GB671141A - Terephthalamide derivatives - Google Patents
Terephthalamide derivativesInfo
- Publication number
- GB671141A GB671141A GB3369/50A GB336950A GB671141A GB 671141 A GB671141 A GB 671141A GB 3369/50 A GB3369/50 A GB 3369/50A GB 336950 A GB336950 A GB 336950A GB 671141 A GB671141 A GB 671141A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxyethyl
- terephthalamide
- ooc
- tetra
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Di- and tetra-esters of terephthalamide of the general formula <FORM:0671141/IV (a)/1> in which R is hydrogen or -C2H4-OOC-R11 and R1 is -OOC-R11, R11 being a lower alkyl group, may be used as plasticizers and coating agents for cellulosic films and sheets such as of regenerated cellulose, cellulose acetate and cellulose nitrate. The b -hydroxyethyl derivatives of the above general formula, where R is hydrogen or a hydroxyethyl group and R1 is a hydroxy group, may be condensed with dibasic acids to produce fibres and fibre-forming polymeric materials.ALSO:The invention comprises terephthalamides of the general formula <FORM:0671141/IV (b)/1> where R is hydrogen, hydroxyethyl or -C2H4.OOC.R11 and R1 is hydroxyl or -OOC.R11, in which R11 is a lower alkyl group; and their preparation by heating a mixture of a terephthalic acid ester and mono-or di-ethanolamine in ethyl alcohol, and if desired esterifying the N,N1-bis (or tetra)-(b -hydroxyethyl)-terephthalamide with a lower aliphatic acid. Examples are given of the preparation of N,N1 - bis - (b - hydroxyethyl)-terephthalamide and its diacetate and dipropionate; N,N1 - tetra - (b - hydroxyethyl) - terephthalamide and its tetra-acetate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US671141XA | 1949-02-11 | 1949-02-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB671141A true GB671141A (en) | 1952-04-30 |
Family
ID=22073793
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3369/50A Expired GB671141A (en) | 1949-02-11 | 1950-02-09 | Terephthalamide derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB671141A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3342893A (en) * | 1963-11-29 | 1967-09-19 | Rohm & Haas | Alkylated condensate of formaldehyde and a diamide of an m-phenylene dicarboxylic acid |
EP3440060A4 (en) * | 2015-11-20 | 2020-04-29 | Hexion Research Belgium SA | Chemical products for surface protection |
US10836916B2 (en) | 2015-11-20 | 2020-11-17 | Hexion Inc. | Chemical products for surface protection |
-
1950
- 1950-02-09 GB GB3369/50A patent/GB671141A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3342893A (en) * | 1963-11-29 | 1967-09-19 | Rohm & Haas | Alkylated condensate of formaldehyde and a diamide of an m-phenylene dicarboxylic acid |
EP3440060A4 (en) * | 2015-11-20 | 2020-04-29 | Hexion Research Belgium SA | Chemical products for surface protection |
US10836916B2 (en) | 2015-11-20 | 2020-11-17 | Hexion Inc. | Chemical products for surface protection |
CN113201319A (en) * | 2015-11-20 | 2021-08-03 | 瀚森公司 | Chemical product for surface protection |
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