GB655913A - Manufacture of condensation products primarily intended for use in the treatment of textile materials - Google Patents
Manufacture of condensation products primarily intended for use in the treatment of textile materialsInfo
- Publication number
- GB655913A GB655913A GB2554648A GB2554648A GB655913A GB 655913 A GB655913 A GB 655913A GB 2554648 A GB2554648 A GB 2554648A GB 2554648 A GB2554648 A GB 2554648A GB 655913 A GB655913 A GB 655913A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glyoxal
- formaldehyde
- urea
- fibres
- kgs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title abstract 5
- 239000007859 condensation product Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000463 material Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 13
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 abstract 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- 229940015043 glyoxal Drugs 0.000 abstract 4
- 239000000047 product Substances 0.000 abstract 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- 229920000877 Melamine resin Polymers 0.000 abstract 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 150000001408 amides Chemical class 0.000 abstract 3
- 239000004202 carbamide Substances 0.000 abstract 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 3
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 abstract 2
- 150000007513 acids Chemical group 0.000 abstract 2
- 230000002579 anti-swelling effect Effects 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- NNTWKXKLHMTGBU-UHFFFAOYSA-N 4,5-dihydroxyimidazolidin-2-one Chemical compound OC1NC(=O)NC1O NNTWKXKLHMTGBU-UHFFFAOYSA-N 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000008098 formaldehyde solution Substances 0.000 abstract 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/10—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with acyclic compounds having the moiety X=C(—N<)2 in which X is O, S or —N
- C08G12/12—Ureas; Thioureas
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Textile fibres having improved anti-shrinking and anti-swelling qualities are obtained by impregnating the fibres with condensates obtained by condensing organic di- or poly-acid amides having no free acids groups, e.g. urea, melamine, or oxamide, in an acid medium with an amount of glyoxal such that only a portion of the reactive hydrogen atoms of the amide groups are substituted and then condensing the product thus obtained in an alkaline medium with sufficient formaldehyde to substitute the remaining hydrogen atoms of the amide. The condensation with formaldehyde is preferably effected in presence of polyalcohols, e.g. glycerol, ethylene glycol or 1.6-hexane diol. The product may be further condensed in an acid medium. The textiles are impregnated with an aqueous solution of the product containing a catalyst, e.g. ammonium nitrate, wrung out, and dried at 110-120 DEG C. for about 15 minutes. In examples: (1) 1.5 kgs. urea are dissolved in 5.8 kgs. glyoxal solution; the solution is acidified with HCl, boiled and cooled; the white precipitate of glyoxal-urea is separated and mixed with an alkaline 30 per cent formaldehyde solution containing glycerol; the mixture is acidified, boiled until all the formaldehyde is combined, mixed with 20 gs. ammonium nitrate and the cellulose fabric immersed therein. A decrease in swelling value from 100 to 53 and shrinkage from 15 to 0.5 per cent is obtained; (2) 2.52 gs. melamine mixed with 5.8 kgs. glyoxal are similarly reacted.ALSO:Textile fibres having improved anti-shrinking and anti-swelling qualities are obtained by impregnating the fibres with condensates obtained by condensing organic di- or poly-acid amides having no free acids groups, e.g. urea, melamine, or oxamide, in an acid medium with glyoxal and formaldehyde (see Group IV (a)). The textiles are impregnated with an aqueous solution of the product containing a catalyst, e.g. ammonium nitrate, wrung out, and dried at 110-120 DEG C. for about 15 minutes.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1010099T | 1948-04-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB655913A true GB655913A (en) | 1951-08-08 |
Family
ID=33396926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2554648A Expired GB655913A (en) | 1948-04-26 | 1948-09-30 | Manufacture of condensation products primarily intended for use in the treatment of textile materials |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE485409A (en) |
| CH (1) | CH286101A (en) |
| FR (1) | FR1010099A (en) |
| GB (1) | GB655913A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1190425B (en) * | 1959-03-12 | 1965-04-08 | Sumitomo Chemical Co | Process for wrinkle-free textile finishing |
| DE1266307B (en) * | 1964-04-11 | 1968-04-18 | Basf Ag | Process for the preparation of dimethylolglyoxalmonourein |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE939568C (en) * | 1951-08-18 | 1956-02-23 | Basf Ag | Process for the production of impregnations on textiles made of cellulose |
| DE945232C (en) * | 1952-06-26 | 1956-07-05 | Basf Ag | Process for making wool or articles thereof shrink-proof |
| NL185069B (en) * | 1953-03-09 | Dow Chemical Co | MOLDED, MORE THAN ONE LAYER, METAL / POLYMER COMPOSITION AND MOLDABLE COMPOSITION. | |
| CN108892762B (en) * | 2018-06-22 | 2020-11-24 | 淄博鲁瑞精细化工有限公司 | Preparation method of fabric hand feeling improved non-ironing resin |
-
1948
- 1948-04-26 FR FR1010099D patent/FR1010099A/en not_active Expired
- 1948-09-30 GB GB2554648A patent/GB655913A/en not_active Expired
- 1948-10-21 BE BE485409D patent/BE485409A/xx unknown
- 1948-10-21 CH CH286101D patent/CH286101A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1190425B (en) * | 1959-03-12 | 1965-04-08 | Sumitomo Chemical Co | Process for wrinkle-free textile finishing |
| DE1266307B (en) * | 1964-04-11 | 1968-04-18 | Basf Ag | Process for the preparation of dimethylolglyoxalmonourein |
Also Published As
| Publication number | Publication date |
|---|---|
| CH286101A (en) | 1952-10-15 |
| BE485409A (en) | 1949-04-21 |
| FR1010099A (en) | 1952-06-13 |
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