may be employed, or the less soluble compounds may be emulsified in water with an emulsifying agent which is free from nitrogen or strong acid groups. The hardening agent may be added to the impregnating liquid or sprayed upon the impregnated material. The impregnating liquid may comprise also a plasticizer or textile softening agent of the cationic type. The liquid may be applied by dipping or by padding rollers or by spraying or spreading devices and may be applied locally by printing rollers or stencils, or it may be applied to the cotton back of a compound fabric comprising artificial or natural silk and a cotton back. The impregnated material may be dried at 50-80 DEG C. prior to hardening treatment at 50-150 DEG C. Specifications 675,168, 675,180, 681,001 and 681,991, [all in Group IV (a)] are referred to.
GB30258/52A 1951-12-01 1952-11-28 Treatment of textile materials for improving crease and shrink resistance Expired GB732573A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US259504A US2752269A (en) 1951-12-01 1951-12-01 Treatment of textile materials

Publications (1)

Publication Number Publication Date
GB732573A true GB732573A (en) 1955-06-29

Family

ID=22985230

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30258/52A Expired GB732573A (en) 1951-12-01 1952-11-28 Treatment of textile materials for improving crease and shrink resistance

Country Status (6)

Country Link
US (1) US2752269A (en)
BE (1) BE515900A (en)
DE (1) DE1024049B (en)
FR (1) FR1071905A (en)
GB (1) GB732573A (en)
NL (1) NL174182B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1094225B (en) * 1955-02-22 1960-12-08 Courtaulds Inc Process for crease and shrink-proof finishing of cellulose textiles

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3073662A (en) * 1963-01-15 Process for the production of fast dye-
US2903381A (en) * 1954-09-03 1959-09-08 Shell Dev Treatment of synthetic textiles with a polyepoxide having a plurality of 1,2 epoxy groups
US2829071A (en) * 1954-04-26 1958-04-01 Shell Dev Treatment of wool containing textiles
US2829072A (en) * 1954-05-19 1958-04-01 Bates Mfg Co Process for the treatment of textile materials with epoxy resins and for curing the same
BE541693A (en) * 1954-10-04 1900-01-01
US2841595A (en) * 1955-01-31 1958-07-01 Shell Dev Process for manufacture of glycidyl ethers of polyhydric phenols
BE546441A (en) * 1955-03-28
NL109055C (en) * 1955-06-28
US2826514A (en) * 1955-11-17 1958-03-11 Shell Dev Treatment of textile materials and composition therefor
GB853619A (en) * 1956-02-06 1960-11-09 Rohm & Haas New unsaturated glycidyl ethers, polymers thereof and methods for producing them
US2886472A (en) * 1956-04-27 1959-05-12 Shell Dev Treatment of textile materials
US2794754A (en) * 1956-04-30 1957-06-04 Shell Dev Treatment of textile materials
US2928808A (en) * 1956-12-10 1960-03-15 Devoe & Raynolds Co Inc Curing of polyepoxides
NL221263A (en) * 1956-10-05
US2928794A (en) * 1956-12-05 1960-03-15 Devoe & Raynolds Co Inc Curing of polyepoxides
US2869970A (en) * 1957-04-11 1959-01-20 Edward M Filachione Tanning with epoxy resins
US3024080A (en) * 1957-10-14 1962-03-06 Rohm & Haas 2, 6-dioxaspiro (3, 3)heptane treated cellulose fabric and the production thereof
DE1155666B (en) * 1957-11-02 1963-10-10 Schickedanz Ver Papierwerk Process for the production of absorbent and water-resistant surface structures from cellulose fibers
US2928810A (en) * 1957-11-15 1960-03-15 Devoe & Raynolds Co Aliphatic alcohol-epoxide resin compositions
US2928811A (en) * 1957-11-18 1960-03-15 Devoe & Raynolds Co Epoxide resin-amide compositions
US3036041A (en) * 1957-12-23 1962-05-22 Richardson Co Reaction products of epoxylated compositions and process
US3073799A (en) * 1958-01-20 1963-01-15 Gen Electric Resin compositions and their preparation
NL240376A (en) * 1958-06-19
US3019076A (en) * 1958-07-22 1962-01-30 Jr Clay E Pardo Treatment of textiles with polyepoxides and polyamides
US3043813A (en) * 1958-10-03 1962-07-10 Union Carbide Corp Polymer of alkenyl epoxycyclopentyl ethers
US3026216A (en) * 1959-10-05 1962-03-20 Union Carbide Corp Treatment of textile fabrics with methylglycidyl ethers
US3128147A (en) * 1959-09-30 1964-04-07 Courtaulds Ltd Process for treating polynosic fibers and products obtained thereby
US3084073A (en) * 1959-12-10 1963-04-02 Rohm & Haas Copolymers of alkyl acrylate, methoxymethyl vinyl sulfide, comonomer containing functional groups, and coating compositions thereof
US3097050A (en) * 1959-12-28 1963-07-09 Rohm & Haas Process of creaseproofing cellulose fabrics with 2, 6-dioxaspiro (3, 3) heaptane and ormaldehyde and fabrics produced thereby
US3150190A (en) * 1960-02-18 1964-09-22 Quaker Chem Corp Acetal condensation products and their preparation
BE600676A (en) * 1960-03-01 1900-01-01
US3131083A (en) * 1960-03-25 1964-04-28 Standard Packaging Corp Method of impregnating card stock
US3228920A (en) * 1960-05-12 1966-01-11 Metal Recovery Systems Chelating resins and method of preparation
US3069311A (en) * 1962-03-28 1962-12-18 Hercules Powder Co Ltd Paper manufacture
US3321099A (en) * 1963-02-04 1967-05-23 Dow Chemical Co Composition for the lamination of glass by means of epoxy resinous materials
US3382030A (en) * 1963-11-08 1968-05-07 Agriculture Usa Modification of cellulose with butadiene diepoxide using a dioxane-water solvent system
US3377406A (en) * 1963-12-16 1968-04-09 Shell Oil Co Process of esterification of polyepoxides with ethylenically unsaturated monocarboxylic acids in the presence of onium salts of inorganic acids
DE1300695B (en) * 1963-12-21 1969-08-07 Henkel & Cie Gmbh Process for the production of molded bodies, coatings and adhesives based on epoxy polyadducts
US3293073A (en) * 1964-02-12 1966-12-20 Union Carbide Corp Process for imparting wash and wear properties to cellulose-containing textile fabric and resulting product
US3293071A (en) * 1964-02-14 1966-12-20 Union Carbide Corp Process for treating cellulosic textile material
US3313796A (en) * 1964-02-24 1967-04-11 Monsanto Co Process for improving the antistatic properties of synthetic articles
NL131186C (en) * 1964-12-24 1900-01-01
CH1795665D (en) * 1964-12-30
US3408182A (en) * 1965-01-18 1968-10-29 Xerox Corp Electrophotographic materials and methods employing photoconductive resinous charge transfer complexes
US3408184A (en) * 1965-01-18 1968-10-29 Xerox Corp Electrophotographic materials and methods employing photoconductive resinous charge transfers complexes
US3402988A (en) * 1965-04-02 1968-09-24 Agriculture Usa Chemical deactivation of catalyst at both faces of a cellulosic fabric impregnated with a resin-catalyst system to improve abrasion resistance of fabric after curing
GB1174344A (en) * 1967-02-13 1969-12-17 Ciba Ltd Epoxide-Containing Compositions
US4240971A (en) * 1969-07-18 1980-12-23 Hercules Incorporated Epoxy-sulfonylazide compounds
US4049851A (en) * 1975-03-21 1977-09-20 Basf Aktiengesellschaft Manufacture of bonded textile sheet materials
EP1138819B1 (en) * 2000-03-31 2007-09-12 Kao Corporation Fiber product treating agents
JP5646572B2 (en) * 2012-10-16 2014-12-24 日本蚕毛染色株式会社 Modified fiber and method for producing the same

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2511913A (en) * 1950-06-20 Compositions of resinous epoxides
NL59974C (en) * 1943-06-16
US2455083A (en) * 1945-05-08 1948-11-30 Pacific Mills Cellulose ethers of 3, 4 epoxy 1-butene and their oxidation products
US2589245A (en) * 1945-12-03 1952-03-18 Devoe & Raynolds Co Amide-epoxide compositions, etc.
US2494295A (en) * 1946-09-13 1950-01-10 Devoe & Raynolds Co Compositions of resinous epoxides and aromatic sulfonamide-aldehyde condensates
US2464753A (en) * 1947-03-25 1949-03-15 Shell Dev Allyl glycidyl mixed diether of bis-(4-hydroxyphenyl)-2,2-propane and polymers thereof
NL68092C (en) * 1947-06-11
US2541027A (en) * 1948-05-11 1951-02-13 Shell Dev Compositions of matter containing epoxy ethers and phosphorus-containing compounds
US2516960A (en) * 1948-08-19 1950-08-01 Du Pont Ethylene-alkylene oxide copolymers
US2606810A (en) * 1949-09-28 1952-08-12 American Cyanamid Co Treatment of wool-containing textile materials and products thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1094225B (en) * 1955-02-22 1960-12-08 Courtaulds Inc Process for crease and shrink-proof finishing of cellulose textiles

Also Published As

Publication number Publication date
US2752269A (en) 1956-06-26
NL174182B (en)
BE515900A (en)
FR1071905A (en) 1954-09-07
DE1024049B (en) 1958-02-13

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