GB683761A - Metachrome dyeing procedure - Google Patents
Metachrome dyeing procedureInfo
- Publication number
- GB683761A GB683761A GB7996/47A GB799647A GB683761A GB 683761 A GB683761 A GB 683761A GB 7996/47 A GB7996/47 A GB 7996/47A GB 799647 A GB799647 A GB 799647A GB 683761 A GB683761 A GB 683761A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dyeing
- condensation product
- initial
- dextrine
- magnesium sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004043 dyeing Methods 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 9
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 8
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 abstract 8
- 239000007859 condensation product Substances 0.000 abstract 5
- 239000000975 dye Substances 0.000 abstract 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 4
- 229920001353 Dextrin Polymers 0.000 abstract 4
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 abstract 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 4
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 4
- 240000008042 Zea mays Species 0.000 abstract 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 235000005822 corn Nutrition 0.000 abstract 2
- 239000000835 fiber Substances 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 210000002268 wool Anatomy 0.000 abstract 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 abstract 1
- 239000005695 Ammonium acetate Substances 0.000 abstract 1
- YEZXUEPAMXUIPW-UHFFFAOYSA-N C(O)(O)=O.C(CCCCCCCCCCCCCCCCC)NC(=N)N Chemical compound C(O)(O)=O.C(CCCCCCCCCCCCCCCCC)NC(=N)N YEZXUEPAMXUIPW-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 229940043376 ammonium acetate Drugs 0.000 abstract 1
- 235000019257 ammonium acetate Nutrition 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 239000001166 ammonium sulphate Substances 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/20—Wool using mordant dyes using metallisable dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
Nitrogenous textile fibres are dyed by means of a chromable dyestuff in the presence of a chromium salt and a cationic surface-active agent, the initial pH of the bath being sufficiently high to prevent rapid chromation but insufficiently high to damage the fibre, and dyeing is continued at an elevated temperature whilst the pH is gradually lowered to promote rapid dyeing and chromation. Magnesium sulphate may also be present in the bath. The initial pH is preferably not greater than 9. In an example: (1) wool is immersed in a bath containing a chrome dye and a mordant obtained by mixing potassium dichromate with a condensation product of octadecyl guanidine bicarbonate and ethylene oxide deposited on magnesium sulphate, the initial pH of 8.5 to 9.0 being lowered during dyeing by adding acetic acid. In other examples: (2) yellow corn dextrine is added to the mordant which is used as in (1); (4) the mordant contains also dextrine; (5), (7) and (9) yellow corn dextrine, the condensation product of (1), potassium dichromate and magnesium sulphate are colloidized in a mixer and the dyeing carried out while adding sulphuric acid to lower the pH; (10) the condensation product of polyethylene oxide and the dimerized acid obtained by heating soya bean acids is used as surface-active agent in the process of (1); (15) yellow dextrine and the condensation product of (1) are blended with a chrome dye and added to a dyebath containing also ammonium acetate, magnesium sulphate and potassium dichromate, the dyeing being started at pH 6.0 and reduced during dyeing to 5.0 by adding acetic acid; (16) wool is dyed from a bath containing a blend of the condensation product of (15) with a chrome dye, ammonium sulphate and potassium dichromate, the initial pH of 5 to 6 being lowered during dyeing by adding acetic acid. In the remaining examples, alternative chrome dyes are used or the dyeing is carried out with a casein or nylon fibre.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US683761XA | 1944-06-27 | 1944-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB683761A true GB683761A (en) | 1952-12-03 |
Family
ID=22082158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7996/47A Expired GB683761A (en) | 1944-06-27 | 1947-03-24 | Metachrome dyeing procedure |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB683761A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1003690B (en) * | 1953-03-06 | 1957-03-07 | Geigy Ag J R | Process for dyeing wool with complex heavy metal compounds of monoazo or azomethine dyes |
-
1947
- 1947-03-24 GB GB7996/47A patent/GB683761A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1003690B (en) * | 1953-03-06 | 1957-03-07 | Geigy Ag J R | Process for dyeing wool with complex heavy metal compounds of monoazo or azomethine dyes |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2869969A (en) | Formaldehyde as an assistant in the dyeing of polyester fibers and blends thereof athigh temperatures | |
| GB683761A (en) | Metachrome dyeing procedure | |
| US3561914A (en) | Process for dyeing natural nitrogenous fibrous material and a preparation thereof | |
| US3391985A (en) | Process for pad-dyeing and printing wool and synthetic textile fibers in carrier compositions | |
| US2903324A (en) | Hasoi | |
| US3098691A (en) | Dyeing of polyester fiber | |
| GB536104A (en) | Improvements in or relating to the chemical treatment of artificial fibres made of proteins | |
| GB826207A (en) | ú´-ú´-dihydroxy-monoazo dyestuffs containing pyrrolidonyl residues and their metal complex compounds | |
| US3597144A (en) | Process for continuously dyeing wool fibers with mordant black 11 and treating with sodium nitrite | |
| US2420729A (en) | Dyeing with indigoid vat dyestuffs | |
| US2117699A (en) | Dyeing of leather | |
| US3619124A (en) | Process for the dyeing or printing of fibrous materials | |
| US3079210A (en) | Process for the dyeing of copolymers of | |
| US2276602A (en) | Process of dyeing and the products | |
| GB614009A (en) | Improvements in or relating to the colouration of yarns or fabrics composed wholly or partly of nylon | |
| GB595344A (en) | Improvements in the art of printing textile yarns and fabrics containing cellulose acetate | |
| GB769174A (en) | Improvements in or relating to the dying of suede leather | |
| US1492051A (en) | Process of mordanting and dyeing wool | |
| US2336221A (en) | Dyeing wooled sheepskins | |
| US2618529A (en) | Application of leuco esters of vat dyestuffs on animal fibers using urea and an acid | |
| GB583349A (en) | Colouration of textile materials | |
| GB496277A (en) | A process for the treatment of artificial fibres obtained from casein | |
| GB930429A (en) | Process for dyeing nitrogenous fibres | |
| GB433230A (en) | Improvements in dyeing animal fibres | |
| GB483564A (en) | Improvements in the production of valuable dyeings on mixed fabrics |