GB714868A - Improvements in or relating to polymerisation products - Google Patents
Improvements in or relating to polymerisation productsInfo
- Publication number
- GB714868A GB714868A GB30125/51A GB3012551A GB714868A GB 714868 A GB714868 A GB 714868A GB 30125/51 A GB30125/51 A GB 30125/51A GB 3012551 A GB3012551 A GB 3012551A GB 714868 A GB714868 A GB 714868A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl methacrylate
- methacrylate
- styrene
- acid
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- YYPNJNDODFVZLE-UHFFFAOYSA-N 3-methylbut-2-enoic acid Chemical compound CC(C)=CC(O)=O YYPNJNDODFVZLE-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000005749 Copper compound Substances 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001880 copper compounds Chemical class 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- FFYWKOUKJFCBAM-UHFFFAOYSA-N ethenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC=C FFYWKOUKJFCBAM-UHFFFAOYSA-N 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 229940049964 oleate Drugs 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Methyl methacrylate is bulk polymerized in admixture with a methyl methacrylate polymer in the presence of a mercaptan accelerator, such as tert.-dodecyl or tert.-hexadecyl mercaptan, a peroxide catalyst, such as benzoyl or lauroyl peroxide, and at least a trace of a copper compound, for example copper oxide, sulphate, methacrylate, or oleate. The speed of polymerization may be increased by incorporation of an acid, preferably a polymerizable acid, such as acrylic, methacrylic, or beta, beta-dimethacrylic acid. The methyl methacrylate monomer may contain a stabilizer such as hydroquinone, and may also be used in conjunction with minor proportions of other monomers containing a vinylidene group, for example vinyl acetate, styrene, alpha-methyl styrene, chlorostyrene, vinyl methacrylate, diglycol methacrylate, acrylonitrile, and vinylidene chloride. The polymeric component may be homopolymeric methyl methacrylate or a copolymer of methyl methacrylate with a minor proportion of another monomer containing a vinylidene group, such as styrene and chlorostyrene.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB30125/51A GB714868A (en) | 1951-12-24 | 1951-12-24 | Improvements in or relating to polymerisation products |
| FR1068579D FR1068579A (en) | 1951-12-24 | 1952-12-24 | Polymerization products and their preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB30125/51A GB714868A (en) | 1951-12-24 | 1951-12-24 | Improvements in or relating to polymerisation products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB714868A true GB714868A (en) | 1954-09-01 |
Family
ID=10302695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30125/51A Expired GB714868A (en) | 1951-12-24 | 1951-12-24 | Improvements in or relating to polymerisation products |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR1068579A (en) |
| GB (1) | GB714868A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2961432A (en) * | 1952-11-19 | 1960-11-22 | Basf Ag | Bulk polymerization comprising polymerizing a liquid monomer in the presence of a polymer powder |
| DE3116132A1 (en) * | 1980-04-29 | 1982-02-04 | Colgate-Palmolive Co., 10022 New York, N.Y. | "POLYMERIZABLE DENTAL MEASURES" |
| GB2159525A (en) * | 1984-05-29 | 1985-12-04 | Lord Corp | Structural adhesive formulations |
| US6624211B2 (en) | 2000-04-03 | 2003-09-23 | 3M Innovative Properties Company | Dental materials with extendable work time, kits, and methods |
-
1951
- 1951-12-24 GB GB30125/51A patent/GB714868A/en not_active Expired
-
1952
- 1952-12-24 FR FR1068579D patent/FR1068579A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2961432A (en) * | 1952-11-19 | 1960-11-22 | Basf Ag | Bulk polymerization comprising polymerizing a liquid monomer in the presence of a polymer powder |
| DE3116132A1 (en) * | 1980-04-29 | 1982-02-04 | Colgate-Palmolive Co., 10022 New York, N.Y. | "POLYMERIZABLE DENTAL MEASURES" |
| GB2159525A (en) * | 1984-05-29 | 1985-12-04 | Lord Corp | Structural adhesive formulations |
| US6624211B2 (en) | 2000-04-03 | 2003-09-23 | 3M Innovative Properties Company | Dental materials with extendable work time, kits, and methods |
| US6964985B2 (en) | 2000-04-03 | 2005-11-15 | 3M Innovative Properties Co. | Dental materials with extendable work time, kits, and methods |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1068579A (en) | 1954-06-28 |
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