GB727535A - Improvements relating to chromium-containing monoazo dyestuffs and their use - Google Patents
Improvements relating to chromium-containing monoazo dyestuffs and their useInfo
- Publication number
- GB727535A GB727535A GB8694/53A GB869453A GB727535A GB 727535 A GB727535 A GB 727535A GB 8694/53 A GB8694/53 A GB 8694/53A GB 869453 A GB869453 A GB 869453A GB 727535 A GB727535 A GB 727535A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chromium
- naphtholdisulphomethylamide
- disalicylato
- chroming
- chromate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052804 chromium Inorganic materials 0.000 title abstract 4
- 239000011651 chromium Substances 0.000 title abstract 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 title 1
- 239000000975 dye Substances 0.000 abstract 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 2
- 210000002268 wool Anatomy 0.000 abstract 2
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- 150000001845 chromium compounds Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000001488 sodium phosphate Substances 0.000 abstract 1
- -1 trisodium phosphate Chemical class 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 abstract 1
- 235000019801 trisodium phosphate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
- C09B45/16—Monoazo compounds containing chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises complex chromium compounds of dyes of the formula <FORM:0727535/IV (c)/1> wherein R is hydrogen, halogen, or methyl, which compounds contain at least one chromium atom in complex linkage with two molecules of the dyestuff. They are made by reacting the said dyestuffs with agents giving off chromium under conditions such that two mols. dyestuff combine with at least one chromium atom, before or after application to the fibre. Chroming may be by use of a trivalent chromium salt in organic aqueous solution or an alkali salt of a disalicylato chromate. The products may be mixed with dispersing agents and basic-reacting salts such as trisodium phosphate, and dye wool, silk, nylon, and polyurethane fibres in green-blue shades. In examples, 5-nitro-2-amino-1-hydroxybenzene or its 4-chloro-, 4-bromo-, or 4-methyl derivatives are each diazotized and coupled with 1,3,6 - naphtholdisulphomethylamide, followed by chroming with ammonium disalicylato chromate. A dyeing example using wool is given.ALSO:1,3,6-Naphtholdisulphomethylamide is obtained from 1-acyloxynaphthalene 3,6-disulphonic acid by conversion of the sulphonic groups with phosphorus pentachloride followed by methylamine, and hydrolysis of the acyloxy group.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH727535X | 1952-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB727535A true GB727535A (en) | 1955-04-06 |
Family
ID=4532059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8694/53A Expired GB727535A (en) | 1952-03-28 | 1953-03-30 | Improvements relating to chromium-containing monoazo dyestuffs and their use |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB727535A (en) |
-
1953
- 1953-03-30 GB GB8694/53A patent/GB727535A/en not_active Expired
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